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1. 发明授权

EP2716910B1 DISC-TYPE SOLAR STIRLING ENGINE POWER GENERATION DEVICE CAPABLE OF OPERATING CONTINUOUSLY DAY AND NIGHT 有权
公开(公告)号：EP2716910B1
公开(公告)日：2020-02-05
申请号：EP12789424.4
申请日：2012-05-23
申请人： Wuhan Kaidi Engineering Technology Research Institute Co., Ltd.
发明人： CHEN, Yilong , YANG, Qingping , ZHANG, Yanfeng
IPC分类号： F03G6/00 , F02G1/043 , F03G6/02 , F03G6/06

2. 发明授权

EP2883940B1 METHOD AND DEVICE FOR BIOMASS GASIFICATION BY CYCLING OF CARBON DIOXIDE WITHOUT OXYGEN 有权
公开(公告)号：EP2883940B1
公开(公告)日：2018-09-26
申请号：EP13827090.5
申请日：2013-07-11
申请人： Wuhan Kaidi Engineering Technology Research Institute Co., Ltd.
发明人： ZHANG, Yanfeng , ZHANG, Liang , XIA, Minggui , LIU, Wenyan
IPC分类号： C10J3/00 , C10K3/00
CPC分类号： C10J3/82 , C10G2/32 , C10G2/34 , C10G2300/1011 , C10J3/482 , C10J3/72 , C10J2200/15 , C10J2300/0916 , C10J2300/0969 , C10J2300/123 , C10J2300/1238 , C10J2300/1269 , C10J2300/1292 , C10J2300/1659 , C10J2300/1693 , C10J2300/1815 , C10J2300/1861 , C10J2300/1884 , C10J2300/1892 , C10K1/004 , C10K1/02 , C10K1/026 , C10K1/08 , C10K3/04 , Y02E50/32 , Y02P20/129 , Y02P20/134 , Y02P20/145 , Y02P30/20
摘要： Disclosed are a method and a device for biomass gasification by cycling of carbon dioxide without oxygen. Concretely the method and the device are integrated, wherein carbon dioxide is used as the only gasifying agent for gasifying biomass and other solid fuels into high-quality synthesis gas, the carbon dioxide in the synthetic gases is recovered, and the carbon dioxide produced in the succeeding process using the synthetic gases is recycled for gasification. The purpose of zero emission of carbon dioxide of the whole system is achieved. The advantages of no oxygen consumption, the production of high-quality synthesis gas, high cold gas efficiency and simple operation are achieved. Zero emission of carbon dioxide of the whole system is achieved.

3. 发明授权

EP2865731B1 METHOD FOR FISCHER-TROPSCH SYNTHESIS AND FOR UTILIZING EXHAUST 有权
标题翻译：用于费氏合成和利用排放的方法
公开(公告)号：EP2865731B1
公开(公告)日：2017-10-04
申请号：EP13810561.4
申请日：2013-04-25
申请人： Wuhan Kaidi Engineering Technology Research Institute Co., Ltd.
发明人： CHEN, Yilong , SONG, Kan , KUAI, Pingyu , ZHANG, Yanfeng , JIN, Jiaqi
IPC分类号： C10G2/00 , B01D53/047 , C07C9/04 , C07C7/12 , C01B3/50 , C10K3/00 , C10K1/32 , C01B3/56 , C01B3/34
CPC分类号： C10G2/40 , B01D53/047 , B01D2257/108 , B01D2257/7025 , C01B3/34 , C01B3/56 , C01B2203/0283 , C01B2203/043 , C01B2203/062 , C01B2203/148 , C10G2/332 , C10G2300/4081 , C10K1/32 , C10K3/00 , Y02C20/20 , Y02P20/156

