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    • 6. 发明公开
    • CATIONIC MICROCAPSULE PARTICLES
    • 阳离子微胶囊粒子
    • EP2279040A2
    • 2011-02-02
    • EP09739146.0
    • 2009-04-27
    • APPLETON PAPERS INC.
    • SCHWANTES, Todd, Arlin
    • B01J13/14C08F2/24C08F265/06C08J3/12C08F220/34C08F220/18C08F220/10
    • C08F2/24B01J13/16C08F2/28C08F265/06Y10T428/2985Y10T428/2987Y10T428/2989C08F2/22
    • The present invention teaches a cationically charged or neutral microcapsule particle comprising an oil soluble or dispersible core material and a wall material at least partially surrounding the core material, the microcapsule wall material comprising the reaction product of a first composition in the presence of a second composition comprising an emulsifier which is cationic or nonionic, the first composition comprising a reaction product of i) an oil soluble or dispersible amine with ii) a multifunctional acrylate or methacrylate monomer or oligomer, an oil soluble acid and an initiator. The cationic or nonionic emulsifier comprises a water soluble or water dispersible material and optionally a water phase initiator. The first composition initiator and the water phase initiator is an energy-activated initiator. The reaction product of the first composition and second composition results in the formation of a population of microcapsules having a microcapsule wall of low permeance to the core material and having a zeta potential of - 5 millivolts or greater. The resulting microcapsules have adherence to anionic surfaces.
    • 本发明教导了包含油溶性或分散性芯材料和至少部分包围芯材料的壁材料的阳离子带电或中性微胶囊颗粒,所述微胶囊壁材料包含第一组合物在第二组合物存在下的反应产物 包含阳离子或非离子乳化剂,第一组合物包含i)油溶性或分散性胺与ii)多官能丙烯酸酯或甲基丙烯酸酯单体或低聚物,油溶性酸和引发剂的反应产物。 阳离子或非离子乳化剂包含水溶性或水分散性材料和任选的水相引发剂。 第一组合物引发剂和水相引发剂是能量活化的引发剂。 第一组合物和第二组合物的反应产物导致形成具有对芯材料低渗透性并且具有-5毫伏或更大的ζ电位的微胶囊壁的微胶囊群。 得到的微胶囊具有与阴离子表面的粘附性。