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1. 发明公开

EP1404444A2 VERFAHREN ZUR HERSTELLUNG VON CYCLOALIPHATISCHEN VERBINDUNGEN, DIE SEITENKETTEN MIT EPOXIDGRUPPEN AUFWEISEN, DURCH HYDRIERUNG AN RU/SIO2 KATALYSATOREN 审中-公开
标题翻译： PROCESS FOR侧链一种产生脂环族化合物与环氧EXHIBIT加氢ON RU / SiO2催化剂
公开(公告)号：EP1404444A2
公开(公告)日：2004-04-07
申请号：EP02758224.6
申请日：2002-06-10
申请人： BASF AKTIENGESELLSCHAFT , Böttcher, Arnd
发明人： BÖTTCHER, Arnd , VANOPPEN, Dominic , ARNDT, Jan-Dirk
IPC分类号： B01J23/46 , B01J37/18 , C07D303/02 , C07C5/10
CPC分类号： B01J37/18 , B01J21/08 , B01J23/462 , C07D303/30 , C08G59/1405 , C08G59/24
摘要： A method for the production of cycloaliphatic compounds (I) having side chains with expoxy groups by heterogenous-catalytic hydrogenation of a compound (II) having at least one carbocyclic, aromatic group and at least one side chain with at least one epoxy group, on a ruthenium catalyst, characterized in that the ruthenium catalyst is obtained by i) single or multiple treatment of an amorphous silicon dioxide based carrier material with a halogen-free aqueous solution of a low-molecular ruthenium compound and subsequent drying of the treated carrier material at a temperature of less than 200° C, ii) reduction of the solid obtained in I) with hydrogen at a temperature ranging from 100 to 350° C, wherein step ii) is carried out directly after step i).

2. 发明公开

EP1412082A1 VERFAHREN ZUR HYDRIERUNG ORGANISCHER VERBINDUNGEN UNTER VERWENDUNG VON RU/SIO2 KATALYSATOREN 审中-公开
标题翻译：工艺用于有机化合物的加氢将Ru / SiO2催化剂
公开(公告)号：EP1412082A1
公开(公告)日：2004-04-28
申请号：EP02740699.0
申请日：2002-06-07
申请人： BASF Aktiengesellschaft
发明人： BÖTTCHER, Arnd , VANOPPEN, Dominic , ARNDT, Jan-Dirk , HENKELMANN, Jochem , KNOLL, Konrad
IPC分类号： B01J23/46 , B01J37/18 , C07C5/10 , C07C29/136 , C07C51/36
CPC分类号： C07D295/023 , B01J21/08 , B01J23/462 , B01J37/18 , C07B2200/09 , C07C5/10 , C07C29/141 , C07C29/172 , C07C29/19 , C07C29/20 , C07C51/36 , C07C209/48 , C07C209/72 , C07C2523/46 , C07C2601/14 , C08F8/04 , C07C13/18 , C07C211/03 , C07C211/11 , C07C211/35 , C07C211/36 , C07C31/12 , C07C31/20 , C07C35/08 , C07C35/21 , C07C31/1355 , C07C29/175
摘要： The invention relates to a method for hydrogenating at least one organic compound by bringing said organic compound into contact with a gas containing hydrogen in the presence of a catalyst. Said catalyst comprises ruthenium as an active metal, either alone or combined with another metal of the subgroups I, VII or VIII of the periodic table, deposited on an amorphous silicon dioxide-based support. Said catalyst is obtained by i): treating the amorphous silicon dioxide-based support with a halogen-free aqueous solution of a low-molecular ruthenium compound, and subsequently drying the treated support at a temperature of less than 200 °C, ii) reducing the solid matter obtained in i) with hydrogen at a temperature ranging from 100 to 350 °C, wherein step ii) is carried out directly after step i).
摘要翻译：有机化合物（S）（I）的氢化包括使（I）在催化剂（a）含有钌，通过至少一次地被卤素无定形二氧化硅为基础的载体材料的处理，得到的存在下，含气体的氢低分子钌化合物并干燥和立即减少所获得的固体用氢的自由wässrige溶液。有机化合物（S）（I）的氢化包括使（I）在催化剂（A）的存在下，含气体的氢含有治疗以获得钌和任选的其它组I，VII或VIII族过渡金属（S）非晶二氧化硅为基础的载体材料与在低于200℃的低分子量钌化合物和干燥的不含卤素的wässrige溶液，并立即降低所获得的固体用氢气在100-350℃下至少一次