4. 发明授权

EP2799522B1 MICROWAVE PLASMA BIOMASS ENTRAINED FLOW GASIFIER AND PROCESS 有权
标题翻译：微波等离子体生物质气流床气化炉及工艺
公开(公告)号：EP2799522B1
公开(公告)日：2017-09-20
申请号：EP12863948.1
申请日：2012-10-26
申请人： Wuhan Kaidi Engineering Technology Research Institute Co., Ltd.
发明人： CHEN, Yilong , ZHANG, Yanfeng , XIA, Minggui , ZHANG, Liang
IPC分类号： C10J3/46 , C10J3/48 , C10J3/18 , C10J3/50 , C10J3/72
CPC分类号： C10J3/72 , C10J3/18 , C10J3/466 , C10J3/485 , C10J3/506 , C10J3/723 , C10J2200/152 , C10J2300/0906 , C10J2300/0916 , C10J2300/0959 , C10J2300/0976 , C10J2300/1238 , Y02P20/145
摘要： A microwave plasma biomass entrained flow gasifier comprising a gasifier body (8), a fuel inlet arranged at the lower part of the gasifier body (8), a synthetic gas outlet at the top part of the gasifier body (8), and a slag discharge outlet (10) at the bottom part of the gasifier body (8). Arranged outside the gasifier body (8) is a fuel preprocessing system, comprising a fuel crushing apparatus (1), a sieving apparatus (2) arranged downstream to the fuel crushing apparatus (1), a particle diameter-qualified fuel chamber (3) and a particle diameter-unqualified fuel chamber (4) arranged in parallel and downstream to the sieving apparatus (2), and a gasifier-front chamber arranged downstream to the particle diameter-qualified fuel chamber (3), where the gasifier-front chamber (5) is connected at the bottom part thereof to the gasifier body (8) via a burner. Arranged at the synthesis gas outlet (9) at the top part of the gasifier is a synthesis gas monitoring unit (12). Also provided is a process utilizing the gasifier for biomass entrained flow gasification. The process comprises: 1) a biomass fuel is preprocessed; 2) a microwave plasma working gas is introduced into a plasma generator, excited into plasma then injected into the gasifier; 3) biomass fuel powdery particles are injected into the gasifier via the burner, while at the same time, an oxidizer is fed into the system via an oxygen/steam inlet, injected into the gasifier simultaneously with the biomass fuel, the biomass fuel is subjected to a thermochemical reaction within the gasifier; 4) the temperature and content of the synthesis gas are monitored for implementing adjustments in oxygen flow rate, steam flow rate, and microwave power; the temperature at the synthesis gas outlet is between 900°C and 1200°C; finally, the synthesis gas is drawn out from the synthesis gas outlet at the top part, while at the same time a liquid slag is discharged via the slug discharge outlet.
摘要翻译：本发明公开了一种微波等离子体生物质夹带流气化炉，包括气化炉体（8），设置在气化炉体（8）下部的燃料入口，气化炉体（8）顶部的合成气出口，炉渣排气口10位于气化器本体8的底部。燃料预处理系统包括燃料破碎装置（1），布置在燃料破碎装置（1）下游的筛分装置（2），颗粒直径合格的燃料室（3）（2）平行且下游布置的粒径不合格燃料室（4）以及布置在粒径合格燃料室（3）下游的气化器前室，其中气化器前室（5）的底部通过燃烧器连接到气化器本体（8）。合成气监测单元（12）设置在气化器顶部的合成气出口（9）处。还提供了利用气化器进行生物质夹带气流的方法。该过程包括：1）对生物质燃料进行预处理; 2）将微波等离子体工作气体引入等离子体发生器，激发成等离子体，然后注入气化器; 3）通过燃烧器将生物质燃料粉末颗粒注入气化器中，同时经由氧气/蒸汽入口将氧化剂供给到系统中，与生物质燃料同时注入到气化器中，生物质燃料经受到气化器内的热化学反应; 4）监测合成气的温度和含量，以实施氧气流量，蒸汽流量和微波功率的调整; 合成气出口处的温度在900℃和1200℃之间; 最后，合成气从顶部的合成气出口排出，同时液渣通过排渣口排出。

