会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 3. 发明授权
    • N-SUBSTITUTED IMIDES AS POLYMERIZATION INITIATORS
    • N-取代AS酰亚胺POLYMERISATIOSINITIATOREN
    • EP1828258B1
    • 2010-06-30
    • EP05815624.1
    • 2005-10-31
    • BASF SE
    • NESVADBA, PeterBENKHOFF, JohannesBUGNON, LuciennePOWELL, KarinJUNG, Tunja
    • C08F4/00C07C239/16C07D209/48C07D207/40C07D221/14
    • C07D207/404B33Y70/00C07D207/46C07D209/48C07D221/14C08F4/00
    • The invention relates to novel N-substituted imides and polymerizable compositions com¬ prising these N-substituted imides. The invention further relates to the use of N-substituted imides as polymerization initiators. The imides are compounds of the formula (I) and (II) wherein n is 1 or 2; m is 1 or 2; R1 and R2 are each, independently of one another, hydrogen, C1-C18alkyl, C1-C-18alkenyl C6-C14aryl, aralkyl, C5-C12cycloalkyl, each of which may be substituted by halogen, C1-C4-alkyl, hydroxy, C1-C6alkoxy, carbonyl, C1-C6alkoxycarbonyl; or R1 and R2 together with the adjacent -CO-N-CO- group may form a monocyclic, bicyclic or polycyclic ring, said ring having up to 50 non hydrogen atoms and wherein said ring may contain the structural element (formula III) more than once; R3 if n is 1, is C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, OR10 or SR11, NR12R13; wherein R3 if n is 2, is C2-C12alkylene, C6-C14arylene, xylylene R4 and R5, correspond to R1 and R2; R6 if n is 1, is hydrogen, C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, NR14R15; wherein R6 if n is 2, is C2-C12alkylene, C6-C14arylene, xylylene; R7 is hydrogen, C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, each of which may be substituted by halogen, C1-C4-alkyl, hydroxy, C1-C6alkoxy, carbonyl, C1-C6alkoxy- carbonyl; or R7 and R14 or R7 and R15 form together with the N-atom attached to R7 a 5- 6 membered ring, optionally interrupted by -NH-, -N(C1-C8alkyl)-, -O- and/or S-atoms.
    • 4. 发明公开
    • ALPHA-HYDROXYKETONES
    • α-羟基酮
    • EP2129659A1
    • 2009-12-09
    • EP08718154.1
    • 2008-03-25
    • BASF SE
    • DIETLIKER, KurtMURER, PeterHÜSLER, RinaldoJUNG, Tunja
    • C07D211/32C07D241/04C07C49/543C07C62/30C07C229/46C07F7/08
    • C07D211/32C07C49/83C07C49/835C07C49/84C07C62/38C07C69/757C07C219/12C07C235/82C07C2601/14C07D295/185C07D305/12C07F7/0836C07F7/0854C07F7/1868G03F7/004G03F7/38G03F7/40
    • Compounds of theFormula (I) wherein x is an integer from 1-4; p is an integer from 1-3; q is an integer from 0-3; Ar is phenyl, naphthyl, anthryl or phenanthryl each of which optionally is substituted by one or more Cl, CN, OR5, C3-C5alkenyl or C1-C6alkyl which optionally is substituted by one or more OR6, COOR or halogen; R1ifx is 1, is OR7, O- X+, NR8R9, C1-C20alkyl optionally substituted by one or more COOR10, or is C2-C20alkyl interrupted by one ore more O, or is C2-C5alkenyl or phenyl-C1-C4alkyl; R1ifx is 2, is for example C1-C20alkylene; R1ifx is 3, is for example a tri- valent radical; R1if x is 4, is for example a tetravalent radical; R2and R3are hydrogen or C1- C8alkyl, or R2and R3together are O, C1-C3alkylene or CH=CH; R4 is C1-C4alkyl; R5, R6, R7, R8, R9 and R10 are for example hydrogen or C1-C4alkyl; and X is a x-valent cationic counter ion; are in particular suitable as photoinitiators forthe curing with UV-A light (320-450 nm).
    • 式(I)的化合物,其中x是1-4的整数; p是1-3的整数; q是0-3的整数; Ar是苯基,萘基,蒽基或菲基,其各自任选被一个或多个被一个或多个OR 6,COOR或卤素取代的C 1,CN,OR 5,C 3 -C 5链烯基或C 1 -C 6烷基取代; R 1如果x是1,是OR 7,O-X +,NR 8 R 9,任选被一个或多个COOR 10取代的C 1 -C 20烷基,或者是被一个或多个O取代的C 2 -C 20烷基,或者是C 2 -C 5烯基或苯基-C 1 -C 4烷基; R1如果x为2,例如为C 1 -C 20亚烷基; R1如果x为3,则为例如三价基团; R1如果x为4,则为例如四价基团; R 2和R 3是氢或C 1 -C 8烷基,或者R 2和R 3一起是O,C 1 -C 3亚烷基或CH = CH; R4是C1-C4烷基; R 5,R 6,R 7,R 8,R 9和R 10例如为氢或C 1 -C 4烷基; X为x价阳离子抗衡离子; 特别适用于用UV-A光(320-450nm)固化的光引发剂。