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1. 发明公开

EP1819870A1 METHOD FOR IMPROVING ARAMID YARN BUNDLES COHESIVENESS 有权转让
标题翻译：方法提高ARAMIDFADENBÜNDELN的凝聚力
公开(公告)号：EP1819870A1
公开(公告)日：2007-08-22
申请号：EP05818008.4
申请日：2005-11-26
申请人： Teijin Twaron B.V.
发明人： WILLEMSEN, Stephanus , PETERS, Martinus , JANSSEN, Johannes
IPC分类号： D06M15/568 , D06M15/572 , D06M15/507 , B60R21/16
CPC分类号： D06M15/568 , D06M7/00 , D06M15/5075 , D06M15/572 , D06M2101/36 , D06M2200/40
摘要： The invention pertains to a method for improving bundle cohesiveness of a bundle of aramid yarns and decreasing its friction coefficient, comprising adding to the bundle of yarns 0.1 - 3.0 wt.%, based on the yarn weight, of a water-soluble or water-dispersible film forming binding agent, followed by treating the bundle of yarns with an oil having an intrinsic viscosity less than 100 mm2/s.

2. 发明公开

EP1694890A1 ARAMID FIBRILS 有权转让
标题翻译： ARAMIDFIBRILLEN
公开(公告)号：EP1694890A1
公开(公告)日：2006-08-30
申请号：EP04820409.3
申请日：2004-11-30
申请人： Teijin Twaron B.V.
发明人： HENDRIKS, Anton, Johannes, Josef , TIECKEN, Jan, Davis, Cornelis , GROTENDORST, Harrie , JOURNEE, René , OLDENZEEL, Mirjam, Ellen
IPC分类号： D01F6/60
CPC分类号： D21H13/26 , D01F6/605 , Y10T428/29 , Y10T428/2904 , Y10T428/2933 , Y10T428/2969
摘要： The invention relates to aramid fibrils having in the wet phase a Canadian Standard Freeness (CSF) value less than 100 ml, after drying a specific surface area (SSA) less than 7 m2/g, and a weight weighted length for particles having a length > 250 µm (WL 0.25) less than 1.2 mm, and to a method of preparing the fibrils comprising the steps a. polymerizing an aromatic diamine and an aromatic dicarboxylic acid halide to an aramid polymer, in a mixture of N-methylpyrrolidone or dimethyl- acetamide and calcium chloride or lithium chloride to obtain a dope wherein the polymer is dissolved in the mixture and the polymer concentration is 2 to 6 wt. %, b. converting the dope to fibrils by using a jet spin nozzle under a gas stream, and c. coagulating the fibrils using a coagulation jet.

3. 发明公开

EP1664161A1 TWO-STEP METHOD FOR DIPPING SYNTHETIC FIBER 审中-公开
标题翻译：两个步骤潜水人工合成
公开(公告)号：EP1664161A1
公开(公告)日：2006-06-07
申请号：EP04764828.2
申请日：2004-09-04
申请人： Teijin Twaron B.V.
发明人： WATANABE, Hirosuke
IPC分类号： C08J5/06 , D06M13/395 , D06M13/02 , C08L21/00
CPC分类号： C08J5/06 , C08J2321/00 , C08L53/02 , D06M13/02 , D06M13/395 , D06M15/356 , D06M15/41 , Y10T428/2913 , Y10T428/2929 , Y10T428/2933
摘要： The invention relates to a two-step method for dipping a synthetic fiber wherein the fiber is first dipped with an aqueous pre-dip composition followed by a dip with resorcinol-formaldehyde latex (RFL) composition, characterized in that the pre-dip composition comprises a blocked isocyanate having at least tri-functional isocyanate groups and a latex wherein the ratio by weight of blocked isocyanate and latex is between 9 and 0.7, preferably between 4 and 1. The invention further pertains to a pre-dip composition for dipping a synthetic fiber, comprising a blocked at least tri-functional isocyanate compound and a latex, further comprising water, an emulsifier, and 2-vinyl pyridine copolymer and to a fiber, cord, and composite article of rubber and fiber or cord, wherein the fiber or cord has distributed over at least a surface portion thereof (1) blocked tri-functional isocyanate compound, preferably HDI-trimer; (2) an RFL adhesive; and (3) an in situ vulcanized rubber compound.