5. 发明公开

EP3144063A1 CATALYST SUITABLE FOR PRODUCTION OF AVIATION KEROSENE FROM BIOMASS FISCHER-TROPSCH SYNTHESIS OIL AND PREPARATION METHOD THEREFOR 审中-公开
标题翻译：催化剂的平面煤油费 - 托生物质合成油和方法及其制备
公开(公告)号：EP3144063A1
公开(公告)日：2017-03-22
申请号：EP15792560.3
申请日：2015-02-06
申请人： Wuhan Kaidi Engineering Technology Research Institute Co., Ltd.
发明人： WANG, Wanwan , SONG, Dechen , XU, Li
IPC分类号： B01J29/48 , B01J37/02 , C10G49/04 , C10G49/08
CPC分类号： B01J29/7884 , B01J29/076 , B01J29/48 , B01J35/002 , B01J35/026 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J37/0018 , B01J37/009 , B01J37/02 , B01J37/0201 , B01J37/04 , B01J37/06 , B01J37/08 , B01J37/343 , B01J2229/16 , B01J2229/20 , B01J2229/36 , B01J2229/40 , B01J2229/42 , B01J2523/00 , C10G49/04 , C10G49/08 , C10G2300/1022 , C10G2300/1081 , B01J2523/68 , B01J2523/847
摘要： Disclosed are a catalyst suitable for production of aviation kerosene from biomass Fischer-Tropsch synthesis oil and a preparation method therefor. Various components by weight in percentage in the catalyst are: 20-50% of an amorphous aluminum-silicon, 5-20% of an aluminum oxide binder, 20-60% of a hydrothermally modified ZSM-22 molecular sieve, 0.5-5% of nickel oxide, and 5-15% of molybdenum oxide. The preparation method is as follows: firstly performing an NH4 + exchange treatment on the K-ZSM-22 molecular sieve to obtain an H-ZSM-22 molecular sieve, then performing a hydrothermal treatment to obtain a modified H-ZSM-22 molecular sieve, and then after uniform mixing with the amorphous aluminum-silicon, adding the aluminum oxide binder and a sesbania powder, mixing and kneading same, grinding into clusters, forming same by band extrusion, then drying and calcinating same, and finally loading active metals Ni and Mo. The catalyst obtained from the present invention has a high activity and a high selectivity, increases the isomerization degree of long-chain alkanes, reduces the freezing points of the fractions of aviation kerosene, and improves the yield of the aviation kerosene.
摘要翻译：本发明公开了适合用于从生物质生产航空煤油的催化剂的费 - 托合成油和用于其的制备方法。在催化剂百分比各种组分按重量计是：无定形铝 - 硅的20-50％，氧化铝粘合剂的5-20％，水热改性的ZSM-22分子筛的20-60％，0.5-5％的氧化镍和氧化钼的5-15％。的制备方法如下：首先进行上NH4 +交换处理的K-ZSM-22分子筛，以获得在H-ZSM-22分子筛，然后进行水热处理，从而获得改性的H-ZSM-22分子筛，再经过均匀的无定形铝 - 硅混合，添加氧化铝粘合剂和田菁粉，混合和捏合相同，研磨成群集，通过色带挤出成型相同，然后将其干燥和煅烧相同，最后加载活性金属镍和Mo从本发明得到的催化剂具有高活性和高选择性，增加长链烷烃的异构化率，减少航空煤油馏分的凝固点，提高了航空煤油的产率。

