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    • 2. 发明公开
    • SUBSTITUIERTE 4-BENZOYL-PYRAZOLE
    • SUBSTITUIERTE 4-苯甲酰基 - 吡唑
    • EP0984962A1
    • 2000-03-15
    • EP98922797.0
    • 1998-05-04
    • BASF AKTIENGESELLSCHAFT
    • ENGEL, StefanBAUMANN, ErnstVON DEYN, WolfgangHILL, Regina, LuiseKARDORFF, UweMAYER, GuidoOTTEN, MartinaRHEINHEIMER, JoachimWAGNER, OliverWITSCHEL, MatthiasMISSLITZ, UlfWALTER, HelmutWESTPHALEN, Karl-Otto
    • C07D405/10A01N43/56C07D493/04C07D303/38C07D305/06
    • C07D405/10C07D493/04
    • 4-benzoyl-pyrazoles having the formula (I) are disclosed, in which the substituents have the following meanings: R1, R2 stand for hydrogen, mercapto, nitro, halogen, cyano, rhodano, C¿1?-C6-alkyl, halogenated C1-C6-alkyl, C1-C6-alkoxy, C2-C6-alkenyl, C2-C6-alkinyl, -OR?10, -OCOR10¿, -OSO¿2R?10, -S(O)¿n?R?10, -SO¿2OR10, -SO2NR?3OR10, -NR10SO¿2R?10 or -NR10¿COR; Q stands for a pyrazol linked at position 4 and having formula (II), in which R11 stands for C¿1?-C6-alkyl, halogenated C1-C6-alkyl, phenyl or phenyl which is partially or entirely halogenated and/or bears one to three of the following radicals: nitro, cyano, C1-C4-alkyl, halogenated C1-C4-alkyl, C1-C4-alkoxy, halogenated C1-C4-alkoxy; R?12¿ stands for hydrogen, C¿1?-C6-alkyl, halogenated C1-C6-alkyl, C1-C6-alkylcarbonyl, halogenated C1-C6-alkylcarbonyl, C1-C6-alkoxycarbonyl, C1-C6-alkylsulfonyl, halogenated C1-C6-alkylsulfonyl, phenylcarbonyl, phenylcarbonylmethyl, phenoxycarbonyl or phenylsulfonyl, the last four substituents being unsubstituted or the phenyl ring being partially or entirely halogenated and/or bearing one to three of the following radicals: nitro, cyano, C1-C4-alkyl, halogenated C1-C4-alkyl, C1-C4-alkoxy, halogenated C1-C4-alkoxy; R?13¿ stands for hydrogen, C¿1?-C6-alkyl or halogenated C1-C6-alkyl; A stands for a group of formulas (IIIa), (IIIb) or (IV), in which the substituents have the meanings indicated in the first claim. Also disclosed are the salts of these compounds useful in agriculture.
    • 公开了具有式(I)的4-苯甲酰基吡唑,其中取代基具有以下含义:R 1,R 2代表氢,巯基,硝基,卤素,氰基,rhodano,C 1 -C 6烷基,卤代 C 1 -C 6烷基,C 1 -C 6烷氧基,C 2 -C 6烯基,C 2 -C 6炔基,-OR 10,-OCOR 10,-OSO 2 R 10,-S(O) 10,-SO 2 OR 10,-SO 2 NR 3 OR 10,-NR 10 SO 2 R 10或-NR 10 COR; Q代表在4位连接且具有式(II)的吡唑,其中R 11代表部分或完全被卤代的C 1 -C 6烷基,卤代C 1 -C 6烷基,苯基或苯基和/或 硝基,氰基,C 1 -C 4烷基,卤代C 1 -C 4烷基,C 1 -C 4烷氧基,卤代C 1 -C 4烷氧基; R 12代表氢,C 1 -C 6烷基,卤代C 1 -C 6烷基,C 1 -C 6烷基羰基,卤代C 1 -C 6烷基羰基,C 1 -C 6烷氧基羰基,C 1 -C 6烷基磺酰基,卤代 C1-C6-烷基磺酰基,苯基羰基,苯基羰基甲基,苯氧基羰基或苯基磺酰基,最后四个取代基是未取代的或苯环部分或完全被卤代和/或带有1-3个下列基团:硝基,氰基,C1- ,卤代C 1 -C 4烷基,C 1 -C 4烷氧基,卤代C 1 -C 4烷氧基; R 13代表氢,C 1 -C 6烷基或卤代C 1 -C 6烷基; A代表式(IIIa),(IIIb)或(IV)的基团,其中取代基具有第一项权利要求中所示的含义。 还公开了用于农业的这些化合物的盐。
