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1. 发明授权

EP2217641B1 MATERIAL FORMED FROM DENDRITIC MOLECULES CONTAINING ASSOCIATIVE GROUPS 有权
标题翻译： AUS DENTRITISCHENMOLEKÜLENMIT ASSOZIATIVEN GRUPPEN GEFORMTES MATERIAL
公开(公告)号：EP2217641B1
公开(公告)日：2017-03-08
申请号：EP08858295.2
申请日：2008-12-02
申请人： ARKEMA FRANCE , Centre National de la Recherche Scientifique (C.N.R.S.)
发明人： TOURNILHAC, François-Genes , HIDALGO, Manuel , LEIBLER, Ludwik
IPC分类号： C08G83/00 , C08G69/42 , C08G69/44
CPC分类号： A61K8/85 , A61K8/4946 , A61K8/496 , A61K8/4966 , A61K8/84 , A61K8/88 , A61K2800/544 , A61Q1/02 , A61Q5/02 , A61Q5/06 , A61Q5/12 , A61Q19/00 , C07D233/36 , C07D233/40 , C07D249/12 , C07D249/14 , C07D251/02 , C07D253/02 , C08G59/02 , C08G59/22 , C08G59/42 , C08G63/12 , C08G63/685 , C08G63/6854 , C08G83/003

2. 发明公开

EP3134457A2 CATALYSEUR A BASE DE TITANE POUR RESINES VITRIMERES DE TYPE EPOXY/ANHYRIDE 有权
标题翻译： TITANBASIERTER KATALYSATORFÜREPOXID- / ANHYDRID-VITRIMERHARZE
公开(公告)号：EP3134457A2
公开(公告)日：2017-03-01
申请号：EP15725790.8
申请日：2015-04-23
申请人： Arkema France , Centre National de la Recherche Scientifique , Ecole Supérieure de Physique et de Chimie Industrielles de la Ville de Paris
发明人： DUQUENNE, Christophe , MOUGNIER, Sébastien-Jun , TOURNILHAC, François-Genes , LEIBLER, Ludwik
IPC分类号： C08G59/42 , C08G59/68
摘要： The present invention relates to a composition containing, besides a thermosetting resin of epoxy type and a hardener of anhydride type, at least one catalyst comprising an organometallic titanium complex. This composition enables the manufacture of vitrimer resins, that is to say of resins that can be deformed in the thermoset state. It also relates to a kit for manufacturing this composition, an object obtained from this composition and a kit for manufacturing this object. Another subject of the invention relates to an organometallic titanium complex corresponding to the structure titanium bis(3-phenoxy-l,2-propane dioxide) (Ti(PPD)
2 ), and the use thereof as vitrimer effect catalyst in systems based on epoxy resin and on hardener of anhydride type.
摘要翻译：本发明涉及除环氧类热固性树脂和酸酐型硬化剂外还含有至少一种包含有机金属钛络合物的催化剂的组合物。这种组合物能够制造葡聚糖树脂，也就是说可以在热固性状态下变形的树脂。它还涉及用于制造该组合物的试剂盒，由该组合物获得的物体和用于制造该物体的试剂盒。本发明的另一主题涉及对应于钛双（3-苯氧基-1,2-二氧化丙烷）（Ti（PPD）2）结构的有机金属钛络合物，以及其在基于环氧树脂的体系中作为葡聚糖效应催化剂的用途树脂和酸酐类固化剂。

3. 发明授权

EP2274377B1 COMPOSITION RENFERMANT UN POLYMÈRE VINYLIQUE HALOGÉNÉ ET UN COPOLYMÈRE PORTEUR DE GROUPES ASSOCIATIFS. 有权
标题翻译：与卤代乙烯基聚合物和通过关联组的共聚物组成
公开(公告)号：EP2274377B1
公开(公告)日：2012-02-01
申请号：EP09750040.9
申请日：2009-05-05
申请人： Arkema France , Centre National de la Recherche Scientifique - CNRS -
发明人： LEIBLER, Ludwik , TOURNILHAC, François-Genes , DUFAURE, Nicolas , HIDALGO, Manuel
IPC分类号： C08L27/00 , C08L33/00 , C08L27/06 , C08L27/16
CPC分类号： C09D127/00 , C08L27/00 , C08L33/00 , C08L2666/04 , C09J127/00
摘要： The present invention relates to a composition comprising: (a) at least one halogenated vinyl polymer and (b) at least one copolymer containing (i) units derived from a first monomer (A) rendering said copolymer compatible with said halogenated vinyl polymer and (ii) units derived from a second monomer (B) bearing at least one given associative group. The present invention also relates to the use of such a copolymer bearing associative groups, for improving certain properties of a halogenated vinyl polymer. The invention finally relates to the uses of the aforementioned composition.

