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    • 1. 发明授权
    • EPOXY RESIN COMPOSITIONS
    • EP3122734B1
    • 2018-01-31
    • EP15709587.8
    • 2015-02-26
    • Blue Cube IP LLC
    • HEFNER, Robert E.BEIGZADEH, DaryooshCOULING, David J.COYLE, Robert W.CARR, David A.
    • C07D301/28C08G59/02
    • C08G59/04C07D301/28
    • A process for preparing an aliphatic or cycloaliphatic epoxy resin composition including the steps of: (I) reacting a mixture of the following components: (a) an aliphatic or cycloaliphatic hydroxyl-containing material, (b) an epihalohydrin, (c) a stoichiometric excess of a base compound or basic acting substance, (d) a catalyst, and (e) optionally, a solvent; wherein the reacting step (I) is carried out under reaction conditions sufficient to form a crude aliphatic or cycloaliphatic epoxy resin composition product in the resultant reaction mixture; (II) neutralizing the resultant reaction mixture of step (I) containing the crude aliphatic or cycloaliphatic epoxy resin composition product with a phosphate neutralizing agent sufficient to partially neutralize the base or basic acting substance and to form a neutralized fluid medium containing aliphatic or cycloaliphatic epoxy resin composition product; (III) removing at least a portion of unreacted epihalohydrin from the reaction mixture of step (II); and (IV) subjecting the reaction mixture of step (III) above to a separation process to recover the aliphatic or cycloaliphatic epoxy resin composition product from the neutralized fluid medium; wherein the aliphatic or cycloaliphatic epoxy resin composition product yield is greater than about 70 percent.
    • 3. 发明公开
    • EPOXY RESIN COMPOSITIONS
    • EPOXIDHARZZUSAMMENSETZUNGEN
    • EP3122734A1
    • 2017-02-01
    • EP15709587.8
    • 2015-02-26
    • Blue Cube IP LLC
    • HEFNER, Robert E.BEIGZADEH, DaryooshCOULING, David J.COYLE, Robert W.CARR, David A.
    • C07D301/28C08G59/02
    • C08G59/04C07D301/28
    • A process for preparing an aliphatic or cycloaliphatic epoxy resin composition including the steps of: (I) reacting a mixture of the following components: (a) an aliphatic or cycloaliphatic hydroxyl-containing material, (b) an epihalohydrin, (c) a stoichiometric excess of a base compound or basic acting substance, (d) a catalyst, and (e) optionally, a solvent; wherein the reacting step (I) is carried out under reaction conditions sufficient to form a crude aliphatic or cycloaliphatic epoxy resin composition product in the resultant reaction mixture; (II) neutralizing the resultant reaction mixture of step (I) containing the crude aliphatic or cycloaliphatic epoxy resin composition product with a phosphate neutralizing agent sufficient to partially neutralize the base or basic acting substance and to form a neutralized fluid medium containing aliphatic or cycloaliphatic epoxy resin composition product; (III) removing at least a portion of unreacted epihalohydrin from the reaction mixture of step (II); and (IV) subjecting the reaction mixture of step (III) above to a separation process to recover the aliphatic or cycloaliphatic epoxy resin composition product from the neutralized fluid medium; wherein the aliphatic or cycloaliphatic epoxy resin composition product yield is greater than about 70 percent.
    • 一种制备脂族或脂环族环氧树脂组合物的方法,包括以下步骤:(I)使下列组分的混合物反应:(a)脂族或脂环族羟基材料,(b)表卤代醇,(c)化学计量 过量的碱性化合物或碱性作用物质,(d)催化剂和(e)任选的溶剂; 其中反应步骤(I)在足以在所得反应混合物中形成脂族或脂环族环氧树脂组合物粗产物的反应条件下进行; (II)将含有粗脂族或脂环族环氧树脂组合物产物的步骤(I)的所得反应混合物与足以部分中和碱或作用物质的磷酸中和剂中和,并形成含有脂族或脂环族环氧基的中和流体介质 树脂组合物产品; (III)从步骤(II)的反应混合物中除去至少一部分未反应的表卤代醇; 和(IV)使上述步骤(III)的反应混合物进行分离过程以从中和的流体介质回收脂族或脂环族环氧树脂组合物产品; 其中脂族或环脂族环氧树脂组合物的产率大于约70%。