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    • 5. 发明公开
    • Polymeric compositions for medical packaging and devices
    • Polymerzusammensetzungfürmedizinische Verpackungen und Vorrichtungen
    • EP1008357A2
    • 2000-06-14
    • EP00200435.6
    • 1994-11-16
    • BAXTER INTERNATIONAL INC.
    • Anderson, WilliamRosenbaum, Larry A.Hayward, Denise S.Hoppesch, Joseph P.Nebgen, GreggWestphal, StanleyDing, Yuan-Pang SamuelWoo, LeconLing, Michael T. K.Laurin, DeanBuan, Angeles Lillian
    • A61L27/00A61L31/00C08L23/02C08L23/04C08L23/06C08L23/08C08L23/10C08L23/14C08L23/16C08L53/00C08L51/04
    • C08L23/02C08L23/0815C08L23/0846C08L23/0853C08L23/0869C08L23/10C08L51/06C08L53/00C08L53/02C08L77/00C08L101/00C08L2203/02C08L2205/08C08L2666/04C08L2666/20C08L2666/14C08L2666/24C08L2666/02
    • A polymer based composition for fabricating into articles is described. The composition comprises:

      a polypropylene in an amount by weight from 40-90% of the composition and having a melting temperature greater than 130°C;
      a radio frequency susceptible polymer in an amount by weight from 5-50% of the composition and having a dielectric loss greater than 0.05 at 1-60 MHz and ambient temperature to 250°C, the susceptible polymer being selected from (1) polymers containing at least one segment selected from the group consisting of urethanes, esters, ureas, imides, sulfones, and amides, and (2) ethylene copolymers having 50-85% ethylene content copolymerized with at least one monomer selected from the group consisting of acrylic acid, methacrylic acid, ester derivatives of acrylic acid with alcohols having 1-10 carbons, vinyl acetate, and vinyl alcohol;
      a compatibilizing polymer in an amount by weight from 5-30% of the composition, the compatibilizing polymer conferring compatibility between the radio frequency susceptible polymer, and the polypropylene, the compatibilizing polymer being a styrenic block copolymer with hydrocarbon soft segments, and
         wherein the composition has an optical haze value of less than 30% for the composition processed into a film of about 0.299 mm in thickness measured in accordance to ASTM D-1003, a mechanical modulus of less than 2758x10 5 Pa when measured according to ASTM D-882 and the composition exhibits no strain whitening after being strained at moderate speeds of about 50 cm per minute to about 100% elongation.
    • 描述了用于制造成制品的基于聚合物的组合物。 组合物包含:重量为组合物重量的40-90%的聚丙烯,其熔点大于130℃; 一种无线电频率敏感聚合物,其量为组合物的5-50%,并且在1-60MHz和环境温度至250℃下的介电损耗大于0.05,敏感聚合物选自(1)含 选自由氨基甲酸酯,酯,脲,酰亚胺,砜和酰胺组成的组中的至少一个片段,和(2)具有50-85%乙烯含量的乙烯共聚物,其与至少一种选自丙烯酸 ,甲基丙烯酸,丙烯酸与具有1-10个碳的醇的酯衍生物,乙酸乙烯酯和乙烯醇; 相容聚合物,其量为组合物的5-30%,相容性聚合物赋予射频易感性聚合物与聚丙烯之间的相容性,相容性聚合物是与烃软链段的苯乙烯嵌段共聚物,并且其中组合物 对于根据ASTM D-1003测量的加工成约0.299mm厚度的膜的组合物的光学雾度值小于30%,当根据ASTM D-1003测量时的机械模量小于2758×10 5 Pa, 882,并且组合物在以约50cm 3 /分钟的中等速度应变至约100%伸长率后不显示应变增白。