6. 发明公开

EP2374863A1 HIGH TEMPERATURE GASIFYING PROCESS WITH BIOMASS AND SYSTEM THEREOF 有权
标题翻译： VERFAHREN UND SYSTEM ZUR HERSTELLUNG VON SYNTHESEGAS AUS BIOMASSE
公开(公告)号：EP2374863A1
公开(公告)日：2011-10-12
申请号：EP09829990.2
申请日：2009-10-30
申请人： Wuhan Kaidi Engineering Technology Research Institute Co., Ltd.
发明人： ZHAO, Feng , ZHANG, Haiqing , SUN, Qin , QIU, Peng , LI, Hong
IPC分类号： C10J3/00 , C10B53/02 , B09B3/00
CPC分类号： C10J3/66 , C10J3/506 , C10J2200/152 , C10J2300/0916 , C10J2300/094 , Y02E50/14 , Y02P20/145
摘要： High temperature gasifying process with biomass includes feeding, carbonization, powder making of charcoal, transporting of powdery charcoal and gasifying in gasifier, wherein carbonization is carried out in the carbonization furnace for pyrolysis of biomass with the heat released by the direct combustion of additionally provided combustible gas and oxygen, the product of carbonization is pyrolysis gas and charcoal. The temperature in the carbonization furnace is controlled at 400~600°C through adjusting the amount of oxygen, the molar number of combustible gas is greater than 1 and less than 5 based on that the molar number of combustible gas is 1 when it is completely combusted with oxygen. The temperature of the flame at the nozzle of the carbonization furnace is controlled at 1800~1200°C through adjusting the amount of additionally provided combustible gas entering into the carbonization furnace. Powdery charcoal is formed through reducing the temperature of charcoal, reducing pressure, powder making, increasing pressure and fluidization, and the powdery charcoal is sent to gasifier through adjusting the transportation amount of the pyrolysis gas. The system for performing the process includes a carbonizing furnace, a powder-making system and so on.
摘要翻译：具有生物质的高温气化过程包括进料，碳化，活性炭粉制造，粉状木炭运输和气化炉气化，其中碳化在炭化炉中进行，用于通过直接燃烧释放的热量附加提供的可燃物气体和氧气，碳化产物是热解气和木炭。通过调节氧气量，碳化炉中的温度控制在400〜600℃，可燃气体的摩尔数大于1且小于5，基于完全可燃气体的摩尔数为1时与氧燃烧。通过调节进入碳化炉的额外提供的可燃气体的量，将碳化炉喷嘴处的火焰温度控制在1800〜1200℃。通过降低木炭的温度，降低压力，制粉，增加压力和流化而形成粉状木炭，通过调节热解气的输送量将粉状木炭送入气化炉。用于执行该方法的系统包括碳化炉，粉末制造系统等。

7. 发明授权

EP2995672B1 METHOD FOR MODIFYING BIOMASS PYROLYSIS OIL 有权
公开(公告)号：EP2995672B1
公开(公告)日：2018-07-11
申请号：EP14794452.4
申请日：2014-04-09
申请人： Wuhan Kaidi Engineering Technology Research Institute Co., Ltd.
发明人： WANG, Dashan , SONG, Dechen , LIU, Qianqian , ZHENG, Shenke , ZHAN, Xiaodong , JIN, Jiaqi , ZHANG, Yanfeng
IPC分类号： C10G55/06 , B01J37/10 , C10G33/04 , C10G11/18 , B01D17/04 , C10L1/02 , C10B53/02 , C10G3/00 , B01J29/08 , B01J29/40
CPC分类号： C10G3/49 , B01D17/047 , B01J29/088 , B01J29/405 , B01J2229/186 , B01J2229/36 , B01J2229/42 , C10B53/02 , C10G11/18 , C10G33/04 , C10G2300/1011 , C10L1/02 , Y02E50/14 , Y02P30/20
摘要： Provided is a method for modifying a biomass pyrolysis oil, which specifically comprises the following steps: a first step of demulsification, layering, and dehydration: adding an inorganic salt ion and an organic demulsifier into the biomass pyrolysis oil, wherein the mass ratio of the inorganic salt to the biomass pyrolysis oil is 1:2000-1:800, the mass ratio of the organic demulsifier to the biomass pyrolysis oil is 1:4000-1:1000, after mixing sufficiently, standing and taking the upper layer of biomass pyrolysis oil; a second step of performing a catalytic cracking modification on the biomass pyrolysis oil: using a modified catalyst: 1) modifying a catalyst: performing an ageing treatment on a carclazyte catalyst supported on a zeolite molecular sieve for 2-8 h with 100% water vapour under the condition of 500-800°C; and 2) placing the aged catalyst into a reactor, injecting the biomass pyrolysis oil into the reactor filled with the catalyst, with a catalyst-to-oil ratio of 1:3-16, and performing a catalytic cracking modification on the biomass pyrolysis oil under the conditions of a mass airspeed of 6-15 h -1 , a reaction temperature of 380-700°C and a reaction pressure of 0.1-0.8 Mpa.