4. 发明公开

EP2115022A1 MATERIAU POLYMERE DE TYPE STYRENE / ANHYDRIDE, GREFFE AYANT DES PROPRIETES AMELIOREES 有权
标题翻译：苯乙烯/ ANHYDRIDPOLYMERMATERIAL及移栽具有改进的特性
公开(公告)号：EP2115022A1
公开(公告)日：2009-11-11
申请号：EP08762023.3
申请日：2008-02-01
申请人： ARKEMA FRANCE , Centre National de la Recherche Scientifique
发明人： DUFAURE, Nicolas , GRIMALDI, Sandra , HIDALGO, Manuel , LEIBLER, Ludwik , TOURNILHAC, François-Genes
IPC分类号： C08F257/02 , C08F267/04 , C08F257/00 , C08F267/00 , C08L51/00
CPC分类号： C08F8/34 , C08F8/14 , C08F8/32 , C08F222/06 , C08F2800/20 , C08F2810/10 , C08L51/06 , C08L2205/08 , C08F212/08
摘要： A polymeric material from the styrene family, consisting of macromolecular chains grafted by nitrogen-containing heterocyclic groups, wherein the macromolecular chains consist of a polymeric backbone to which a grafting agent is attached by at least one covalent bond, the grafting agent comprises, in a single molecule, one or more associative groups capable of being bound by hydrogen bonds, and one or more reactive groups capable of forming covalent bonds with the polymeric backbone, at least one of the associative groups of the modifier is an imidazolidone heterocyclic ring. The mean number of imidazolidone groups to be inserted into the macromolecular chains is dependent both on the mean mass of said chains and on the final properties to be imparted to the material. The polymeric material of the invention can be extruded, co-extruded, injected, blow-moulded, moulded, overmoulded, calendered, or thermoformed. Objects such as tubes, films, plates, stiffeners, bottles and containers can be made. The polymeric material of the invention can also be blended with other materials such as other polymers, and can thus be modified by elastomeric phases that enhance the impact strength thereof. The polymeric material of the invention can be a component of masterbatches of additives such as pigments and fillers. The present invention further relates to the use of said polymeric material as a compatibilisation agent in a composition including, inter alia, at least two polymers belonging to different polymeric classes.

5. 发明授权

EP2115022B1 MATERIAU POLYMERE DE TYPE STYRENE / ANHYDRIDE, GREFFE AYANT DES PROPRIETES AMELIOREES 有权
标题翻译：苯乙烯/ ANHYDRIDPOLYMERMATERIAL及移栽具有改进的特性
公开(公告)号：EP2115022B1
公开(公告)日：2012-08-22
申请号：EP08762023.3
申请日：2008-02-01
申请人： ARKEMA FRANCE , Centre National de la Recherche Scientifique
发明人： DUFAURE, Nicolas , GRIMALDI, Sandra , HIDALGO, Manuel , LEIBLER, Ludwik , TOURNILHAC, François-Genes
IPC分类号： C08F8/00 , C08F212/08 , C08F222/06 , C08L35/06 , C08F8/32
CPC分类号： C08F8/34 , C08F8/14 , C08F8/32 , C08F222/06 , C08F2800/20 , C08F2810/10 , C08L51/06 , C08L2205/08 , C08F212/08
摘要： A polymeric material from the styrene family, consisting of macromolecular chains grafted by nitrogen-containing heterocyclic groups, wherein the macromolecular chains consist of a polymeric backbone to which a grafting agent is attached by at least one covalent bond, the grafting agent comprises, in a single molecule, one or more associative groups capable of being bound by hydrogen bonds, and one or more reactive groups capable of forming covalent bonds with the polymeric backbone, at least one of the associative groups of the modifier is an imidazolidone heterocyclic ring. The mean number of imidazolidone groups to be inserted into the macromolecular chains is dependent both on the mean mass of said chains and on the final properties to be imparted to the material. The polymeric material of the invention can be extruded, co-extruded, injected, blow-moulded, moulded, overmoulded, calendered, or thermoformed. Objects such as tubes, films, plates, stiffeners, bottles and containers can be made. The polymeric material of the invention can also be blended with other materials such as other polymers, and can thus be modified by elastomeric phases that enhance the impact strength thereof. The polymeric material of the invention can be a component of masterbatches of additives such as pigments and fillers. The present invention further relates to the use of said polymeric material as a compatibilisation agent in a composition including, inter alia, at least two polymers belonging to different polymeric classes.

