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    • 3. 发明公开
    • FLUORINATED ACRYLATE BLOCK COPOLYMERS WITH LOW DYNAMIC SURFACE TENSION
    • 荧光素丙烯酸酯 - 木瓜蛋白酶MER GERINGER DYNAMISCHEROBERFLÄCHENSPANNUNG
    • EP2817370A1
    • 2014-12-31
    • EP13706244.4
    • 2013-02-22
    • BASF SE
    • THOMSON, MaryKNISCHKA, RalfAUSCHRA, ClemensENGELBRECHT, Lothar
    • C08L53/00C09D153/00C09J153/00C08L27/12C08L33/14C08L33/16C08L75/04C09D133/16C09J133/16C09D11/00
    • The present invention relates to a composition, comprising a binder resin, a block copolymer which comprises at least a block A and a block B, wherein the block A comprises monomer units derived from a compound selected from (meth)acrylic acid, a (meth)acrylic acid ester, a (meth)acrylamide, a vinyl aromatic compound, or any mixture thereof, the block B comprises monomer units derived from a compound selected from a fluorinated (meth)acrylic ester having the following formula (I): H2C═C(R1)(C(0)ORF-1), wherein R1 is H or methyl; and RF-1 is an organic residue containing a perfluorinated C4-6 alkyl group, a fluorinated alpha-olefin having the following formula (II): H2C═CH(RF-2) (II) wherein RF-2 is an organic residue containing a perfluorinated C4-6 alkyl group, i.e. —(CF2)3-5—CF3 or any mixture thereof.
    • 本发明涉及包含粘合剂树脂,至少包含嵌段A和嵌段B的嵌段共聚物的组合物,其中嵌段A包含衍生自选自(甲基)丙烯酸,(甲基)丙烯酸, )丙烯酸酯,(甲基)丙烯酰胺,乙烯基芳族化合物或其任何混合物,嵌段B包含衍生自选自具有下式(I)的氟化(甲基)丙烯酸酯的化合物的单体单元:H 2 C = C(R 1)(C(O)ORF-1),其中R 1为H或甲基; 并且RF-1是含有全氟化C 4-6烷基的有机残基,具有下式(II)的氟化α-烯烃:H 2 C = CH(RF-2)(II)其中RF-2是含有 全氟化C 4-6烷基,即 - (CF 2)3-5-CF 3或其任何混合物。