8. 发明公开

EP3315588A1 ULTRA HIGH PRESSURE COOLING AND PURIFICATION PROCESS AND APPARATUS FOR OIL PRODUCTION BIOMASS SYNGAS 审中-公开
标题翻译：超高压冷却和净化生产生物质合成气的方法和设备
公开(公告)号：EP3315588A1
公开(公告)日：2018-05-02
申请号：EP16813569.7
申请日：2016-04-15
申请人： Wuhan Kaidi Engineering Technology Research Institute Co., Ltd.
发明人： ZHANG, Yanfeng , NIE, Hongtao , XIA, Minggui , LIU, Wenyan , ZHANG, Liang
IPC分类号： C10J3/84 , C10K1/10 , C10K1/04 , C10K1/02
CPC分类号： C10K1/026 , B01J47/14 , B03C3/014 , C10J3/20 , C10J3/723 , C10J3/84 , C10J3/86 , C10J2300/0916 , C10J2300/1693 , C10J2300/1884 , C10J2300/1892 , C10K1/02 , C10K1/04 , C10K1/046 , C10K1/10 , C10K1/101 , Y02P20/129
摘要： An ultra high pressure cooling and purification process and apparatus for an oil production biomass syngas, the process comprising: (1) performing two-stage waste heat recovery and cyclone dust removal processing, with by-products of high pressure and low pressure steam, (2) removing a portion of heavy tar precipitated out from the biomass syngas by cooling in a second stage indirect heat exchange process, (3) further removing dust and lowering a temperature using a washing solution, (4) conducting deep removal of dust and coke using a moist air flow, and purging to remove remaining small amounts of dust and tar fog in the biomass syngas, and causing the pressure thereof to drop to 0.3-1 MPa, so as to obtain a biomass syngas having respective dust and tar fog contents of less then 10 mg/Nm3, and a temperature of
摘要翻译：一种用于采油生物质合成气的超高压冷却和净化工艺及设备，所述工艺包括：（1）利用高压和低压蒸汽的副产品进行两阶段余热回收和旋风除尘处理，（ 2）通过在第二阶段间接热交换过程中冷却从生物质合成气中除去部分重质焦油，（3）使用洗涤溶液进一步除去灰尘并降低温度，（4）深度除去灰尘和焦炭使用潮湿的空气流，并吹扫以去除生物质合成气中残留的少量灰尘和焦油雾，并使其压力降至0.3-1MPa，从而获得具有相应灰尘和焦油雾含量的生物质合成气小于10mg / Nm 3，温度<45℃。该设备主要由集成热交换和除尘装置，填料塔洗涤器和湿式静电除尘器组成。本发明通过优化工艺方案设计，控制合适的工艺参数，实现了生物质合成气的阶梯式冷却，分阶段回收废热，分阶段除尘，达到了脱焦，冷却，净化的目的。

9. 发明公开

EP3284539A1 HIGH-PRESSURE PULVERIZER 审中-公开
标题翻译：高压粉碎机
公开(公告)号：EP3284539A1
公开(公告)日：2018-02-21
申请号：EP16779620.0
申请日：2016-04-15
申请人： Wuhan Kaidi Engineering Technology Research Institute Co., Ltd.
发明人： TAN, Ninggang , NIU, Xiangshan , ZHANG, Yong
IPC分类号： B02C7/08
CPC分类号： B02C7/08 , B02C7/11 , B02C15/00 , B02C15/08 , B02C2210/02
摘要： Disclosed is a high-pressure pulverizer, which comprises a pulverizer body (1) and an electric motor (2). A high-pressure container (3) is arranged outside the pulverizer body (1). A sealed space is formed between the high-pressure container (3) and the pulverizer body (1). A feeding port (3a) is formed in an outer wall of an upper portion of the high-pressure container (3). The feeding port (3a) is in sealed communication with a feeding pipe of the pulverizer body (1) through a soft feeding joint (4). A discharging port (3b) is formed in an outer wall of a lower portion of the high-pressure container (3). The discharging port (3b) is in sealed communication with a discharging pipe of the pulverizer body (1) through a soft discharging joint (5). A bearing base (6) is arranged at the bottom of the high-pressure container (3). The pulverizer body (1) is mounted on the bearing base (6) through a shock pad (7). A connecting shaft (8) is movably inserted into the top of the high-pressure container (3) in a sealed manner. The upper end of the connecting shaft (8) is in transmission connection with an output shaft of the electric motor (2). The lower end of the connecting shaft is connected to a main shaft of the pulverizer body (1). When the pulverizer is operating, high-pressure inert media is provided in a sealed space between the pulverizer body (1) and the high-pressure container (3). The pressure of the inert media is greater than or equal to the pressure in the pulverizer body (1). The pulverizer is suitable for pulverizing materials such as coal and non-metallic ore.
摘要翻译：公开了一种高压粉碎机，其包括粉碎机本体（1）和电动机（2）。粉碎机本体（1）的外部设有高压容器（3）。在高压容器（3）和粉碎机本体（1）之间形成密封空间。进料口（3a）形成在高压容器（3）的上部的外壁中。进料口（3a）通过软进料接头（4）与粉磨机本体（1）的进料管道密封连通。排放口（3b）形成在高压容器（3）的下部的外壁中。排放口（3b）通过软排放接头（5）与粉碎机本体（1）的排放管密封连通。轴承座（6）设置在高压容器（3）的底部。粉碎机本体（1）通过减震垫（7）安装在轴承座（6）上。连接轴（8）以密封的方式可移动地插入高压容器（3）的顶部。连接轴（8）的上端与电动机（2）的输出轴传动连接。连接轴的下端连接到粉碎机本体（1）的主轴。当粉碎机运行时，高压惰性介质被提供在粉碎机本体（1）和高压容器（3）之间的密封空间中。惰性介质的压力大于或等于粉碎机本体（1）中的压力。该粉碎机适用于粉碎煤和非金属矿石等物料。

