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    • 4. 发明公开
    • CELLULOSIC RESIN COMPOSITION AND CELLULOSIC RESIN FILM
    • ZELLULOSE-KUNSTHARZ-ZUSAMMENSETZUNG UND ZELLULOSE-KUNSTHARZ-FILM
    • EP2392613A1
    • 2011-12-07
    • EP10735689.1
    • 2010-01-08
    • Adeka Corporation
    • HARADA MasashiYAMAZAKI YujiKAMIMURA Satoshi
    • C08L1/10C08J5/18C08L67/02
    • C08G63/20C08J5/18C08J2301/10C08L1/10C08L1/14
    • Provided are a cellulose resin composition which can give a cellulose ester film free from the problems with bleeding and has excellent moisture permeability, even when containing a plasticizer in a relatively large amount, and a cellulose resin film which is obtained from the cellulose resin composition.
      The present invention relates to a cellulose resin composition obtained by adding (A) a polyester plasticizer to a cellulose resin. The aforementioned (A) polyester plasticizer is obtained from a polybasic acid, a glycol and a stopper, wherein 70 to 30 mol% of the aforementioned polybasic acid is a succinic acid and/or an adipic acid; 30 to 70 mol% of the aforementioned polybasic acid is at least one selected from a group consisting of a terephthalic acid, a phthalic acid and an isophthalic acid; the aforementioned glycol is at least one selected from a group consisting of an ethylene glycol, a 1,2-propylene glycol, a 1,3-butanediol and a 2-methyl-1,3-propanediol; the aforementioned stopper is an acetic acid and/or a benzoic acid; and the weight-average molecular weight is 600 to 2,000.
    • 可以提供即使含有较大量的增塑剂也能够得到没有出血问题的纤维素酯膜和具有优异的透湿性的纤维素树脂组合物和由纤维素树脂组合物获得的纤维素树脂膜。 本发明涉及通过将(A)聚酯增塑剂添加到纤维素树脂中而获得的纤维素树脂组合物。 上述(A)聚酯增塑剂由多元酸,二元醇和塞子得到,其中70〜30摩尔%的上述多元酸是琥珀酸和/或己二酸; 30〜70摩尔%的上述多元酸是选自对苯二甲酸,邻苯二甲酸和间苯二甲酸中的至少一种; 上述二醇是选自乙二醇,1,2-丙二醇,1,3-丁二醇和2-甲基-1,3-丙二醇中的至少一种; 上述塞子是乙酸和/或苯甲酸; 重均分子量为600〜2000。