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1. 发明授权

EP1971675B1 MISCHPULVER ODER MISCHGRANULAT AUF BASIS VON GLUTAMINSÄURE-N,N-DIESSIGSÄURE UND IHREN SALZEN 有权
标题翻译：混合粉末或混合颗粒基于谷氨酸N，N-二及其盐的
公开(公告)号：EP1971675B1
公开(公告)日：2012-06-06
申请号：EP06841537.1
申请日：2006-12-21
申请人： BASF SE
发明人： SEEBECK, Tanja , KISSAU, Lars
IPC分类号： C11D3/33 , C11D1/66 , C11D1/72 , C11D3/37
CPC分类号： C11D1/66 , C11D1/72 , C11D3/33 , C11D3/3707 , C11D3/3753 , C11D3/3776
摘要： What is described is a mixed powder or mixed granule comprising at least 80% by weight of a mixture of (a) from 5 to 95% by weight of at least one glutamic acid-N,N-diacetic acid derivative of the general formula (I) MOOC-(CH2)2C(COOM)-N(CH2COOM)2 (I) where M is hydrogen, ammonium, alkali metal, (b) from 5 to 95% by weight of at least one polyethylene glycol or of at least one nonionic surfactant or of a mixture thereof or of a polymer selected from the group consisting of polyvinyl alcohols, polyvinylpyrrolidones (PVPs), polyalkylene glycols and derivatives thereof, processes for producing these mixed powders or mixed granules, the use of these mixed powders or mixed granules, and also a solid washing composition and a solid dishwasher detergent comprising the inventive mixed powder or mixed granule.

2. 发明授权

EP1924676B1 REINIGUNGSFORMULIERUNGEN FÜR DIE MASCHINELLE GESCHIRRREINIGUNG ENTHALTEND HYDROPHIL MODIFIZIERTE POLYCARBOXYLATE 有权
标题翻译：清洁制剂机器洗餐具含亲水性改性的羧酸盐
公开(公告)号：EP1924676B1
公开(公告)日：2009-04-15
申请号：EP06793039.6
申请日：2006-08-29
申请人： BASF SE
发明人： SEEBECK, Tanja , TROPSCH, Jürgen , KISSAU, Lars
IPC分类号： C11D3/33 , C11D3/37
CPC分类号： C11D3/3757 , C11D3/33
摘要： The invention relates to a phosphate-free cleaning formulation for machine dishwashing comprising as components: a) 1 to 20% by weight of copolymers of a1) 50 to 99.5 mol% of a monoethylenically unsaturated monocarboxylic acid and/or of a salt thereof, a2) 0.5 to mol% of an alkoxylated monoethylenically unsaturated monomer of the formula (I), a3) 0 to 50 mol% of a monoethylenically unsaturated dicarboxylic acid, an anhydride and/or a salt thereof, a4) 0 to 20 mol% of a further copolymerizable monoethylenically unsaturated monomer, where the copolymer has an average molecular weight Mw of from 30 000 to 500 000 g/mol and a K value of from 40 to 150, measured at pH 7 in 1% strength by weight aqueous solution at 25°C, b) 1 to 50% by weight of complexing agents chosen from the group consisting of nitrilotriacetic acid, ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, hydroxyethylethylenediaminetriacetic acid and glycine-N,N-diacetic acid and derivatives thereof, glutamic acid-N,N-diacetic acid, iminodisuccinate, hydroxyiminodisuccinate, S,S-ethylenediaminedisuccinate and aspartic acid-diacetic acid, and the salts of the abovementioned substances, c) 1 to 15% by weight of low-foaming nonionic surfactants, d) 0.1 to 30% by weight of bleaches and optionally bleach activators, e) 0 to 60% by weight of further builders, f) 0 to 8% by weight of enzymes, g) O to 50% by weight of one or more further additives, where the sum of components a) to g) is 100% by weight.

