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    • 9. 发明公开
    • AMPHIPHILE POLYMERZUSAMMENSETZUNGEN UND IHRE VERWENDUNG
    • EP1756188A1
    • 2007-02-28
    • EP05748294.5
    • 2005-06-07
    • BASF Aktiengesellschaft
    • OETTER, GünterKRÜGER, ChristianKÖHLE, HaraldSCHERER, MariaWAGNER, NorbertBRATZ, MatthiasBERGHAUS, RainerVAN GELDER, Richard
    • C08G18/62C08G18/28C08G18/78C08G18/75
    • A01N25/04A01N25/30C08G18/283C08G18/3876C08G18/7831C08L33/06C08L75/04A01N47/24A01N43/653A01N43/40A01N53/00C08L2666/04
    • The invention relates to amphiphilic polymer compositions, to a method for their production and to their use for producing aqueous active ingredient compositions of water-insoluble active ingredients, in particular active ingredients for crop protection. The amphiphilic polymer compositions are obtained by reacting a) at least one hydrophobic polymer P1, which carries functional groups R1 that are reactive in relation to isocyanate groups and which is composed of ethylenically unsaturated monomers M1, comprising: a1) at least 10 wt. %, (in relation to the total quantity of the monomers M1), of monomers M1a of general formula (I), in which X represents oxygen or an N-R4 group; R1, R2, R3, and R4 are defined as cited in the claims and the description; a2) up to 90 wt. %, (in relation to the total quantity of the monomers M1) of neutral, monoethylenically unsaturated monomers M1b, whose solubility in water at 25 °C is less than 50 g/l and which differ from the monomers M1a; and a3) up to 30 wt. %, (in relation to the total quantity of the monomers M1, of ethylenically unsaturated monomers M1c, which differ from the monomers M1a and M1b, b) at least one hydrophilic polymer P2, which carries functional groups R2 that are reactive in relation to isocyanate groups, c) with at least one compound V, which has a functionality of at least 1.5 in relation to the isocyanate groups.
    • 本发明涉及两亲聚合物组合物,其制备方法及其用于制备水不溶性活性成分,特别是用于保护作物的活性成分的水性活性成分组合物。 两亲聚合物组合物通过以下反应获得:a)至少一种带有官能团R1的疏水性聚合物P1,所述官能团R1相对于异氰酸酯基团是反应性的并且由烯属不饱和单体M1组成,其包含:a1)至少10wt。 (其中X代表氧或N-R4基团)的通式(I)的单体M1a(相对于单体M1的总量) R1,R2,R3和R4如权利要求和描述中所定义; a2)高达90wt。 %(相对于单体M1的总量)中性单烯属不饱和单体M1b,其在25℃下在水中的溶解度小于50g / l并且不同于单体M1a; 和a3)高达30wt。 (相对于不同于单体M1a和M1b的烯属不饱和单体M1c的总量),b)至少一种亲水性聚合物P2,其带有相对于异氰酸酯呈反应性的官能团R2 基团,c)与至少一种化合物V反应,所述化合物V相对于异氰酸酯基团具有至少1.5的官能度。