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1. 发明公开

EP1631497A2 LINERLESS LABELS 有权
标题翻译：无衬标签
公开(公告)号：EP1631497A2
公开(公告)日：2006-03-08
申请号：EP04752698.3
申请日：2004-05-19
申请人： APPLETON PAPERS INC.
发明人： MATHIAPARANAM, Ponnampalam , FISCHER, Mark, R. , JUSTA MACNEIL, Stacey, Ann
IPC分类号： B65C1/00
CPC分类号： B41M5/327 , B41M5/3336 , B41M2205/04 , B41M2205/36 , B41M2205/40 , C09J7/29 , C09J2203/334 , Y10T428/2848
摘要： A linerless label system comprising pressure adhesive coating, release coating and thermal imaging coating is described. The thermal imaging coating contains as one of its components the compounds of the formula (I) wherein R 1 and R 2 are selected from methyl, ethyl, aryl, aryl substituted with methyl, ethyl, methoxy, ethoxy or halogen, benzyl or benzyl with phenyl substituted with methyl, ethyl, methoxy, ethoxy or halogen, R 3 ,R 4 ,R 5 and R 6 are selected from hydrogen, halogen, methyl, ethyl, methoxy, ethoxy, phenyl, R 7 and R 8 are each independently selected from methyl or ethyl, R 9 is selected from hydrogen, methoxy or ethoxy, R 10 is selected from hydrogen, dimethylamino or diethylamino, R 11 is methyl. The imaged linerless label according to the invention has been a bar reflectance of less than 20 at 670 nanometers, a print control contrast signal of at least 80 and a BNL background of at least 75%.

2. 发明授权

EP1183224B1 PROCESS FOR PREPARING ALKOXY OR ARYLMETHOXY AROXYETHANES 有权
标题翻译：用于生产烷氧基或芳基甲氧基 - AROXYETHANEN
公开(公告)号：EP1183224B1
公开(公告)日：2004-08-04
申请号：EP01903473.5
申请日：2001-02-01
申请人： Appleton Papers Inc.
发明人： MATHIAPARANAM, Ponnampalam , BERGGREN, Debra Arlene
IPC分类号： C07C41/16 , C07C43/20
CPC分类号： C07C41/16 , C07C43/2055 , C07C43/225
摘要： The present invention is a novel process, with or without solvent, for manufacture of compounds of formula (a), wherein P is selected from phenyl and naphthyl; wherein R1 and R2 and R3 are each independently selected from hydrogen, alykl, alkoxy, aryl, aralkyl, aralkoxy, halogen, alkoxyalkoxy, and aralkoxyalkoxy; wherein R5 is selected from substituted or unsubstituted phenyl, and substituted or unsubstituted naphthyl, the substituents being each independently selected from alkyl (C1-C8), alkoxy (C1-C8), aroxy, aralkoxy (C1-C8) and halogen. The process comprises reacting substituted phenols or naphthols of the formula (b) with ethylene carbonate in the presence of a first catalyst selected from metal halide, quaternary ammonium halide and quarternary phosphonium halide thereby forming an intermediate of the formula (c), then reacting the intermediate with a first compound selected from alkyl or aralkylhalide, alkyl or aralkyl sulfate, and alkyl or aralkyl sulfonate together with a metal hydroxide in the presence of a second catalyst, the second catalyst selected from quaternary ammonium salt or quaternary phosphonium salt.

3. 发明授权

EP1165325B1 THERMALLY-RESPONSIVE RECORD MATERIAL 有权
标题翻译：热响应记录材料
公开(公告)号：EP1165325B1
公开(公告)日：2006-02-08
申请号：EP00988156.6
申请日：2000-12-19
申请人： APPLETON PAPERS INC.
发明人： MATHIAPARANAM, Ponnampalam , DEBRAAL, John, Charles , FISHER, Mark, Robert , JUSTA MACNEIL, Stacey, Ann , BERGGREN, Debra, Arlene
IPC分类号： B41M5/30
CPC分类号： B41M5/3375 , C07C43/202 , C07C43/2055 , C07C43/225
摘要： The present invention is a novel thermally-responsive record material comprising a substrate having provided thereon in substantially contiguous relationship an electron donating dye precursor, an acidic developer material, a compound of formula (I) wherein P is selected from (II) and (III), wherein R1, R2 and R3 are independently selected from hydrogen, alkyl, alkoxy, aryl, aralkyl, aralkoxy, halogen, and alkoxyalkoxy; wherein R4 is independently selected from alkoxyalkyl, alkoxyalkoxy, and aralkoxyalkoxy, and a suitable binder therefor. In the context of the present invention the alkyl moieties in the alkyl, aralkyl, aralkoxy, alkoxyalkyl, alkoxyalkoxy and aralkoxyalkoxy preferably are eight carbons or less, and more preferably from one through four carbons. Substituents on aryl moieties in aryl, aralkyl, aralkoxy, and aralkoxyalkoxy groups can include hydrogen, alkyl, alkoxy and halogen. The alkyl group in these substituents also is eight carbons or less, and more preferably from one through four carbons. The thermally responsive record material of the invention has the unexpected and remarkable properties of enhanced image intensity or density, and/or improved thermal response.
摘要翻译：本发明是一种新颖的热响应记录材料，它包括其上以基本上邻接的关系提供给电子染料前体，酸性显影剂材料，其中P选自（II）和（III）的式（I）），其中R 1，R 2和R 3独立地选自氢，烷基，烷氧基，芳基，芳烷基，芳烷氧基，卤素和烷氧基烷氧基; 其中R 4独立地选自烷氧基烷基，烷氧基烷氧基和芳烷氧基烷氧基，以及适合的粘合剂。在本发明的上下文中，烷基，芳烷基，芳烷氧基，烷氧基烷基，烷氧基烷氧基和芳烷氧基烷氧基中的烷基部分优选为八个碳或更少，更优选1至4个碳。芳基，芳烷基，芳烷氧基和芳烷氧基烷氧基中的芳基部分上的取代基可以包括氢，烷基，烷氧基和卤素。这些取代基中的烷基也是8个碳以下，更优选1〜4个碳。本发明的热响应记录材料具有增强的图像强度或密度和/或改善的热响应的意想不到的和显着的性能。