4. 发明公开

EP1966319A2 METHOD FOR OBTAINING PARA-TYPE WHOLLY AROMATIC PARTICLES 有权转让
标题翻译：程序，以获取全部芳香族颗粒对位
公开(公告)号：EP1966319A2
公开(公告)日：2008-09-10
申请号：EP06831788.2
申请日：2006-12-21
申请人： Teijin Twaron B.V.
发明人： TORU, Kurino , KOSAKU, Asagi
IPC分类号： C08L77/10 , C08J3/12
CPC分类号： C08L77/10 , C08J3/12 , C08J3/14 , C08J2377/10 , Y10T428/29
摘要： The invention pertains to a method for obtaining para-type wholly aromatic polyamide particles, comprising the steps: a) introducing an aramid polymer solution into a water-based coagulating liquid to obtain a hydrous shaped product; and b) subjecting the never-dried or partly-dried shaped product having a water content of 10 to 99% by weight to freeze-grinding. These aramid polymer particles can be used as a filler material.

5. 发明授权

EP1737905B1 COMPOSITE MATERIALS COMPRISING PPTA AND NANOTUBES 有权
标题翻译：包含PPTA和纳米管的复合材料
公开(公告)号：EP1737905B1
公开(公告)日：2007-10-24
申请号：EP05739601.2
申请日：2005-03-18
申请人： Teijin Twaron B.V.
发明人： BOERSTOEL, Hanneke , SWIERENGA, Hendrik , KLINKHAMER, Aart
IPC分类号： C08K7/24 , C08K7/00 , D01D5/04
CPC分类号： D01F1/02 , B82Y30/00 , D01D1/02 , D01F6/605 , Y10T428/249924 , Y10T428/24994 , Y10T428/2913 , Y10T428/2927 , Y10T428/30
摘要： The invention pertains to a composite material comprising PPTA (poly-p-phenyleneterephthalamide) and nanotubes having an aspect ratio of at least 100 and a cross sectional diameter of 5 nm or less, the composite material containing up to12 wt.% of nanotubes, obtainable by adding the nanotubes to sulfuric acid, decreasing the temperature to solidify the mixture, adding PPTA to the solid mixture, heating to above the solidifying point and mixing the mixture, and spinning, casting, or molding the mixture to the composite material. The process comprises the steps: a) adding nanotubes having an aspect ratio of at least 100 and a cross-sectional diameter of 5 nm or less to sulfuric acid at a temperature above the solidifying point of the sulfuric acid; b) decreasing the temperature to below the solidifying point of the sulfuric acid and mixing for a sufficient time to solidify the mixture; c) adding PPTA to the solid mixture; and d) heating to above the solidifying point and mixing the mixture.
摘要翻译：本发明涉及包含PPTA（聚对苯二甲酰对苯二胺）和长径比为至少100且横截面直径为5nm或更小的纳米管的复合材料，所述复合材料含有至多12重量％的纳米管，可获得通过将纳米管添加到硫酸中，降低温度以固化混合物，向固体混合物中加入PPTA，加热至高于凝固点并混合混合物，并将混合物纺丝，浇铸或模塑成复合材料。该方法包括以下步骤：a）在高于硫酸凝固点的温度下，将具有至少100的纵横比和5nm或更小的横截面直径的纳米管添加到硫酸; b）将温度降低至低于硫酸的凝固点并混合足够时间以固化混合物; c）向固体混合物中加入PPTA; 和d）加热至高于凝固点并混合混合物。

6. 发明公开

EP1831287A1 METHOD FOR PRODUCING A LOW REDUCING AGENT-CONTAINING KERATIN AND PRODUCTS THEREOF 审中-公开
标题翻译：用于生产角蛋白低的还原剂添加量及其制品
公开(公告)号：EP1831287A1
公开(公告)日：2007-09-12
申请号：EP05816434.4
申请日：2005-11-26
申请人： Teijin Twaron B.V.
发明人： FLORIS, Theodorus, Arnoldus, Gerardus , SLANGEN, Karel, Joseph , BOS, Martin, Thomas, Alexander
IPC分类号： C08H1/06 , C08L89/04
CPC分类号： C08H1/06
摘要： The invention pertains to a method for producing a low reducing agent-containing keratin, comprises the steps of (a) cleaving disulfide (CysS-SCys) bonds in a keratin-containing starting material, using a reducing agent in an aqueous medium, to obtain an intermediate keratin product wherein at least 90% of cleaved disulfide bonds have the structure CysS' or CysSH; (b) removing excess of reducing agent at a pH between 9 and 14 to obtain an aqueous solution or dispersion of keratin having a ratio R of at least 10%, wherein R = 100*([CysS'] + [CysSH])/([CysS'] + [CysSH] + 2[CysS-SCys]); and (c) optionally, removing water to obtain a keratin-containing dispersion, powder, or granule. The invention further relates to products such as aqueous solutions, dispersions, powders, granulates, and the use of the keratin obtained in the 15 preparation of foam, shaped articles, and formulations.