3. 发明公开

EP1699557A1 RUTHENIUM-HETEROGENKATALYSATOR, VERFAHREN ZUR HYDRIERUNG EINER CARBOCYCLISCHEN AROMATISCHEN GRUPPE UND KERNHYDRIERTE BISGLYCIDYLETHER DER BISPHENOLE A UND F 审中-公开
标题翻译：钌的非均相催化剂，PROCESS FOR加氢的碳环芳族基团和环的氢化双酚A和F的二缩水甘油醚
公开(公告)号：EP1699557A1
公开(公告)日：2006-09-13
申请号：EP04804056.2
申请日：2004-12-18
申请人： BASF Aktiengesellschaft
发明人： ARNDT, Jan-Dirk , VAN LAAR, Frederik , BECKER, Michael
IPC分类号： B01J23/46 , B01J37/18 , C07D303/30 , C08G59/24 , B01J21/08 , B01J23/58
CPC分类号： B01J23/462 , B01J21/08 , B01J23/58 , B01J35/10 , B01J35/1019 , B01J35/1047 , B01J35/1061 , C07D303/30 , C08G59/1405
摘要： Disclosed are a heterogeneous ruthenium catalyst containing silicon oxide as a carrier material, the catalyst surface comprising alkaline earth metal ions (M2+), methods for hydrogenating a carbocyclic aromatic group to the corresponding carbocyclic aliphatic group, particularly a method for producing diglycidyl ether of formula (I), wherein R represents CH3 or H, by hydrogenating the nucleus of the corresponding aromatic diglycidyl ether of formula (II), in which said heterogeneous ruthenium catalyst is used, and diglycidyl ether of formula (I) that is produced according to the inventive method.

4. 发明公开

EP1529024A1 VERFAHREN ZUR HERSTELLUNG VON ACETYLENALKOHOLEN 审中-公开
公开(公告)号：EP1529024A1
公开(公告)日：2005-05-11
申请号：EP03792224.2
申请日：2003-07-23
申请人： BASF AKTIENGESELLSCHAFT
发明人： HENKELMANN, Jochem , KINDLER, Alois , ARNDT, Jan-Dirk , KLASS, Katrin
IPC分类号： C07C29/42
CPC分类号： C07C29/42 , C07C403/08 , C07C2601/16 , C07C33/042 , C07C33/048 , C07C33/14 , C07C33/48
摘要： The invention relates to a method for producing acetylene alcohols of general formula (I), wherein R1, R2 can independently be identical or different and represent optionally substituted hydrogen, an optionally substituted saturated, monounsaturated or polyunsaturated C1-C30 alkyl radical, aryl radical, cycloalkylalkyl radical, or cycloalkyl radical, or a group of general formula (II), wherein R3, R4 can independently be identical or different and represent optionally substituted hydrogen or an optionally substituted saturated, monounsaturated, or polyunsaturated C1-C30 alkyl radical, aryl radical, cycloalkylalkyl radical, or cycloalkyl radical while the dashed line can represent an additional double bond. Said acetylene alcohols are produced by monoethynylating a ketone of general formula R1-CO-R2 by (a) reacting lithium with a C1-C10 alkyl halide, (b) introducing acetylene gas, and (c) adding the ketone.
摘要翻译：一种通过酮的单乙炔化生产乙炔醇的方法，包括：（a）锂与1-10C烷基卤的反应; （b）引入乙炔气; 和（c）加入酮。通过式R1-CO-R2酮的单炔化反应制备式（I）炔炔醇的方法，包括：（a）锂与1-10C烷基卤的反应，（b）引入乙炔气和（c）加入酮。与C-CR1R2-OH（I）R1，R2 = H或任选不饱和的1-30C烷基，芳基，环烷基烷基或环烷基（全部被取代的）或式-CH2CH2CHR3R4或-CH2CH = CR3R4基团相当; 和R 3，R 4 = H或任选不饱和的，任选取代的1-30C烷基，芳基，环烷基烷基或环烷基。