10. 发明公开

EP3266854A1 DIESEL OIL AND JET FUEL PRODUCTION SYSTEM AND METHOD UTILIZING FISCHER-TROPSCH SYNTHETIC OIL 审中-公开
标题翻译：柴油和喷射燃料生产系统及利用费歇尔合成油的方法
公开(公告)号：EP3266854A1
公开(公告)日：2018-01-10
申请号：EP16758449.9
申请日：2016-02-26
申请人： Wuhan Kaidi Engineering Technology Research Institute Co., Ltd.
发明人： ZHAO, Tao , LAI, Bo , YANG, Weiguang , WANG, Dawei , HAO, Xuewen , ZHOU, Yanjie , XU, Li
IPC分类号： C10G67/00 , C10G45/02 , C10G47/00
CPC分类号： C10G67/02 , B01J19/245 , B01J2219/24 , C10G45/02 , C10G47/00 , C10G65/12 , C10G65/14 , C10G2300/1022 , C10G2400/04
摘要： A diesel oil and jet fuel production system and method utilizing Fischer-Tropsch synthetic oil. The method comprises two parts, hydrofining and hydro-upgrading, and comprises the following steps: mixing a Fischer-Tropsch synthetic oil with hydrogen and introducing the same into a hydrofining reactor (A), and introducing a product thereof into a first fractionating tower (C); taking a cut naphtha fraction as an ethylene cracking raw material, and introducing a diesel fraction into a hydroisomerization reactor (E); introducing an unconverted oil into a hydrocracking reactor (D), mixing the products of the two reactors and then introducing the mixed products into a second fractionating tower (F) to obtain a jet fuel and diesel oil product, and circulating the unconverted oil to the hydrocracking reactor (D). The method can produce diesel oil, jet fuel and a hydrotreating wax oil product, has a simple technique, a stable process, low equipment investment, low costs, a long running period, and a high yield of diesel oil and jet fuel which can directly serve as fuel or blending components.
摘要翻译：一种利用费托合成油的柴油和喷气燃料生产系统和方法。该方法包括加氢精制和加氢精制两部分，包括以下步骤：将费 - 托合成油与氢气混合并将其引入加氢精制反应器（A）中，并将其产物引入第一分馏塔（ C）; 取出石脑油馏分作为乙烯裂解原料，并将柴油馏分引入加氢异构化反应器（E）中; 将未转化的油引入加氢裂化反应器（D）中，混合两个反应器的产物，然后将混合产物引入第二分馏塔（F）以获得喷气燃料和柴油产物，并将未转化的油循环至加氢裂化反应器（D）。该方法可生产柴油，喷气燃料和加氢蜡蜡油产品，工艺简单，工艺稳定，设备投资少，成本低，运行周期长，柴油和喷气燃料的产率高，可直接使用作为燃料或混合成分。

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