会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 9. 发明公开
    • Olefin polymerization catalyst having a multidentate ligand
    • 具有多齿配体的烯烃聚合催化剂
    • EP0617052A3
    • 1995-04-12
    • EP94200736.0
    • 1994-03-22
    • Asahi Kasei Kogyo Kabushiki Kaisha
    • Aoki, ToshiyaKaneshima, Tokitaka
    • C08F4/52C08F4/602C08F10/00
    • C08F10/00C08F4/6192C08F4/659C08F4/65912C08F4/6592C08F210/16C08F2420/02C08F2420/05C08F4/64058C08F210/14C08F2500/03C08F2500/01C08F2500/07C08F4/64089C08F4/64044
    • Disclosed is an olefin polymerization catalyst comprising a transition metal selected from metals of Groups IIIA including the lanthanide series, IVA, VA, VIA, VIIA and VIII of the Periodic Table of the Elements, and ligands L¹ and L² bonded thereto, wherein a combination of L¹ and L² is (1) a combination of ligand L¹ which is a group containing at least one phosphorus-containing group and ligand L² which is a ligand having a σ-bond, or a ligand having a σ-bond and a bond selected from at least one π-bond and at least one lone electron pair donative bond; (2) a combination of ligand L¹ which is a 5-membered heterocyclic pentadentate ligand having one or more heteroatoms and ligand L² which is a ligand having a σ-bond, or a ligand having a σ-bond and a bond selected from at least one π-bond and at least one lone electron pair donative bond, provided that when the pentadentate ligand contains only one heteroatom, L² is a ligand having a σ-bond, or a ligand having a σ-bond and at least one lone electron pair donative bond; and (3) a combination of ligand L¹ which is a trispyrazolyl tridentate ligand and ligand L² which is an alkapolyenyl ligand, and wherein each L¹ contains an element of Group VB or Group VIB. The catalyst of the present invention has extremely high catalytic activity for an olefin polymerization reaction as compared to conventional olefin polymerization catalysts.
    • 本发明公开了一种烯烃聚合催化剂,其包含选自元素周期表的镧系,IVA,VA,VIA,VIIA和VIII族的IIIA族金属和与其键合的配体L 1和L 2的过渡金属,其中 L 1和L 2是(1)作为含有至少一个含磷基团的基团的配体L 1和作为具有σ-键的配体的配体L 2的组合,或者是具有σ键和选自 至少一个π键和至少一个孤电子对供体键; (2)作为具有一个或多个杂原子的五元杂环五齿配位体的配位体L 1和具有σ-键的配体的配位体L 2或具有σ-键和至少选自至少一个选自 一个π键和至少一个孤电子对供体键,条件是当五齿配体仅含有一个杂原子时,L 2是具有σ-键的配体或具有σ-键和至少一个孤电子对的配体 捐赠债券; 和(3)作为三吡唑基三齿配体的配体L 1和作为链多烯基配体的配体L 2的组合,并且其中每个L 1含有VB族或VIB族的元素。 与常规烯烃聚合催化剂相比,本发明的催化剂对烯烃聚合反应具有极高的催化活性。
    • 10. 发明公开
    • Olefin polymerization catalyst having a multidentate ligand
    • 烯烃聚合物催化剂mitmehrzähnigem配体。
    • EP0617052A2
    • 1994-09-28
    • EP94200736.0
    • 1994-03-22
    • Asahi Kasei Kogyo Kabushiki Kaisha
    • Aoki, ToshiyaKaneshima, Tokitaka
    • C08F4/52C08F4/602C08F10/00
    • C08F10/00C08F4/6192C08F4/659C08F4/65912C08F4/6592C08F210/16C08F2420/02C08F2420/05C08F4/64058C08F210/14C08F2500/03C08F2500/01C08F2500/07C08F4/64089C08F4/64044
    • Disclosed is an olefin polymerization catalyst comprising a transition metal selected from metals of Groups IIIA including the lanthanide series, IVA, VA, VIA, VIIA and VIII of the Periodic Table of the Elements, and ligands L¹ and L² bonded thereto, wherein a combination of L¹ and L² is (1) a combination of ligand L¹ which is a group containing at least one phosphorus-containing group and ligand L² which is a ligand having a σ-bond, or a ligand having a σ-bond and a bond selected from at least one π-bond and at least one lone electron pair donative bond; (2) a combination of ligand L¹ which is a 5-membered heterocyclic pentadentate ligand having one or more heteroatoms and ligand L² which is a ligand having a σ-bond, or a ligand having a σ-bond and a bond selected from at least one π-bond and at least one lone electron pair donative bond, provided that when the pentadentate ligand contains only one heteroatom, L² is a ligand having a σ-bond, or a ligand having a σ-bond and at least one lone electron pair donative bond; and (3) a combination of ligand L¹ which is a trispyrazolyl tridentate ligand and ligand L² which is an alkapolyenyl ligand, and wherein each L¹ contains an element of Group VB or Group VIB. The catalyst of the present invention has extremely high catalytic activity for an olefin polymerization reaction as compared to conventional olefin polymerization catalysts.
    • 公开了一种烯烃聚合催化剂,其包含选自包括元素周期表的镧系,IVA,VA,VIA,VIIA和VIII族的IIIA族金属的过渡金属,以及配位体L 1和L 2键合 其中L 1和L 2的组合是(1)作为含有至少一个含磷基团的基团的配体L 1和作为具有至少一个含磷基团的配体的配体L 2的组合, σ键或具有σ键和选自至少一个π键和至少一个单电子对捐赠键的键的配体; (2)配体L 1的组合,其为具有一个或多个杂原子的5元杂环五齿配体和具有σ键的配体的配体L 2或具有σ-键的配体, 选自至少一个π键和至少一个单电子对供体键的键,条件是当五齿配体仅含有一个杂原子时,L 2是具有σ-键的配体或具有σ 和至少一个单电子对捐赠债券; 和(3)作为三吡唑基三齿配体的配体L 1和作为烷基多烯基配体的配体L 2的组合,并且其中每个L 1含有VB族或VIB族的元素。 与常规烯烃聚合催化剂相比,本发明的催化剂对于烯烃聚合反应具有极高的催化活性。