5. 发明公开

EP1703973A1 RUTHENIUM-HETEROGENKATALYSATOR, KERNHYDRIERTE BISGLYCIDYLETHER DER BISPHENOLE A UND F UND VERFAHREN ZU IHRER HERSTELLUNG 审中-公开
标题翻译：钌的非均相催化剂，双酚A的环氢化双缩水甘油醚及F AND METHOD FOR PRODUCING
公开(公告)号：EP1703973A1
公开(公告)日：2006-09-27
申请号：EP04804055.4
申请日：2004-12-18
申请人： BASF Aktiengesellschaft
发明人： ARNDT, Jan-Dirk , VAN LAAR, Frederik , BECKER, Michael , HERWIG, Stephan
IPC分类号： B01J23/46 , B01J37/18 , C07D303/30 , C08G59/24 , B01J21/08
CPC分类号： C07D303/28 , B01J21/08 , B01J23/462 , B01J23/58 , B01J33/00 , B01J35/002 , B01J35/006 , B01J35/008 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1047 , B01J35/1061 , B01J37/14 , C07D303/30 , C08G59/24
摘要： Disclosed are a heterogeneous ruthenium catalyst containing silicon oxide as a carrier material, the ratio Q2/Q3 between Q2 structures and Q3 structures in the silicon oxide, which is determined using 29Si solid-state NMR, being less than 25, a method for the production of a diglycidyl ether of formula (I), wherein R represents CH3 or H, by hydrogenating the nucleus of the corresponding aromatic diglycidyl ether of formula (II) using the inventive heterogeneous ruthenium catalyst, as well as diglycidyl ether of formula (I) produced according to said method.

6. 发明公开

EP1412083A2 VERFAHREN ZUR HERSTELLUNG VON SORBIT DURCH HYDRIERUNG GEEIGNETER MONO- UND DISACCHARIDE AN EINEM RU/SIO2-KATALYSATOR 有权
标题翻译：生产由SORBITOL氢化的单糖AT A RU / SiO2催化剂
公开(公告)号：EP1412083A2
公开(公告)日：2004-04-28
申请号：EP02747366.9
申请日：2002-06-10
申请人： BASF AKTIENGESELLSCHAFT
发明人： VANOPPEN, Dominic , MAAS-BRUNNER, Melanie , KAMMEL, Ulrich , ARNDT, Jan-Dirk
IPC分类号： B01J23/46 , B01J37/18 , C07C31/26 , C07C29/141
CPC分类号： B01J23/462 , B01J21/08 , B01J35/1019 , B01J35/1023 , B01J37/18 , C07C29/132 , C07C31/26
摘要： The invention relates to a method for the production of sorbit by catalytic hydrogenation of a monosaccharide forming sorbit during said hydrogenation in a liquid phase, characterized in that the catalyst is obtained by 1) single or multiple treatment of an amorphous silicon dioxide based carrier material with a halogen-free aqueous solution of a low-molecular ruthenium compound and subsequent drying of the treated carrier material at a temperature of less than 200° C, ii) reduction of the solid obtained in I) with hydrogen at a temperature ranging from 100 to 350° C, wherein step ii) is carried out directly after step i).

7. 发明公开

EP1399255A2 RUTHENIUM-KATALYSATOREN AUF EINEM TRÄGER AUF SIO2-BASIS FÜR DIE KATALYTISCHE HYDRIERUNG VON SACCHARIDEN 有权
标题翻译：糖类到钌催化剂的催化加氢反应在SiO 2载体
公开(公告)号：EP1399255A2
公开(公告)日：2004-03-24
申请号：EP02748756.0
申请日：2002-06-10
申请人： BASF AKTIENGESELLSCHAFT
发明人： VANOPPEN, Dominic , MAAS-BRUNNER, Melanie , KAMMEL, Ulrich , ARNDT, Jan-Dirk
IPC分类号： B01J23/46 , B01J37/18 , C07C31/26 , C07C29/141
CPC分类号： C07C29/132 , B01J21/08 , B01J23/462 , B01J35/0013 , B01J35/002 , B01J35/006 , B01J35/1009 , B01J35/1014 , B01J35/1023 , B01J35/1042 , B01J37/0201 , B01J37/18 , C07C31/26 , C07C31/18
摘要： The invention relates to novel ruthenium catalysts which can be obtained by: 1) single or multiple treatment of an amorphous silicon-dioxide-based carrier material with a halogen-free aqueous solution of a low-molecular ruthenium compound and subsequent drying of the treated carrier material at a temperature of less than 200° C, ii) reduction of the solid obtained in I) with hydrogen at a temperature ranging from 100 to 350° C, wherein step ii) is carried out directly after step i). The invention also relates to a method for the production and use thereof in catalytic hydrogenation of monosaccharides and disaccharides for the production of sugar alcohols with the exception of sorbit.