3. 发明公开

EP2052066A1 REINIGUNGSFORMULIERUNG FÜR GESCHIRRSPÜLMASCHINEN 审中-公开
标题翻译：清洁制剂洗碗机
公开(公告)号：EP2052066A1
公开(公告)日：2009-04-29
申请号：EP07788080.5
申请日：2007-07-31
申请人： BASF SE
发明人： VANDERMEULEN, Guido , HERRERA TABOADA, Lidcay , SEEBECK, Tanja
IPC分类号： C11D3/37 , C11D3/33 , C11D1/825 , C11D1/66
CPC分类号： C11D3/378 , C11D1/66 , C11D1/825 , C11D3/33
摘要： A cleaning formulation for machine dishwashing, comprising: a) 1 to 20 % by weight of one or more copolymers, obtainable by polymerization of aa) 5 to 80 % by weight of one or more monoethylenic unsaturated monocarbon acids or the salts thereof, bb) 5 to 60 % by weight of one or several monoethylecic unsaturated dicarbon acids or the salts or anhydrides thereof, cc) 1 to 50% by weight of one or more sulfon acid containing monomers or the salts thereof and dd) 0 to 50 % by weight of further ionic or non-ionic monomers: b) 1 to 50 % by weight of one or more complexing agents from the group consisting of nitrilotriacetic acid, ethylenediaminetetraacetic acid, glycine-N,N-diacetic acid, glutamic acid-N,N-diacetic acid, minodisuccinate, hydroxyiminodisuccinate, S,S-ethylenediamine-disuccinate aspartic acid-diacetic acid, and the salts thereof: c) 1 to 15 % by weight nonionic surfectants; d) 0 to 30 % by weight of bleaches and optionally bleach activators: e) 0 to 60 % by weight of one or more further additives, such as anionic or zwitterionic surfactants, bleach catalysts, alkali carriers, corrosion inhibitors, antifoams, dyes, fragrances, fillers, organic solvents and water.

4. 发明授权

EP1941016B1 VERFAHREN ZUR HERSTELLUNG VON GRANULÄREN ODER PULVERFÖRMIGEN WASCHMITTELZUSAMMENSETZUNGEN 有权
标题翻译：用于生产粒状或粉状洗衣洗涤剂组合物
公开(公告)号：EP1941016B1
公开(公告)日：2012-07-04
申请号：EP06793896.9
申请日：2006-09-29
申请人： BASF SE
发明人： SEEBECK, Tanja , GÜMBEL, Helmut
IPC分类号： C11D3/37 , C11D11/00
CPC分类号： C11D11/0082 , C11D3/3761
摘要： The invention relates to a method for producing granular or powdery detergent compositions, involving the production of a detergent base powder by drying an aqueous detergent slurry. The invention is characterized in that a copolymer is added to the slurry. This copolymer can be obtained by radically copolymerizing: (A) 20 to 80 % by weight of at least one monomer from the group of monoethylenically unsaturated monocarboxylic acids, dicarboxylic acids and dicarboxylic acid anhydrides, and; (B) 20 to 80 % by weight at least one monomer from the group of aliphatic or aromatic monoolefins.

5. 发明授权

EP1924675B1 REINIGUNGSFORMULIERUNGEN FÜR DIE MASCHINELLE GESCHIRRREINIGUNG ENTHALTEND HYDROPHIL MODIFIZIERTE POLYCARBOXYLATE 有权
标题翻译：清洁制剂机器洗餐具含亲水性改性的羧酸盐
公开(公告)号：EP1924675B1
公开(公告)日：2010-11-10
申请号：EP06778368.8
申请日：2006-08-28
申请人： BASF SE
发明人： SEEBECK, Tanja , TROPSCH, Jürgen , KISSAU, Lars
IPC分类号： C11D3/33 , C11D3/37
CPC分类号： C11D3/3757 , C11D3/33
摘要： The invention relates to a phosphate-free cleaning formulation for machine dishwashing, comprising as components: a) 1 to 20% by weight of copolymers of a1) 50 to 93 mol% acrylic acid and/or of a water-soluble salt of acrylic acid, a2) 5 to 30 mol% of methacrylic acid and/or of a water-soluble salt of methacrylic acid and a3) 2 to 20 mol% of at least one nonionic monomer of the formula (I), b) 1 to 50% by weight of complexing agents chosen from the group consisting of glycine-N,N-diacetic acid derivatives and glutamic acid-N,N-diacetic acid and salts thereof, c) 1 to 15% by weight of low-foaming nonionic surfactants, d) 0 to 30% by weight of bleaches and optionally bleach activators, e) 0 to 60% by weight of further builders, f) 0 to 8% by weight of enzymes, g) 0 to 50% by weight of one or more further additives, such as anionic or zwitterionic surfactants, bleach catalysts, alkali carriers, corrosion inhibitors, antifoams, dyes, fragrances, fillers, organic solvents and water, where the sum of components a) to g) is 100% by weight.

6. 发明公开

EP1941016A1 VERFAHREN ZUR HERSTELLUNG VON GRANULÄREN ODER PULVERFÖRMIGEN WASCHMITTELZUSAMMENSETZUNGEN 有权
标题翻译：用于生产粒状或粉状洗衣洗涤剂组合物
公开(公告)号：EP1941016A1
公开(公告)日：2008-07-09
申请号：EP06793896.9
申请日：2006-09-29
申请人： BASF SE
发明人： SEEBECK, Tanja , GÜMBEL, Helmut
IPC分类号： C11D3/37 , C11D11/00
CPC分类号： C11D11/0082 , C11D3/3761
摘要： The invention relates to a method for producing granular or powdery detergent compositions, involving the production of a detergent base powder by drying an aqueous detergent slurry. The invention is characterized in that a copolymer is added to the slurry. This copolymer can be obtained by radically copolymerizing: (A) 20 to 80 % by weight of at least one monomer from the group of monoethylenically unsaturated monocarboxylic acids, dicarboxylic acids and dicarboxylic acid anhydrides, and; (B) 20 to 80 % by weight at least one monomer from the group of aliphatic or aromatic monoolefins.

