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    • 2. 发明公开
    • Pyrimidine derivative, liquid crystal composition comprising the derivative, and liquid crystal display device fabricated by using the composition
    • 嘧啶衍生物,含有液晶组合物,和产品使用这种组合物的液晶显示装置制成
    • EP1006109A1
    • 2000-06-07
    • EP98250419.3
    • 1998-12-01
    • CHISSO CORPORATION
    • Haseba, YasuhiroMatsui, ShuichiMiyazawa, KazutoshiTakeuchi, HiroyukiTomi, YoshitakaTakeshita, FusayukiNakagawa, Etsuo
    • C07D239/26C07D239/28C09K19/34
    • C07D239/26C09K19/3458C09K19/3469C09K19/42C09K19/44C09K19/46C09K2019/0448C09K2019/0451Y10T428/10
    • An object of the invention is to provide liquid crystalline compounds having a comparatively high voltage holding ratio, high Δn and high Δε, and being excellent in miscibility with known liquid crystalline compounds at low temperatures; to provide liquid crystal compositions comprising the liquid crystalline compound; and to provide liquid crystal display devices fabricated by using the liquid crystal composition; the liquid crystalline compounds are expressed by the general formula (1)
      wherein R represents hydrogen atom or an alkyl group having 1 to 20 carbon atoms; n1 and n2 are independently 0, 1, or 2 provided that the sum of n1 and n2 is 1 or 2; ring A and ring B independently represent 1,4-phenylene, fluorine substituted 1,4-phenylene expressed by the formula (a)
      or 1,4-cyclohexylene provided that at least one of ring A and ring B is fluorine substituted 1,4-phenylene expressed by the formula (a); Za, Zb, and Zc independently represent single bond, -CH 2 CH 2 -, -COO-, -CF 2 O-, or -CH 2 CH 2 CH 2 CH 2 -; Q 1 , Q 2 , Q 3 , Q 4 , Q 5 , Q 6 , and Q 7 independently represent hydrogen atom, a halogen atom, or methyl group provided that when at least one of Za, Zb, and Zc is -CH 2 CH 2 -, Q 2 is fluorine atom; Y represents hydrogen atom, a halogen atom, or a halogenated alkyl group having 1 to 5 carbon atoms; and each atom constituting this compound may be replaced by its isotope.
    • 本发明的一个目的是提供一种具有比较高的电压保持率,高DELTA n和高DELTAε,并且是优异的在低温下用已知的液晶化合物的混溶性的液晶化合物; 为了提供液晶组合物,包含液晶化合物; 并提供一种通过使用该液晶组合物制造的液晶显示装置; 液晶化合物是由通式(1) worinřdarstellt氢原子或烷基具有1至20个碳原子基团中过表达; n1和n2是unabhängig0,1或2提供确实n1和n2的总和为1或2; 环A和环B代表unabhängig1,4-亚苯基,氟substituiertem 1,4-亚苯基的式(a)中或提供1,4-亚环己做环A中的至少一个和环B是氟substituiertem表达 的1,4-亚苯基的式(a)中表达; ZA,ZB,ZC和表示unabhängig单键,-CH2CH2 - , - COO - , - CF 2 O-,或-CH2CH2CH2CH2-; Q1,Q2,Q3,Q4,Q5,Q6,Q7和unabhängig表示氢原子,卤原子,或甲基设置并当ZA,ZB,ZC和中的至少一个是-CH 2 CH 2,Q 2是氟原子; Y表示氢原子,卤原子,或具有1至5个碳原子的卤代烷基; 和构成该化合物的每个原子可被其同位素置换。