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    • 7. 发明公开
    • Liquid jet recording head and recording apparatus having same
    • 液体喷射记录头及具有该记录头的记录装置
    • EP0447587A1
    • 1991-09-25
    • EP90105464.3
    • 1990-03-22
    • CANON KABUSHIKI KAISHA
    • Noguchi, HiromichiInamoto, TadayoshiSaito, Megumi
    • B41J2/16C08F299/02C08F283/10C08L63/10C08L51/00G03F7/004
    • B41J2/14129B41J2/1604B41J2/1623B41J2/1631B41J2/1632B41J2/1639B41J2/164B41J2/1643B41J2202/03C08F285/00C08F290/144C08L63/10G03F7/038C08L2666/02
    • A liquid jet recording head comprises a cured product of an active energy-ray-curing resin composition as at least a part of its constitution, said composition comprising:

      (A) a graft copolymerized polymer having a number average molecular weight of 5,000 or more and a weight average molecular weight of 50,000 or less which comprises a trunk chain composed mainly of structural units derived from at least one monomer (hereinafter referred to as "monomer (a)") selected from the group consisting of alkyl methacrylates, acrylonitrile and stylene and has graft chains having structural units derived from at least one monomer (hereinafter referred to as "monomer (b)") selected from the group consisting of the monomers represented by the following formula x and other monomers presented by the formula y:

      (wherein R 1 is hydrogen or an alkyl or hydroxyalkyl group having 1 to 3 carbon atoms, R 2 is hydrogen or an alkyl or acyl group having 1 to 4 carbon atoms which may have hydroxy group, R 3 is an alkyl group having 2 to 6 carbon atoms, a halogen-substituted alkyl group having 2 to 6 carbon atoms, an alkylether group represented by the formula:
      (wherein 2≦m + n≦6, n≠O and m≠0), or a phenylalkyl group represented by the formula:
      (wherein 2≦m + n≦4, or the case where n = 0 or m = 0 is contained), added to said trunk chain;
      (B) a linear polymer having a number average molecular weight of 50,000 or more and a weight average molecular weight of 350,000 or less and having a glass transition temperature of 60 ° C or more which comprises structural units derived from at least one monomer (hereinafter referred to as "monomer (c)") selected from the group consisting of methyl methacrylate, ethyl methacrylate, isobutyl methacrylate, t-butyl methacrylate, benzyl methacrylate, acrylonitile, isobornyl mechacrylate, isobornyl acrylate, tricyclodecaneacrylate, tricyclodecane methacrylate, tricyclodecaneoxyethyl methacrylate, styrene, dimethylaminoethyl methacrylate and cyclohexyl methacrylate and other structural units derived from at least one monomer (hereinafter called monomer (b)) selected from the group consisting of the monomers represented by the formula (x) and the monomers represented by the formula (y) provided that the monomer (a) and the monomer (b ) may have either the same composition or different compositions;
      (C) a resin esterificated at part of epoxy groups present in an epoxy resin containing at least one compound having two or more epoxy groups in one molecule with an unsaturated carboxylic acid;
      (D) a monomer having an ethylenically unsaturated bond; and
      (E) a polymerization intiator capable of generating a Lewis acid by irradiation of an active energy ray.
    • 1。一种液体喷射记录头,其特征在于,作为其构成的至少一部分含有活性能量射线固化型树脂组合物的固化物,所述组合物含有:(A)数均分子量为5000以上的接枝共聚聚合物, 包含主要由来源于选自甲基丙烯酸烷基酯,丙烯腈和苯乙烯的至少一种单体(以下称为“单体(a)”)的结构单元构成的主链和重均分子量为50,000以下的重均分子量和 具有由选自由下式x表示的单体和由式y表示的其它单体组成的组中的至少一种单体衍生的结构单元(以下称为“单体(b)”)的接枝链:其中R1 是氢或具有1至3个碳原子的烷基或羟烷基,R 2是氢或具有1至4个碳原子的可以具有羟基的烷基或酰基,R 3是 具有2至6个碳原子的烷基,具有2至6个碳原子的卤素取代的烷基,由下式表示的烷基醚基团(其中2≤m+n≤6,n≠0且m≠0)或 在所述主链上加成由下式表示的苯基烷基(式中,2≤m+n≤4,或含有n = 0或m = 0的情况) (B)数均分子量为50,000以上且重均分子量为350,000以下且玻璃化转变温度为60℃以上的线型聚合物,其包含由至少一种单体衍生的结构单元(以下称为 (甲基)丙烯酸甲酯,甲基丙烯酸异丁酯,甲基丙烯酸叔丁酯,甲基丙烯酸苄酯,丙烯腈,甲基丙烯酸甲酯,丙烯酸异冰片酯,丙烯酸异冰片酯,丙烯酸三环癸酯,甲基丙烯酸三环癸酯,甲基丙烯酸三环癸烷氧基乙酯, ,甲基丙烯酸二甲氨基乙酯和甲基丙烯酸环己酯以及选自由式(x)表示的单体和由式(y)表示的单体组成的组中的至少一种单体(在下文中称为单体(b))衍生的其他结构单元 单体(a)和单体(b)可以具有相同的组成或不同的组成 位数; (C)在含有1个分子中具有2个以上环氧基的至少1种化合物的环氧树脂中存在的环氧基的一部分与不饱和羧酸一起酯化的树脂; (D)具有烯键式不饱和键的单体; 和(E)能够通过照射活性能量射线产生路易斯酸的聚合引发剂。