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    • 7. 发明公开
    • One liquid type epoxy resin composition
    • FlüssigeEpoxydharzzusammensetzung eines Typs。
    • EP0193068A1
    • 1986-09-03
    • EP86101998.2
    • 1986-02-17
    • Asahi Kasei Kogyo Kabushiki Kaisha
    • Ishimura, HidekazuOhtsuka, MasahikoYamamura, Hideo
    • C08G59/18C08G59/50C08G59/56C08J5/24
    • C08G59/18C08G59/50C08G59/56
    • @ The present invention provides a one-liquid type epoxy resin composition which is useful especially as a coating material and adhesive for a wide range of applications. The resin composition comprises

      (1) an epoxy resin (A) containing at least an average of two epoxy groups per molecular unit; and
      (2) a curing agent (B) consisting essentially of a powdery amine compound (C) having a softening point of 50 to 150°C, the particles of said powdery amine compound being coated with at least one of the following layers:

      (i) a layer formed by adhesion to the surface of said particles of at least one compound selected from the group consisting of an isocyanate (D), a carboxylic acid (E), a carboxylic acid anhydride (F), an acid halogenated compound (G) and an epoxy compound (H); and
      (ii) a layer formed by covalent bonding of the powdery amine compound (C) with at least one compound selected from the group consisting of an isocyanate (D), a carboxylic acid (E), a carboxylic acid anhydride (F), an acid halogenated compound (G) and an epoxy compound (H);


      the softening temperature of said curing agent (B) being 5 to 50°C higher than the softening temperature of said powdery amine compound (C).
    • 本发明提供一种单液型环氧树脂组合物,其特别用作涂料和用于广泛应用的粘合剂。 树脂组合物包含(1)每分子单元至少含有两个环氧基的环氧树脂(A); 和(2)基本上由软化点为50-150℃的粉末状胺化合物(C)组成的固化剂(B),所述粉末状氨基化合物的颗粒被涂覆有以下至少一层:( i)通过粘附至所述颗粒表面的至少一种选自异氰酸酯(D),羧酸(E),羧酸酐(F),酸卤化化合物(D) G)和环氧化合物(H); 和(ii)通过粉末状胺化合物(C)与至少一种选自异氰酸酯(D),羧酸(E),羧酸酐(F), 酸卤化化合物(G)和环氧化合物(H); 所述固化剂(B)的软化温度比所述粉末状氨基化合物(C)的软化温度高5〜50℃。
    • 9. 发明公开
    • Hardener for curable one-package epoxy resin system
    • 可固化单组分环氧树脂体系的固化剂
    • EP0304503A1
    • 1989-03-01
    • EP87112414.5
    • 1987-08-26
    • Asahi Kasei Kogyo Kabushiki Kaisha
    • Ishimura, HidekazuOtsuka, MasahikoTakahashi, YasushiIshikawa, Tadayoshi
    • C08G59/18C08J3/24
    • C08J3/226C08G59/18C08G59/184C08J2363/00C08J2463/00Y10S525/936
    • A master batch of hardener for curable one-­package epoxy resin system which comprises (I) a hardener consisting of

      (I) a hardener consisting of

      (i) a powder of an amine compound (A) as a core having at least one tertiary amino group in the molecule while having no primary and secondary amino groups, the powder having both a group (X) capable of absorbing infrared rays of 1630 to 1680 cm⁻¹ in wave length and a group (Y) capable of absorbing infrared rays of 1680 to 1725 cm⁻¹ in wave length at least on the surface of the powder, and
      (ii) a reaction product of the amine compound (A) and an epoxy resin as a shell; and

      (II) an epoxy resin (B) in a ratio of 10 to 50,000 parts by weight to 100 parts by weight of the hardener (I).
      A hardener containing the master batch is also disclosed.
    • 一种用于可固化单包装环氧树脂体系的硬化剂母料,其包含(I)由(I)硬化剂组成的硬化剂,所述硬化剂由(i)作为核心的胺化合物(A)的粉末具有至少一个叔氨基 基团,同时不具有伯和仲氨基,粉末具有能够吸收波长为1630至1680cm -1的红外线的基团(X)和能够吸收1680的红外线的基团(Y) (ii)胺化合物(A)和作为壳的环氧树脂的反应产物;和(ii)胺化合物(A)和作为壳的环氧树脂的反应产物。 和(II)相对于100重量份硬化剂(I)为10至50,000重量份的环氧树脂(B)。 还公开了包含母料的硬化剂。