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    • 2. 发明公开
    • RUBBER-BASED MULTILAYER PRESSURE-SENSITIVE ADHESIVE ASSEMBLY HAVING LOW VOC CHARACTERISTICS
    • EP3336153A1
    • 2018-06-20
    • EP16204949.8
    • 2016-12-19
    • 3M Innovative Properties Company
    • Eckhardt, DoreenMatzeit, NiklasKluenker, EikeWaid, Robert DenisChastek, Thomas QBieber, PierreStegmaier, Petra
    • C09J7/02
    • C09J7/26C09J7/22C09J7/38C09J133/04C09J153/00C09J2201/622C09J2400/243C09J2433/00C09J2453/00C09J2453/006
    • The present disclosure relates to a multilayer pressure sensitive adhesive assembly comprising a polymeric foam layer and a first pressure sensitive adhesive layer adjacent to the polymeric foam layer, wherein the polymeric foam comprises:
      a) a multi-arm block copolymer having the formula Q n -Y, wherein:
      (i) Q represents an arm of the multi-arm block copolymer and each arm independently has the formula G-R,
      (ii) n represents the number of arms and is a whole number of at least 3, and
      (iii) Y is the residue of a multifunctional coupling agent,
      wherein each R is a rubbery block comprising a polymerized conjugated diene, a hydrogenated derivative of a polymerized conjugated diene, or combinations thereof; and each G is a glassy block comprising a polymerized monovinyl aromatic monomer;
      b) a polymeric plasticizer having a weight average molecular weight Mw of at least 10.000 g/mol;
      c) at least one hydrocarbon tackifier, wherein the hydrocarbon tackifier(s) have a Volatile Organic Compound (VOC) value of less than 1000 ppm, when measured by thermogravimetric analysis according to the weight loss test methods described in the experimental section; and
      d) optionally, a linear block copolymer having the formula L - (G) m , wherein L is a rubbery block comprising a polymerized olefin, a polymerized conjugated diene, a hydrogenated derivative of a polymerized conjugated diene, or any combinations thereof; and wherein m is 1 or 2;
      and wherein the first pressure sensitive adhesive comprises:
      a) a linear block copolymer having the formula M - (G) p , wherein M is a rubbery block comprising a polymerized olefin, a polymerized conjugated diene, a hydrogenated derivative of a polymerized conjugated diene, or any combinations thereof; and wherein p is 1 or 2;
      b) at least one second hydrocarbon tackifier;
      c) a (meth)acrylate copolymer having a Tg higher than 25°C and a weight average molecular weight (Mw) comprised between 1000 and 100.000 Daltons, and comprising:
      (i) (meth)acrylic acid ester monomer units having a Tg higher than 25°C when homopolymerized; and
      (ii) optionally, monofunctional ethylenically unsaturated comonomer units;

      d) optionally, a multi-arm block copolymer having the formula Sq-Z, wherein:
      (i) S represents an arm of the multi-arm block copolymer and each arm independently has the formula G-N,
      (ii) q represents the number of arms and is a whole number of at least 3, and
      (iii) Z is the residue of a multifunctional coupling agent,
      wherein each N is a rubbery block comprising a polymerized conjugated diene, a hydrogenated derivative of a polymerized conjugated diene, or combinations thereof; and
      e) optionally, a diblock copolymer having the formula T - (G), wherein T is a rubbery block comprising a polymerized olefin, a polymerized conjugated diene, a hydrogenated derivative of a polymerized conjugated diene, or any combinations thereof.
      The present disclosure also relates to a method of manufacturing such a multilayer pressure sensitive adhesive assembly and uses thereof.