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    • 5. 发明公开
    • METHOD OF REGULATING MOLECULAR WEIGHT DISTRIBUTION OF POLYETHER GLYCOL
    • VERFAHREN ZUR REGULIERUNG DER MOLEKULARGEWICHTSVERTEILUNG VON POLYETHERGLYKOL
    • EP1130044A1
    • 2001-09-05
    • EP99921170.9
    • 1999-05-19
    • Asahi Kasei Kabushiki Kaisha
    • AKEDO, Takaharu
    • C08G65/20
    • C08G65/2696C08G65/20C08G65/2666
    • A method for controlling the molecular weight distribution of polyether glycol in producing polyether glycol having a specified number average molecular weight by polymerizing tetrahydrofuran as a starting monomer with the use of a heteropoly-acid as a catalyst, which method comprises conducting the polymerization in the presence of an amount of water which can form two phases of the organic phase and a catalyst phase, sampling the polymerization product during the polymerization to determine the molecular weight distribution and, when the molecular weight distribution thus found is narrower than the specified molecular weight distribution, making the residence time distribution of the starting monomer in the catalyst phase wider, while, when the found molecular weight distribution is wider than the specified molecular weight distribution, making the residence time distribution of the starting monomer in the catalyst phase narrower.
    • 一种通过使用杂多酸作为催化剂聚合四氢呋喃作为起始单体来控制聚醚二醇在制备具有特定数均分子量的聚醚二醇中的分子量分布的方法,该方法包括在存在下进行聚合 的一定量的水可以形成有机相和催化剂相的两相,在聚合期间对聚合产物进行取样以确定分子量分布,并且当所发现的分子量分布窄于指定的分子量分布时, 使起始单体在催化剂相中的停留时间分布更宽,而当发现的分子量分布大于特定的分子量分布时,使起始单体在催化剂相中的停留时间分布变窄。