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    • 4. 发明公开
    • NOVEL POLYTHIOPHENE/POLYANION COMPOSITIONS
    • EP4279524A1
    • 2023-11-22
    • EP22174528.4
    • 2022-05-20
    • AGFA-GEVAERT NV
    • HERCKENS, RoaldLOCCUFIER, Johan
    • C08G61/12C09D165/00C08L65/00H01L51/00
    • A conductive polymer dispersion including:
      (a) at least one oligo- or polythiophene obtained by copolymerization of at least one monomer according to Formula I and at least one monomer according to Formula II,

      wherein
      A represents a substituted or unsubstituted C 1 to C 5 alkylene bridge;
      R is selected from the group consisting of a linear or branched substituted or unsubstituted C 1 -C 18 -alkyl group, a substituted or unsubstituted C 5 -C 12 -cycloalkyl group, a substituted or unsubstituted C 6 -C 14 -aryl group, a substituted or unsubstituted C 7 -C 18 -aralkyl group and a hydroxyl group;
      s represents an integer from 0 to 8;
      Ra and Rb are independently from each other selected from the group consisting of hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted alkaryl group and a substituted or unsubstituted aryl or heteroaryl group;

      (b) a polymeric polyanion wherein at least 75 mol% of the monomeric units of the polymeric polyanion are functionalized with a functional group selected from the group consisting of a sulfonic acid or salt thereof, a phosphonic acid or salt thereof, a phosphate ester or salt thereof, a sulfate ester or salt thereof and a carboxylic acid or salt thereof,
      characterized in that a weight ratio of the monomer according to Formula I to the monomer according to Formula II is from 75/25 to 25/75.