8. 发明公开

EP1373277A1 METALLORGANISCHE GERÜSMATERIALIEN UND VERFAHREN ZU DEREN HERSTELLUNG 有权
标题翻译：有机金属骨架材料和方法及其
公开(公告)号：EP1373277A1
公开(公告)日：2004-01-02
申请号：EP02727373.9
申请日：2002-03-07
申请人： BASF AKTIENGESELLSCHAFT
发明人： MÜLLER, Ulrich , HESSE, Michael , LOBREE, Lisa , HÖLZLE, Markus , ARNDT, Jan-Dirk , RUDOLF, Peter
IPC分类号： C07F1/08 , C07F3/06 , C07F19/00 , B01J31/22
CPC分类号： C07F19/005 , B01J20/226 , B01J31/0237 , B01J31/0247 , B01J31/1691 , B01J31/2239 , B01J35/1057 , B01J2231/32 , B01J2531/26 , C07F1/08 , C07F3/06
摘要： The invention relates to a method for producing an organometallic building material, comprising reacting, in the presence of a base and a solvent, a fluid mixture that contains a metal salt having at least one bidentate organic compound capable of coordination with metal ions, said solvent containing at least one cyclic amide (lactam) and/or at least one cyclic ester (lactone).

9. 发明公开

EP1572607A1 KONTINUIERLICHES VERFAHREN ZUR HERSTELLUNG VON ZUCKERALKOHOLEN 审中-公开
标题翻译：连续工艺，糖醇生产
公开(公告)号：EP1572607A1
公开(公告)日：2005-09-14
申请号：EP03780110.7
申请日：2003-12-03
申请人： BASF Aktiengesellschaft
发明人： ARNDT, Jan-Dirk , KLASS, Katrin , VAN LAAR, Frederik , HERWIG, Stephan , HENKELMANN, Jochem
IPC分类号： C07C29/141 , C07C31/18 , C07C31/26 , B01J23/46
CPC分类号： B01J37/18 , B01J21/08 , B01J23/462 , B01J33/00 , C07C29/132 , C07C31/26
摘要： The invention relates to a continuous method for the production of sugar alcohols by catalytic hydrogenation of an aqueous solution of a saccharide, which forms the corresponding sugar alcohol on hydrogenation, on a ruthenium catalyst which may be obtained by: i) a single or multiple treatment of a support material made from amorphous silicon dioxide with a halogen free aqueous solution of a low molecular weight ruthenium compound and subsequent drying of the treated support material at a temperature below 200 °C, ii) reduction of the solid obtained in step i) with hydrogen at a temperature in the range 100 to 350 °C, whereby step ii) is carried out directly after step i). The aqueous saccharide solution is brought into contact with the support material before the hydrogenation.

10. 发明公开

EP1404730A1 KERNHYDRIERTE BLOCKCOPOLYMERE MIT ASSYMETRISCHEM AUFBAU 有权
标题翻译：具有ASSYMETRISCHEM施工环氢化的嵌段共聚物
公开(公告)号：EP1404730A1
公开(公告)日：2004-04-07
申请号：EP02771644.8
申请日：2002-05-14
申请人： BASF AKTIENGESELLSCHAFT
发明人： KNOLL, Konrad , BÖTTCHER, Arnd , ISHAQUE, Michael , OSSWALD, Friederike , ARNDT, Jan-Dirk
IPC分类号： C08F297/04 , C08F8/04 , C08L53/02 , C08L25/06
CPC分类号： C08F8/04 , C08F297/04 , C08L23/26 , C08L25/06 , C08L53/02 , C08L2666/24 , C08L2666/04
摘要： The invention relates to core-hydrogenated block copolymers comprised of vinyl aromatic monomers and dienes having at least two blocks S, which are of different molecular weights and are comprised of vinyl aromatic monomers. The invention also relates to mixtures containing core-hydrogenated polystyrene and to methods for the production thereof.

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