6. 发明公开

EP2326677A1 PROCEDE POUR AUGMENTER LA COMPATIBILITE DE POLYMERES 审中-公开
标题翻译：方法用于增加聚合物的相容性
公开(公告)号：EP2326677A1
公开(公告)日：2011-06-01
申请号：EP09748403.4
申请日：2009-09-17
申请人： Arkema France , CNRS
发明人： DUFAURE, Nicolas , TOURNILHAC, François-Genes , HIDALGO, Manuel , LEIBLER, Ludwik
IPC分类号： C08F8/30 , C08L23/08 , C08L33/00 , C08L51/06 , C08L51/08 , C08L77/00
CPC分类号： C08F8/48 , C08F8/30 , C08L23/0869 , C08L33/12 , C08L51/06 , C08L77/00 , C08L2205/08 , C08F210/02 , C08F220/14 , C08L2666/02
摘要： The invention relates to a method for increasing the compatibility between at least two polymers, which comprises: (a) selecting at least two immiscible polymers (A) and (B), at least one of which does not bear a nitrogenous heterocycle-based associative group, and (b) modifying the polymer (A) and/or the polymer (B) so as to obtain a blend of polymers (Pi) which are derived from the polymers (A) and (B) and which each bear nitrogenous heterocycle-based associative groups, said associative groups being present in sufficient amount for the polymers (Pi) to be more compatible with one another than the polymers (A) and (B). It also relates to the polymer composition that can be obtained according to this method.

7. 发明公开

EP2217641A1 MATERIAL FORMED FROM DENDRITIC MOLECULES CONTAINING ASSOCIATIVE GROUPS 有权
标题翻译：通过关联组成形的材料OFF树突状分子
公开(公告)号：EP2217641A1
公开(公告)日：2010-08-18
申请号：EP08858295.2
申请日：2008-12-02
申请人： ARKEMA FRANCE , Centre National de la Recherche Scientifique - CNRS
发明人： TOURNILHAC, François-Genes , HIDALGO, Manuel , LEIBLER, Ludwik
IPC分类号： C08G83/00 , C08G69/42 , C08G69/44
CPC分类号： A61K8/85 , A61K8/4946 , A61K8/496 , A61K8/4966 , A61K8/84 , A61K8/88 , A61K2800/544 , A61Q1/02 , A61Q5/02 , A61Q5/06 , A61Q5/12 , A61Q19/00 , C07D233/36 , C07D233/40 , C07D249/12 , C07D249/14 , C07D251/02 , C07D253/02 , C08G59/02 , C08G59/22 , C08G59/42 , C08G63/12 , C08G63/685 , C08G63/6854 , C08G83/003
摘要： The present invention relates to a material comprising dendritic molecules each constituted of fragments that are at least bifunctional and of fragments that are at least trifunctional joined together by ester or thioester bridges, alone or in combination with amide or urea bridges, said bridges being formed from two functions carried by different fragments, said molecules containing, on the fragments located at the ends of the dendritic branches, associative end groups capable of forming associations with one another by hydrogen bonds and joined covalently to the functions that are not involved in said bridges. It also relates to the method of production thereof, as well as to its uses and to compositions, notably cosmetic, containing this material.

