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    • 8. 发明公开
    • SULFONIUM COMPOUNDS, THEIR PREPARATION AND USE
    • SULFONIUMVERBINDUNGEN,DEREN HERSTELLUNG UND VERWENDUNG
    • EP2838927A2
    • 2015-02-25
    • EP13716792.0
    • 2013-04-17
    • BASF SE
    • KUNIMOTO, KazuhikoKURA, Hisatoshi
    • C08G59/68C08L63/00G03F7/004C09D11/02C09D163/00
    • C08G59/62B05D3/007C07C309/08C07C309/10C07C2601/08C07C2601/14C07D307/10C07D309/08C07D333/46C08G59/4064C08L63/00C09D11/02C09D163/00C09J163/00G03F7/0045
    • Compounds of the formula (I), Ia or (Ib) wherein A
      1- and A
      - is for example (II) is 1 or 2; X is C
      1 -C
      4 alkylene or CO; Y is for example O, O(CO), O(CO)O, R
      1 is for example hydrogen, d-dsalkyl, C
      3 -C
      30 cycloalkyl, phenyl, naphthyl, anthracyl, phenanthryl, biphenylyl, fluorenyl or C
      3 -C
      20 heteroaryl, all of which optionally are substituted; R
      2 and R
      3 for example are C
      1 -C
      10 haloalkylene which is optionally substituted, or R
      2 and R
      3 are phenylene, which optionally is substituted; R
      4 is a group (A) or a group (B); R
      5 and R
      6 for example are C
      1 -C
      20 alkyl; or R
      4 and R
      5 or R
      4 and R
      6 together form a straight-chain C
      2 -C
      6 alkylene, R
      5 and R
      6 together form a straight-chain C
      2 -C
      6 alkylene; R
      7 , R
      8 , R
      9 and R
      10 ifor example are C
      1 -C
      20 alkyl; M for example is C
      1 -C
      20 alkylene, C
      2 -C
      20 alkenylene, C
      2 -C
      20 alkynylene; R
      25 and R
      26 are for example hydrogen, C
      1 -C
      20 alkyl; R
      27 , R
      28 , R
      29 , R
      30 and R
      31 are for example hydrogen, C
      1 -C
      20 alkyl, C
      2 -C
      20 alkenyl, C
      3 -C
      20 cycloalkyl, or two radicals R
      27 and R
      28 , R
      28 and R
      29 , R
      29 and R
      30 and/or R
      30 and R
      31 together form a straight-chain C
      2 -C
      6 alkylene, or R
      25 and R
      27 together form 1,2-phenylene, R
      33 and R
      34 for example are hydrogen, C
      1 -C
      20 alkyl; R
      35 , R
      36 and R
      37 for example are hydrogen, C
      1 -C
      20 alkyl; are suitable as thermo-acid generators.
    • 其中A1和A-为(II)的式(I),(Ia)或(Ib)的化合物为1或2; X是C 1 -C 4亚烷基或CO; Y是例如O,O(CO),O(CO)O,R 1是例如氢,d-二烷基,C 3 -C 30环烷基,苯基,萘基,蒽基,菲基,联苯基,芴基或C 3 -C 20杂芳基, 任选被取代; R 2和R 3例如是任选被取代的C 1 -C 10卤代亚烷基,或者R 2和R 3是任选被取代的亚苯基; R4是一组(A)或一组(B); R5和R6例如是C1-C20烷基; 或R 4和R 5或R 4和R 6一起形成直链C 2 -C 6亚烷基,R 5和R 6一起形成直链C 2 -C 6亚烷基; R 7,R 8,R 9和R 10如果为C 1 -C 20烷基; M例如是C 1 -C 20亚烷基,C 2 -C 20亚烯基,C 2 -C 20亚炔基; R 25和R 26是例如氢,C 1 -C 20烷基; R27,R28,R29,R30和R31是例如氢,C1-C20烷基,C2-C20链烯基,C3-C20环烷基或两个基团R27和R28,R28和R29,R29和R30和/或R30和R31共同形成直链 链C 2 -C 6亚烷基或R 25和R 27一起形成1,2-亚苯基,R 33和R 34例如是氢,C 1 -C 20烷基; R 35,R 36和R 37例如是氢,C 1 -C 20烷基; 适合作为热酸发生器使用。