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    • 8. 发明公开
    • Electrophotographic photosensitive member and electrophotographic apparatus, device unit and facsimile machine using the same
    • 电子照相感光构件,静电照相装置,装置单元,并使用相同的传真机。
    • EP0504794A1
    • 1992-09-23
    • EP92104575.3
    • 1992-03-17
    • CANON KABUSHIKI KAISHA
    • Maruyama, Akio, c/o Canon Kabushiki KaishaKikuchi, Toshihiro, c/o Canon Kabushiki KaishaAmamiya, Shoji, c/o Canon Kabushiki KaishaNagahara, Shin, c/o Canon Kabushiki KaishaAoki, Katsumi, c/o Canon Kabushiki KaishaTsuji, Haruyuki, c/o Canon Kabushiki Kaisha
    • G03G5/147G03G5/06
    • G03G5/0614G03G5/0616G03G5/0668G03G5/14791
    • A electrophotographic photosensitive member and an electrophotographic apparatus, a device unit and a facsimile machine using an electrophotographic photosensitive member which comprises a conductive support, a photosensitive layer and a protective layer, the protective layer containing resin formed by hardening a light-setting type acrylic monomer, and the photosensitive layer containing at least one compound selected from the group consisting of (A), (B) and (C) below:

      (A) styryl compounds having a structure expressed by the following formula (1) and a melting point not higher than 135 °C;
      wherein Ar¹ and Ar² are aromatic ring groups, Ar³ is a bivalent aromatic ring group or a bivalent heterocyclic group, R¹ is an alkyl group or an aromatic ring group, R² is a hydrogen atom, an alkyl group or an aromatic ring group, and n₁ is 1 or 2, R¹ and R² possibly linking to form a ring when n₁ = 1:
      (B) triarylamine compounds having a structure expressed by the following formula (2) and a melting point not higher than 150 °C;
      wherein Ar⁴, Ar⁵ and Ar⁶ are each an aromatic ring group or a heterocyclic group:
      (C) hydrazone compounds having a structure expressed by the following formula (3) and a melting point not higher than 155 °C;
      wherein R³ is a hydrogen atom or an alkyl group, R⁴ and R⁵ are alkyl groups, aralkyl groups or aromatic ring groups, n₂ is 1 or 2, A is an aromatic ring group, a heterocyclic group or - CH = C(R⁶)R⁷ (R⁶ and R⁷ are hydrogen atoms, aromatic ring groups or heterocyclic groups, but will never be hydeogen atoms at the same time). The photosensitive member suppresses the occurrence of cracks during forming of the protective layer, has high durability, and is free from any image defects.
    • 甲电子照相感光件,并在电子照相装置,装置单元和使用电子照相光敏元件,它包括一个导电支撑,一个感光层和保护层,通过硬化的光固化型丙烯酸类单体形成的保护层包含树脂的传真机 ,和感光层含有选自(A)的中的至少一种化合物,(B)和下面(C):具有由下式表示的结构(A)苯乙烯基化合物(1)和熔点不 高于135℃; worin的Ar <1>和Ar <2>是芳族环基团中,Ar <3>为二价芳环基团或二价杂环基,R <1>是烷基或芳香环基,R < 2>是氢原子的烷基或芳香环基,和n1是1或2,R <1>和R <2>可能连接形成环。当N1 = 1:(B)三芳基胺具有化合物 结构由下式(2)表示,熔点不高于150℃; worin的Ar <4>中,Ar <5>和Ar <6>各自与芳族环基或杂环基团:具有由下式表示的结构(C)腙化合物(3)和熔点不 高于155℃; worin - [R <3>是氢原子或烷基,R <4>和R <5>是烷基,芳烷基或芳族环基团,n 2为1或2,A是芳族环基团, 杂环基或 - CH = C(R <6>)R <7>(R <6>和R <7>是氢原子,芳族环基团或杂环基团,但绝不会在同一时间hydeogen原子) , 感光部件禁止裂缝的发生保护层的形成过程中,具有较高的耐久性,并且是从任何图像缺陷。