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    • 2. 发明公开
    • Improvements for reducing coke deposition in thermal upgrading processes
    • Vernelungsverfahren的热忱的呃,
    • EP0540793A1
    • 1993-05-12
    • EP91310328.9
    • 1991-11-07
    • ALBERTA OIL SANDS TECHNOLOGY AND RESEARCH AUTHORITY
    • Lott, Roger KaiLott, Roger KaiCyr, Theodore
    • C10G47/26C10G47/00C10G47/34
    • C10G47/00C10G47/26C10G47/34
    • In a hydrocracking process, a feed mixture comprising a heavy oil containing asphaltenes and sulfur moieties, an oil-soluble metal compound additive (e.g. Fe(CO)₅) which will impede coalescence of coke precursors, and a hydrocarbon diluent which is a solvent for the asphaltenes, is mixed and heated to a mild temperature (e.g. 150°C) to disperse the additive and associate it with the asphaltenes. The mixture is then further heated to hydrocracking temperature and reacted in a reactor wherein a prolific hydrogen flow is passed through the breadth and length of the charge to mix the charge and strip light ends. The combination of features results in impeding the evolution of coke precursors, so that a substantial proportion thereof remains in the agglomerate state, and in improving the conversion of the 504°C⁺ part of the feedstock.
    • 在加氢裂化过程中,包含含有沥青质和硫部分的重油的进料混合物,将阻碍焦炭前体聚结的油溶性金属化合物添加剂(例如Fe(CO)psi)和作为溶剂的烃稀释剂 将沥青质混合并加热至温和的温度(例如150℃)以分散添加剂并将其与沥青质相关联。 然后将混合物进一步加热至加氢裂化温度,并在反应器中进行反应,其中多余的氢气流通过电荷的宽度和长度以混合电荷并剥离光末端。 特征的组合导致阻碍焦炭前体的进化,使得其中相当大的比例保持在附聚状态,并且改善了504℃&原料和部分原料的转化率。