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    • 1. 发明公开
    • STABLE AQUEOUS POLYMER DISPERSIONS
    • EP3896103A1
    • 2021-10-20
    • EP21176952.6
    • 2018-07-05
    • ARKEMA FRANCE
    • SAIJA, Leo MarioLUGLI, MarioFINETTI, FilippoAMADEI, Umberto
    • C08F212/08D04H1/587D04H1/64D06M15/233D06M15/263
    • The invention relates to an aqueous polymer dispersion which is stable for at least 12 h, when dissolved in a high amount of organic solvents and eventually acidified at very low pH (pH
      a) at least one (meth)acrylic monomer which is a (meth)acrylic ester of a C 1 -C 12 alcohol without any other functional group than (meth)acrylate
      b) at least monomer b1) or initiator b2) or both as defined below :
      b1) at least one vinylic, allylic or (meth)acrylic monomer, bearing an anionic group derived from strong acids with pKa
      b2) at least one initiator, bearing the same anionic group as b1)

      c) at least one hydroxy-functional vinylic, allylic or (meth)acrylic monomer
      d) optionally, at least one carboxy-functional ethylenically unsaturated monomer
      e) optionally, at least one vinylic monomer bearing only one vinyl group, without any other functional group than vinylic group
      f) optionally, at least one vinylic or (meth)acrylic monomer bearing at least one functional group selected from : nitrile, amide, acetoacetoxy, diacetone, free silane or alkoxy-blocked silane, epoxy, urea or ureïdo
      g) optionally, at least one multifunctional vinylic or (meth)acrylic monomer and which polymer bears : the anionic groups as defined in b) in an amount of at least 0.05 meq/g and hydroxy groups as defined in c) in an amount of at least 0.1 meq/g.
    • 4. 发明公开
    • STABLE AQUEOUS POLYMER DISPERSIONS
    • EP3434701A1
    • 2019-01-30
    • EP17183080.5
    • 2017-07-25
    • ARKEMA FRANCE
    • SAIJA, Leo MarioLUGLI, MarioFINETTI, FilippoAMADEI, Umberto
    • C08F212/08
    • The invention relates to an aqueous polymer dispersion which is stable for at least 12 h, when dissolved in a high amount of organic solvents and eventually acidified at very low pH (pH
      a) at least one (meth)acrylic monomer which is a (meth)acrylic ester of a C 1 -C 12 alcohol without any other functional group than (meth)acrylate
      b) at least monomer b1) or initiator b2) or both as defined below :
      b1) at least one vinylic, allylic or (meth)acrylic monomer, bearing an anionic group derived from strong acids with pKa
      b2) at least one initiator, bearing the same anionic group as b1)
      c) at least one hydroxy-functional vinylic, allylic or (meth)acrylic monomer
      d) optionally, at least one carboxy-functional ethylenically unsaturated monomer
      e) optionally, at least one vinylic monomer bearing only one vinyl group, without any other functional group than vinylic group
      f) optionally, at least one vinylic or (meth)acrylic monomer bearing at least one functional group selected from : nitrile, amide, acetoacetoxy, diacetone, free silane or alkoxy-blocked silane, epoxy, urea or ureïdo
      g) optionally, at least one multifunctional vinylic or (meth)acrylic monomer and which polymer bears : the anionic groups as defined in b) in an amount of at least 0.05 meq/g and hydroxy groups as defined in c) in an amount of at least 0.1 meq/g.