7. 发明授权

EP2175975B1 VERFAHREN ZUR HERSTELLUNG EINES RIESELFÄHIGEN UND LAGERSTABILEN FESTSTOFFES ENTHALTEND IM WESENTLICHEN ALPHA-ALANIN-N,N-DIESSIGSÄURE UND/ODER EIN ODER MEHRERE DERIVATE DER ALPHA-ALANIN-N,N-DIESSIGSÄURE 有权
标题翻译：用于生产和流动储存稳定的固体基本上包含α-丙氨酸-N，N-二和/或一种或多种α-丙氨酸-N，衍生物N-二
公开(公告)号：EP2175975B1
公开(公告)日：2012-06-20
申请号：EP08774531.1
申请日：2008-06-30
申请人： BASF SE
发明人： HEINZ, Robert , FLORE, Karin , KISSAU, Lars , HEIDENFELDER, Thomas , SEEBECK, Tanja , MRZENA, Frank
IPC分类号： B01J2/30 , C07C227/44 , C11D3/33 , C11D3/37 , B01J2/22 , C11D17/00 , C11D7/32
CPC分类号： C07C227/44 , B01J2/22 , B01J2/30 , C11D7/3245 , C11D17/0047 , C07C229/16
摘要： What is proposed is a process for producing a free-flowing and storage-stable solid comprising essentially a-alanine-N,N-diacetic acid and/or one or more derivatives of a-alanine-N,N-diacetic acid, proceeding from a powder of a-alanine-N,N-diacetic acid and/or one or more derivatives of a-alanine-N,N-diacetic acid, by a. compacting the powder of a-alanine-N,N-diacetic acid on a roller press to obtain slugs, b. crushing the slugs and c. screening the crushed slugs, which is characterized in that the compaction on the roller press is carried out with addition of polyethylene glycol having a melting point greater than 35°C.

8. 发明公开

EP1971675A1 MISCHPULVER ODER MISCHGRANULAT AUF BASIS VON GLUTAMINSÄURE-N,N-DIESSIGSÄURE UND IHREN SALZEN 有权
标题翻译：混合粉末或混合颗粒基于谷氨酸N，N-二及其盐的
公开(公告)号：EP1971675A1
公开(公告)日：2008-09-24
申请号：EP06841537.1
申请日：2006-12-21
申请人： BASF SE
发明人： SEEBECK, Tanja , KISSAU, Lars
IPC分类号： C11D3/33 , C11D1/66 , C11D1/72 , C11D3/37
CPC分类号： C11D1/66 , C11D1/72 , C11D3/33 , C11D3/3707 , C11D3/3753 , C11D3/3776
摘要： What is described is a mixed powder or mixed granule comprising at least 80% by weight of a mixture of (a) from 5 to 95% by weight of at least one glutamic acid-N,N-diacetic acid derivative of the general formula (I) MOOC-(CH2)2C(COOM)-N(CH2COOM)2 (I) where M is hydrogen, ammonium, alkali metal, (b) from 5 to 95% by weight of at least one polyethylene glycol or of at least one nonionic surfactant or of a mixture thereof or of a polymer selected from the group consisting of polyvinyl alcohols, polyvinylpyrrolidones (PVPs), polyalkylene glycols and derivatives thereof, processes for producing these mixed powders or mixed granules, the use of these mixed powders or mixed granules, and also a solid washing composition and a solid dishwasher detergent comprising the inventive mixed powder or mixed granule.

