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    • 9. 发明公开
    • VERFAHREN ZUR HERSTELLUNG VON ALDEHYDEN
    • EP1047655A1
    • 2000-11-02
    • EP99904776.4
    • 1999-01-14
    • BASF AKTIENGESELLSCHAFT
    • GEISSLER, BernhardRÖPER, MichaelZELLER, EdgarPACIELLO, RoccoDECKER, JürgenVOSS, HartwigMAHR, Norbert
    • C07C45/50C07C29/16B01J31/20B01J31/18
    • C08G73/0206B01J31/1658B01J31/1805B01J2231/321B01J2531/80B01J2531/822C07C45/50Y02P20/584C07C47/02
    • The invention relates to a method for the production of aldehydes or aldehydes and alcohols by hydroformylation of olefins in the presence of a complexing catalyst homogeneously dissolved in a reaction mixture, containing a metal of Group VIIIa of the periodic table of the elements and a phosphorus-free, polydentate nitrogen compound suitable for complex formation as ligand at temperatures ranging from 50 to 100 °C and pressures from 20 to 1,000 bar and recirculating the catalyst complex in the hydroformylation reaction, wherein a) derivatized polyamines are used that are substantially non-water soluble and suitable for complex formation and have a mean molecular weight of more than 1,000 Dalton and at least 10 nitrogen atoms; b) the catalyst complex remaining in the bottom of the distillation column and the excess ligands obtained from the reaction mixture are recirculated totally or partially in the hydroformylation once the hydroformylation reaction and the separation or partial separation by distillation of the aldehydes and the alcohols has been completed; c) continuos or at least batchwise evacuation of at least part of the high boiler from the bottom of the distillation of the reaction mixture is then carried out.
    • 本发明涉及一种在均匀溶解在反应混合物中的络合催化剂存在下通过烯烃的加氢甲酰化生产醛或醛和醇的方法,该反应混合物含有元素周期表的第VIIIa族金属和磷 - 所述多齿氮化合物适合于在50-100℃和20-1,000巴的压力下将配合物形成配位体并在羰基化反应中再循环所述催化剂配合物,其中a)使用基本上非水的衍生多胺 可溶且适于复合物形成并具有超过1,000道尔顿的平均分子量和至少10个氮原子; b)一旦加氢甲酰化反应和醛和醇的蒸馏分离或部分分离,残留在蒸馏塔底部的催化剂配合物和从反应混合物获得的过量配体在加氢甲酰化中全部或部分再循环 完成; c)然后进行从反应混合物的蒸馏的底部连续或至少分批地排出至少部分高沸点化合物。