    • 6. 发明公开
    • SUBSTITUIERTE 2-BENZOYL-CYCLOHEXAN-1,3-DIONE MIT HERBIZIDER WIRKUNG
    • 替代二-2-苯甲酰基环己烷-1,3二酮麻醉剂治疗剂WIRKUNG
    • EP0958276A1
    • 1999-11-24
    • EP97953895.0
    • 1997-12-19
    • BASF AKTIENGESELLSCHAFT
    • HILL, Regina, LuiseKARDORFF, UweRACK, MichaelBAUMANN, ErnstVON DEYN, WolfgangENGEL, StefanMAYER, GuidoOTTEN, MartinaRHEINHEIMER, JoachimWITSCHEL, MatthiasMISSLITZ, UlfWALTER, HelmutWESTPHALEN, Karl-Otto
    • C07D333A01N35A01N37A01N41C07C251C07C257C07C259C07C317
    • A01N41/10A01N35/10A01N37/52C07C251/48C07C259/10C07C317/32C07C317/44C07C2601/16
    • The invention concerns 2-benzoyl-cyclohexan-1,3-diones of formula (I), in which R1, R2 stand for hydrogen, nitro, halogen, cyano, rhodano, alkyl, halogen alkyl, alkoxyalkyl, alkenyl, alkinyl, -OR?5, -OCOR6¿, -OSO¿2R?6, -SH, -S(O)¿n?R?7, -SO¿2OR5, -SO2NR?5R8, -NR8SO¿2R?6 or -NR8COR6; R3¿ stands for hydrogen, cyano, alkyl, halogen alkyl, -OR?7, -SR7 or -NR7R10; R4¿ stands for hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkinyl, -COR9, -CO2R?9, -COSR9¿ or -CONR8R9; X stands for oxygen or NR8; n equals 0, 1 or 2; R5 stands for hydrogen, alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R6 stands for alkyl or halogen alkyl; R7 stands for alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R8 stands for hydrogen or alkyl; R9 stands for alkyl, alkenyl, alkinyl, phenyl or benzyl; R10 stands for alkyl, halogen alkyl, alkenyl or alkinyl; Q stands for an optionally substituted cyclohexan-1,3-dione ring linked in position 2. Also disclosed are the salts of these compounds useful in agriculture; processes and intermediate products for preparing the compounds of formula (I), agents containing the same and the use of these derivatives or agents containing the same for controlling undesirable plants.
    • 本发明涉及式I的2-苯甲酰基环己烷-1,3-二酮,其中R1,R2各自为氢,硝基,卤素,氰基,氰硫基,烷基,卤代烷基,烷氧基烷基,烯基,炔基,-OR5,-OCOR6,-OSO2R6, -SH,-S(O)nR7,-SO2OR5,-SO2NR5R8,-NR8SO2R6或-NR8COR6; R3是氢,氰基,烷基,卤代烷基,-OR7,-SR7或-NR7R10; R4是氢,取代或未取代的烷基, 环烷基,烯基,环烯基,炔基,-COR 9,-CO 2 R 9,-COSR 9或-CONR 8 R 9; X是氧或NR 8; n是0,1或2; R 5是氢,烷基,卤代烷基,烷氧基烷基,烯基或炔基; 烷基或卤代烷基; R 7是烷基,卤代烷基,烷氧基烷基,烯基或炔基; R 8是氢或烷基; R 9是烷基,烯基,炔基,苯基或苄基; R 10是烷基,卤代烷基,链烯基或炔基; Q是环己烷-1 具有或不具有取代基的2-二酮环,其位置2;及其农业上有用的盐;制备式I化合物的方法和中间体; 包含它们的组合物; 以及使用这些衍生物或包含它们的组合物来控制不期望的植物。