9. 发明公开

EP1924676A1 REINIGUNGSFORMULIERUNGEN FÜR DIE MASCHINELLE GESCHIRRREINIGUNG ENTHALTEND HYDROPHIL MODIFIZIERTE POLYCARBOXYLATE 有权
标题翻译： REINIGUNGSFORMULIERUNGENFÜRDIE MASCHINELLE GESCHIRRREINIGUNG ENTHALTEND亲水改性聚碳酸酯
公开(公告)号：EP1924676A1
公开(公告)日：2008-05-28
申请号：EP06793039.6
申请日：2006-08-29
申请人： BASF SE
发明人： SEEBECK, Tanja , TROPSCH, Jürgen , KISSAU, Lars
IPC分类号： C11D3/33 , C11D3/37
CPC分类号： C11D3/3757 , C11D3/33
摘要： The invention relates to a phosphate-free cleaning formulation for machine dishwashing comprising as components: a) 1 to 20% by weight of copolymers of a1) 50 to 99.5 mol% of a monoethylenically unsaturated monocarboxylic acid and/or of a salt thereof, a2) 0.5 to mol% of an alkoxylated monoethylenically unsaturated monomer of the formula (I), a3) 0 to 50 mol% of a monoethylenically unsaturated dicarboxylic acid, an anhydride and/or a salt thereof, a4) 0 to 20 mol% of a further copolymerizable monoethylenically unsaturated monomer, where the copolymer has an average molecular weight Mw of from 30 000 to 500 000 g/mol and a K value of from 40 to 150, measured at pH 7 in 1% strength by weight aqueous solution at 25°C, b) 1 to 50% by weight of complexing agents chosen from the group consisting of nitrilotriacetic acid, ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, hydroxyethylethylenediaminetriacetic acid and glycine-N,N-diacetic acid and derivatives thereof, glutamic acid-N,N-diacetic acid, iminodisuccinate, hydroxyiminodisuccinate, S,S-ethylenediaminedisuccinate and aspartic acid-diacetic acid, and the salts of the abovementioned substances, c) 1 to 15% by weight of low-foaming nonionic surfactants, d) 0.1 to 30% by weight of bleaches and optionally bleach activators, e) 0 to 60% by weight of further builders, f) 0 to 8% by weight of enzymes, g) O to 50% by weight of one or more further additives, where the sum of components a) to g) is 100% by weight.
摘要翻译：本发明涉及用于机械洗碗的无磷酸盐清洁制剂，其包含作为组分的组分：a）1至20重量％的a1）50至99.5摩尔％的单烯属不饱和单羧酸和/或其盐的共聚物，a2 ）0.5摩尔％式（I）的烷氧基化单烯属不饱和单体，a3）0-50摩尔％单烯属不饱和二羧酸，酸酐和/ 进一步可共聚的单烯属不饱和单体，其中共聚物的平均分子量M w为30000-500000g / mol和K值为40-150，在25℃下在1重量％浓度水溶液中在pH 7下测量 C）b）1至50重量％选自次氮基三乙酸，乙二胺四乙酸，二亚乙基三胺五乙酸，羟乙基乙二胺三乙酸和甘氨酸-N，N-二乙酸及其衍生物，谷氨酰胺 N，N-二乙酸，亚氨基二琥珀酸盐，羟基亚氨基二琥珀酸盐，S，S-乙二胺二琥珀酸盐和天冬氨酸二乙酸，以及上述物质的盐，c）1-15重量％低泡非离子表面活性剂，d ）0.1至30重量％的漂白剂和任选的漂白活化剂，e）0至60重量％的其他助洗剂，f）0至8重量％的酶，g）0至50重量％的一种或多种添加剂，其中组分a）至g）的总和为100重量％。

10. 发明公开

EP1924675A1 REINIGUNGSFORMULIERUNGEN FÜR DIE MASCHINELLE GESCHIRRREINIGUNG ENTHALTEND HYDROPHIL MODIFIZIERTE POLYCARBOXYLATE 有权
标题翻译：清洁制剂机器洗餐具含亲水性改性的羧酸盐
公开(公告)号：EP1924675A1
公开(公告)日：2008-05-28
申请号：EP06778368.8
申请日：2006-08-28
申请人： BASF SE
发明人： SEEBECK, Tanja , TROPSCH, Jürgen , KISSAU, Lars
IPC分类号： C11D3/33 , C11D3/37
CPC分类号： C11D3/3757 , C11D3/33
摘要： The invention relates to a phosphate-free cleaning formulation for machine dishwashing, comprising as components: a) 1 to 20% by weight of copolymers of a1) 50 to 93 mol% acrylic acid and/or of a water-soluble salt of acrylic acid, a2) 5 to 30 mol% of methacrylic acid and/or of a water-soluble salt of methacrylic acid and a3) 2 to 20 mol% of at least one nonionic monomer of the formula (I), b) 1 to 50% by weight of complexing agents chosen from the group consisting of glycine-N,N-diacetic acid derivatives and glutamic acid-N,N-diacetic acid and salts thereof, c) 1 to 15% by weight of low-foaming nonionic surfactants, d) 0 to 30% by weight of bleaches and optionally bleach activators, e) 0 to 60% by weight of further builders, f) 0 to 8% by weight of enzymes, g) 0 to 50% by weight of one or more further additives, such as anionic or zwitterionic surfactants, bleach catalysts, alkali carriers, corrosion inhibitors, antifoams, dyes, fragrances, fillers, organic solvents and water, where the sum of components a) to g) is 100% by weight.

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