4. 发明公开

EP1183224A1 PROCESS FOR PREPARING ALKOXY OR ARYLMETHOXY AROXYETHANES 有权
标题翻译：用于生产烷氧基或芳基甲氧基 - AROXYETHANEN
公开(公告)号：EP1183224A1
公开(公告)日：2002-03-06
申请号：EP01903473.5
申请日：2001-02-01
申请人： Appleton Papers Inc.
发明人： MATHIAPARANAM, Ponnampalam , BERGGREN, Debra Arlene
IPC分类号： C07C41/00 , C07C43/02 , C07C43/20
CPC分类号： C07C41/16 , C07C43/2055 , C07C43/225
摘要： The present invention is a novel process, with or without solvent, for manufacture of compounds of formula (a), wherein P is selected from phenyl and naphthyl; wherein R1 and R2 and R3 are each independently selected from hydrogen, alykl, alkoxy, aryl, aralkyl, aralkoxy, halogen, alkoxyalkoxy, and aralkoxyalkoxy; wherein R5 is selected from substituted or unsubstituted phenyl, and substituted or unsubstituted naphthyl, the substituents being each independently selected from alkyl (C1-C8), alkoxy (C1-C8), aroxy, aralkoxy (C1-C8) and halogen. The process comprises reacting substituted phenols or naphthols of the formula (b) with ethylene carbonate in the presence of a first catalyst selected from metal halide, quaternary ammonium halide and quarternary phosphonium halide thereby forming an intermediate of the formula (c), then reacting the intermediate with a first compound selected from alkyl or aralkylhalide, alkyl or aralkyl sulfate, and alkyl or aralkyl sulfonate together with a metal hydroxide in the presence of a second catalyst, the second catalyst selected from quaternary ammonium salt or quaternary phosphonium salt.

5. 发明公开

EP1165325A1 THERMALLY-RESPONSIVE RECORD MATERIAL 有权
标题翻译：热敏感AUFZEICHNUNGSMATRIAL
公开(公告)号：EP1165325A1
公开(公告)日：2002-01-02
申请号：EP00988156.6
申请日：2000-12-19
申请人： Appleton Papers Inc.
发明人： MATHIAPARANAM, Ponnampalam , DEBRAAL, John, Charles , FISHER, Mark, Robert , JUSTA MACNEIL, Stacey, Ann , BERGGREN, Debra, Arlene
IPC分类号： B41M5/20 , B41M5/24
CPC分类号： B41M5/3375 , C07C43/202 , C07C43/2055 , C07C43/225
摘要： The present invention is a novel thermally-responsive record material comprising a substrate having provided thereon in substantially contiguous relationship an electron donating dye precursor, an acidic developer material, a compound of formula (I) wherein P is selected from (II) and (III), wherein R1, R2 and R3 are independently selected from hydrogen, alkyl, alkoxy, aryl, aralkyl, aralkoxy, halogen, and alkoxyalkoxy; wherein R4 is independently selected from alkoxyalkyl, alkoxyalkoxy, and aralkoxyalkoxy, and a suitable binder therefor. In the context of the present invention the alkyl moieties in the alkyl, aralkyl, aralkoxy, alkoxyalkyl, alkoxyalkoxy and aralkoxyalkoxy preferably are eight carbons or less, and more preferably from one through four carbons. Substituents on aryl moieties in aryl, aralkyl, aralkoxy, and aralkoxyalkoxy groups can include hydrogen, alkyl, alkoxy and halogen. The alkyl group in these substituents also is eight carbons or less, and more preferably from one through four carbons. The thermally responsive record material of the invention has the unexpected and remarkable properties of enhanced image intensity or density, and/or improved thermal response.

6. 发明公开

EP1159242A1 MODIFIER COMPOUNDS 审中-公开
标题翻译：改性剂化合物
公开(公告)号：EP1159242A1
公开(公告)日：2001-12-05
申请号：EP01901719.3
申请日：2001-01-04
申请人： Appleton Papers Inc.
发明人： MATHIAPARANAM, Ponnampalam
IPC分类号： C07C43/20 , C07C43/225
CPC分类号： B41M5/3375 , C07C43/202 , C07C43/2055 , C07C43/225
摘要： The present invention is a novel class of compounds useful in thermally-responsive record material of the type comprising a substrate having provided thereon in substantially contiguous relationship an electron donating dye precursor, and an acidic developer material. The novel compound of the invention is a compound of the formula (I), wherein P is selected from (II) and (III) wherein R1 is selected from hydrogen, alkoxy, and aralkoxy; wherein R2 is aralkoxyalkoxy when P is phenyl, and R2 is selected from aralkoxyalkoxy or alkoxyalkoxy when P is naphthyl. Said alkyl moieties are each independently from one to eight carbons, said aryl moieties each independently being unsubstituted or substituted by alkyl (C1-C8), alkoxy (C1-C8) or halogen. The compounds of the invention enable manufacture of thermally responsive record material of the invention having the unexpected and remarkable properties of enhanced image intensity or density, and/or improved thermal response. The compounds of the invention also find use in diverse applications such as emolients and softening agents for creams, lots and cosmetics.

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