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    • 4. 发明公开
    • ONE-STEP PROCESS FOR MAKING A POLYMER COMPOSITE COATING WITH HIGH BARRIER
    • EINSTUFIGES VERFAHREN ZUR HERSTELLUNG EINER POLYMERVERBUNDBESCHICHTUNG MIT HOCHBARRIERE
    • EP3145960A1
    • 2017-03-29
    • EP15796624.3
    • 2015-05-21
    • Agency for Science, Technology and Research
    • LI, XuCHIENG, Yu YuanWONG, Siew YeeZHANG, Xikui
    • C08F2/44C09D4/02C09D129/02C09D133/02C08K7/26C08F20/06C08L33/14C09D133/00
    • C08J7/047C08F2/44C08F20/06C08J2429/04C08J2433/02C09D4/06C09D133/02C09D129/04C08L33/02C08K3/346C08K9/06
    • This invention relates to a a one-step process for making a polymer composite suspension for coating plastic films characterized in that a first polymer is synthesized in-situ optionally in the presence of other polymers and in the presence of clay. Preferably the polymer composite suspension comprises a) 1.0 to 11.0 wt % of clay or silane modified clay, b) 0.1 to 10.0 wt % of poly (acrylic acid), which is a copolymer of acrylic acid (AA) with at least one other monomer selected from 2-ethylhexyl acrylate (EHA), β-carboxyethyl acrylate (β-CEA), methacrylamidoethyl ethylene urea (WAM II) and ethoxylated behenyl methacrylate (β-EM), c) 1.0 to 15.0 wt % of other polymers, preferably poly (vinyl alcohol) and d) 70 to 97 wt % of water or mixture of water with 2-propanol. The coating films made from the suspensions show good barrier capabilities against water vapor and oxygen can be used to make barrier layers on or within plastic films for packaging applications. The invention also relates to methods for making silane modified clay usable in the process for making the suspensions.
    • 本发明涉及一种用于制备用于涂覆塑料膜的聚合物复合悬浮液的一步法,其特征在于第一聚合物任选地在其它聚合物存在下和在粘土存在下原位合成。 优选地,聚合物复合悬浮液包含a)1.0至11.0重量%的粘土或硅烷改性粘土,b)0.1至10.0重量%的聚丙烯酸,其是丙烯酸(AA)与至少一种其它单体的共聚物 选自丙烯酸2-乙基己酯(EHA),丙烯酸β-羧乙酯(β-CEA),甲基丙烯酰氨基乙基亚乙基脲(WAM II)和乙氧基化山梨糖基甲基丙烯酸酯(β-EM),c)1.0至15.0wt%的其它聚合物, (乙烯醇)和d)70-97重量%的水或水与2-丙醇的混合物。 由悬浮液制成的涂膜对水蒸气显示出良好的屏障能力,氧气可用于在包装应用的塑料薄膜之上或之内制造阻隔层。 本发明还涉及可用于制备悬浮液的方法中制备硅烷改性粘土的方法。