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1. 发明公开

EP2361900A2 Method for producing glycolic acid 有权
标题翻译：生产乙醇酸的方法
公开(公告)号：EP2361900A2
公开(公告)日：2011-08-31
申请号：EP11162394.8
申请日：2006-05-25
申请人： Asahi Kasei Chemicals Corporation
发明人： Hinago, Hidenori , Nagahara, Hajime , Aoki, Toshiya
IPC分类号： C07C51/08 , C07C59/06 , C12P7/42
CPC分类号： C12P7/42 , C07C51/08 , C07C51/412 , C07C59/06
摘要： Provided is a production method of glycolic acid having a first step of preparing glycolonitrile from formaldehyde and hydrocyanic acid and a second step of hydrolyzing the glycolonitrile into glycolic acid directly or via a glycolate salt, which method can produce glycolic acid in easy production and purification steps while consuming less energy. In the production method, by carrying out the first and second steps continuously or by storing the glycolonitrile obtained in the first step at pH 4 or less and carrying out a hydrolysis reaction of the second step at from pH 5 to 9, a production yield of glycolic acid, activity for the production of glycolic acid and accumulated concentration of glycolic acid are improved, resulting in the production of glycolic acid having an improved purity and quality.
摘要翻译：本发明提供一种乙醇酸的制造方法，该制造方法具有从甲醛和氢氰酸制备乙醇腈的第一工序和将乙醇腈直接或经由羟基乙酸盐水解成乙醇酸的第二工序，该制造方法在制造和纯化工序中容易制造乙醇酸同时消耗更少的能量。在制备方法中，通过连续进行第一和第二步骤或通过将在第一步骤中获得的乙醇腈储存在pH4或更低并且在pH5到9进行第二步骤的水解反应，生产产率乙醇酸，乙醇酸生产活性和乙醇酸累积浓度得到改善，导致生产具有改善的纯度和质量的乙醇酸。

2. 发明授权

EP2361900B1 Method for producing glycolic acid 有权
标题翻译：一种用于生产乙醇酸过程
公开(公告)号：EP2361900B1
公开(公告)日：2015-04-08
申请号：EP11162394.8
申请日：2006-05-25
申请人： Asahi Kasei Chemicals Corporation
发明人： Hinago, Hidenori , Nagahara, Hajime , Aoki, Toshiya
IPC分类号： C07C51/08 , C07C59/06 , C07C51/41 , C12P7/42
CPC分类号： C12P7/42 , C07C51/08 , C07C51/412 , C07C59/06

3. 发明公开

EP2527294A1 Nitrogen-containing carbon material and method of producing the same 失效
标题翻译： Stickstoffhaltiges Kohlenstoffmaterial und Herstellungsverfahrendafür
公开(公告)号：EP2527294A1
公开(公告)日：2012-11-28
申请号：EP12004775.8
申请日：2006-09-22
申请人： Asahi Kasei Chemicals Corporation
发明人： Hinago, Hidenori , Nagahara, Hajime
IPC分类号： C01B31/02 , H01M4/02 , C01B21/06 , C01B21/087 , H01M4/96 , H01M4/583 , H01M4/587 , H01M8/02 , H01G9/058
CPC分类号： H01M4/96 , C01B21/0605 , C01B21/087 , C01B32/05 , C01P2002/72 , C01P2002/82 , C01P2002/85 , C01P2006/80 , H01G11/32 , H01G11/34 , H01M4/583 , H01M4/587 , H01M8/0234 , H01M2004/021 , Y02E60/13
摘要： The present invention provides a nitrogen-containing carbon material characterized in that it satisfies a specific relational expression between the number ratio of nitrogen atoms to carbon atoms and the number ratio of hydrogen atoms to carbon atoms and has peaks in specific regions in the X-ray diffraction and in the laser Raman spectrum. The nitrogen-containing carbon material of the present invention can be produced by carbonizing azulmic acid in an inert gas atmosphere, and it is useful as an electrode material or the like because it has a high nitrogen content and a low hydrogen content.
摘要翻译：本发明提供一种含氮碳材料，其特征在于，其满足氮原子与碳原子的数量比和氢原子与碳原子的数量比的特定关系式，并且在X射线的特定区域具有峰值衍射和激光拉曼光谱。本发明的含氮碳材料可以通过在惰性气体气氛中碳化薁酸来制造，由于氮含量高，氢含量低，因此可以用作电极材料等。

4. 发明授权

EP2527294B1 Nitrogen-containing carbon material and method of producing the same 失效
标题翻译：碳材料及其制造方法的含氮
公开(公告)号：EP2527294B1
公开(公告)日：2013-12-04
申请号：EP12004775.8
申请日：2006-09-22
申请人： Asahi Kasei Chemicals Corporation
发明人： Hinago, Hidenori , Nagahara, Hajime
IPC分类号： C01B21/087 , C01B31/02 , H01G9/04 , H01M8/02 , C01B21/06 , H01M4/02 , H01M4/96 , H01M4/587 , H01M4/583 , H01G11/34
CPC分类号： H01M4/96 , C01B21/0605 , C01B21/087 , C01B32/05 , C01P2002/72 , C01P2002/82 , C01P2002/85 , C01P2006/80 , H01G11/32 , H01G11/34 , H01M4/583 , H01M4/587 , H01M8/0234 , H01M2004/021 , Y02E60/13
摘要： The present invention provides a nitrogen-containing carbon material characterized in that it satisfies a specific relational expression between the number ratio of nitrogen atoms to carbon atoms and the number ratio of hydrogen atoms to carbon atoms and has peaks in specific regions in the X-ray diffraction and in the laser Raman spectrum. The nitrogen-containing carbon material of the present invention can be produced by carbonizing azulmic acid in an inert gas atmosphere, and it is useful as an electrode material or the like because it has a high nitrogen content and a low hydrogen content.

5. 发明公开

EP2361900A3 Method for producing glycolic acid 有权
标题翻译：一种用于生产乙醇酸过程
公开(公告)号：EP2361900A3
公开(公告)日：2011-09-14
申请号：EP11162394.8
申请日：2006-05-25
申请人： Asahi Kasei Chemicals Corporation
发明人： Hinago, Hidenori , Nagahara, Hajime , Aoki, Toshiya
IPC分类号： C07C51/08 , C07C59/06 , C12P7/42
CPC分类号： C12P7/42 , C07C51/08 , C07C51/412 , C07C59/06
摘要： Provided is a production method of glycolic acid having a first step of preparing glycolonitrile from formaldehyde and hydrocyanic acid and a second step of hydrolyzing the glycolonitrile into glycolic acid directly or via a glycolate salt, which method comprises storing the glycolonitrile obtained in the first step at pH 4 or less and carrying out a hydrolysis reaction of the second step at from pH 5 to 9.

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