8. 发明公开

EP1778741A1 MATERIAU POLYMERE CONTENANT DES CHAINES PORTANT DES FONCTIONS IMIDAZOLIDONE 有权
标题翻译： MATERIAU POLYMERE CONTENTANT DES CHAINES PORTANT DES FONCTIONS IMIDAZOLIDONE
公开(公告)号：EP1778741A1
公开(公告)日：2007-05-02
申请号：EP05788743.2
申请日：2005-07-06
申请人： Arkema France , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS)
发明人： TOURNILHAC, François-Genes , LEIBLER, Ludwik , SOULIE-ZIAKOVIC, Corinne , CORDIER, Philippe , HIDALGO, Manuel , LINEMANN, Annett
IPC分类号： C08F8/30
CPC分类号： C08F8/30 , C08F8/32 , C08F8/34 , C08G69/48 , Y10T428/1352 , Y10T428/139 , C08F220/14 , C08F210/02
摘要： The invention concerns a polymer material consisting of macromolecular chains bound by hydrogen bonds wherein: the macromolecular chains consist of a polymer skeleton whereon is fixed by at least one covalent bond a modifying agent, the modifying agent comprising, assembled in a common molecule, one or more associative groups capable of being bound by hydrogen bonds and one or more reactive groups capable of forming covalent bonds with the polymer skeleton, at least one of the associative groups of the modifying agent is an imidazolidone heterocycle, the macromolecular chains bear on average 1 to 10 imidazolidone groups per chain. The average number of imidazolidone groups to be introduced into the macromolecular chains depends both on the average mass of said chains and the final properties desired for the material. The inventive polymer material can be extruded, co-extruded, injected, blown, moulded, overmoulded, calandered, thermoformed. It can be used to produce articles such as tubes, films, plates, extruded strings, bottles, containers. The inventive polymer material can also be mixed with other materials such as other polymers, thus it is used for example as impact modifier or rheology regulator. The invention further concerns the use of said polymer material as compatibility agent in a composition comprising among others at least two polymers belonging to different classes of polymers.
摘要翻译：本发明涉及一种由氢键结合的大分子链组成的聚合物材料，其中：大分子链由聚合物骨架组成，其中聚合物骨架由至少一个共价键与改性剂固定，所述改性剂包含组装在共同分子中的一个或能够与氢键结合的更多缔合基团和能够与聚合物骨架形成共价键的一个或多个反应性基团，改性剂的至少一个缔合基团为咪唑烷酮杂环，大分子链平均承载1至每个链10个咪唑烷酮基团。引入大分子链的咪唑烷酮基团的平均数量取决于所述链的平均质量和材料所需的最终性能。本发明的聚合物材料可以被挤出，共挤出，注射，吹塑，模塑，包覆成型，压延，热成型。它可用于生产诸如管子，薄膜，板材，挤压线，瓶子，容器等物品。本发明的聚合物材料也可以与其他材料例如其他聚合物混合，因此其例如用作冲击改性剂或流变学调节剂。本发明还涉及所述聚合物材料在组合物中作为相容剂的用途，所述组合物包含至少两种属于不同种类聚合物的聚合物。

9. 发明公开

EP2576193A1 RESINES ET COMPOSITES THERMODURS EPOXY ACIDES POUVANT ETRE FACONNES A CHAUD ET RECYCLES 失效
标题翻译：热施加RECYCLING和有资格的酸固化热固性树脂和复合材料
公开(公告)号：EP2576193A1
公开(公告)日：2013-04-10
申请号：EP11728325.9
申请日：2011-05-30
申请人： Arkema France , Centre National de la Recherche Scientifique
发明人： LEIBLER, Ludwik , MONTARNAL, Damien , TOURNILHAC, François-Genes , CAPELOT, Mathieu
IPC分类号： B29C73/16 , C08G59/42 , C08L63/02 , C08L63/04 , B29C73/02
CPC分类号： B29C73/02 , B29C73/163 , B29K2063/00 , C08G59/4207 , C08L63/00 , C09D163/00
摘要： Resins and thermoset composites comprising them, these materials being able to be hot-fashioned. These compositions resulting from placing at least one thermosetting resin precursor, this thermosetting resin precursor comprising hydroxyl functions and/or epoxy groups, and optionally ester functions, in contact with at least one hardener chosen from carboxylic acids, in the presence of at least one transesterification catalyst whose total molar amount is between 5% and 25% of the total molar amount of hydroxyl and epoxy contained in the thermosetting resin precursor. Process for manufacturing these materials, process for transforming and process for recycling these materials. New solid forms of resins and of thermoset composites that may be used in the implementation of these processes.

10. 发明公开

EP2384342A1 COPOLYMERES A BLOCS PORTEURS DE GROUPES ASSOCIATIFS ET ADHESIF LES COMPRENANT 有权
标题翻译：通过关联团和键合材料嵌段共聚物THAT
公开(公告)号：EP2384342A1
公开(公告)日：2011-11-09
申请号：EP10707623.4
申请日：2010-01-29
申请人： Arkema France , Centre National de la Recherche Scientifique CNRS
发明人： DUFAURE, Nicolas , HIDALGO, Manuel , GRANGE, Aurélie , TOURNILHAC, François-Genes , LEIBLER, Ludwik
IPC分类号： C08F8/30 , C09J151/06 , C09J153/00
CPC分类号： C08F8/30 , C08F293/005
摘要： The present invention relates to a hot-melt adhesive that comprises a block copolymer having associative groups containing a nitrogen heterocyclic compound. The invention also relates to block copolymers having associative groups specifically adapted for implementation in a hot-melt adhesive.

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