7. 发明公开

EP1743964A1 Cord 有权
标题翻译：绳
公开(公告)号：EP1743964A1
公开(公告)日：2007-01-17
申请号：EP05015392.3
申请日：2005-07-15
申请人： Teijin Twaron B.V. , Toho Tenax Europe GmbH
发明人： Schwung, Klaus Peter , Wohlmann, Bernd, Dr. , Peters, Maria Gemma Martinus Wilhelmus , Janssen, Johannes Theodorus Petronella
IPC分类号： D02G3/38 , D02G3/40 , D02G3/48
CPC分类号： D02G3/447 , D02G3/38 , D02G3/404 , D02G3/48 , D07B1/025
摘要： Cord, bestehend aus einem Kern und einem Mantel, wobei der Kern in eine Matrix eingebettete Hochmodulfasern enthält, welcher mit den Mantel bildenden Fasern zumindest überwiegend umhüllt ist.
摘要翻译：帘线具有包含高模块纤维的芯，其嵌入基质中并主要涂覆有形成壁板的纤维。形成壁架的纤维是在芯部处受伤的复丝纱线。芯的基质是热塑性塑料。热塑性聚氨酯，聚酯，聚苯硫醚，聚乙烯和聚酰胺，其熔点和/或熔点范围为180-260摄氏度。还包括以下独立权利要求：（1）包含绳索（v）的v带，包含绳索的齿形带。

8. 发明公开

EP1694914A1 PARA-ARAMID FIBRID FILM 有权转让
标题翻译：对位芳纶，沉析纤维-FILM
公开(公告)号：EP1694914A1
公开(公告)日：2006-08-30
申请号：EP04803347.6
申请日：2004-11-30
申请人： Teijin Twaron B.V.
发明人： HENDRIKS, Anton, Johannes, Josef , WILBERS, Dennis , GROTENDORST, Harrie , JOURNEE, René , OLDENZEEL, Mirjam, Ellen
IPC分类号： D21H13/26 , D01F6/60
CPC分类号： D01F6/605 , D21H13/26 , Y10T428/249924
摘要： A para-aramid fibrid film is disclosed that has at least 95% of the bonds of the polymer are para-oriented. A method for making said para-aramid fibrid film by (a) polymerizing a para-oriented aromatic diamine and a para-oriented aromatic dicarboxylic acid halide to an aramid polymer having only para-oriented bonds in a mixture of solvents consisting of N-methylpyrrolidone or dimethylacetamide and calcium chloride or lithium chloride to obtain a dope wherein the polymer is dissolved in the mixture of solvents and the polymer concentration is 2 to 6 wt. %, and (b) converting the dope to para-aramid fibrid film is also described.
摘要翻译：公开了对位芳族聚酰胺隔离纤维膜，其中至少95％的聚合物的键是对位取向的。（a）将对位芳族二胺和对位取向的芳族二羧酸卤化物聚合到由N-甲基吡咯烷酮组成的溶剂混合物中仅具有对位取向键的芳族聚酰胺聚合物来制备所述对位芳族聚酰胺隔离纤维膜的方法或二甲基乙酰胺和氯化钙或氯化锂，以获得其中聚合物溶解在溶剂混合物中并且聚合物浓度为2至6重量％的涂料。％，和（b）将该涂料转化为对位芳族聚酰胺隔离纤维膜。

9. 发明公开

EP1581688A1 ARAMID FILAMENT YARN PROVIDED WITH A CONDUCTIVE FINISH 有权
标题翻译：用导电设备所提供芳纶纱
公开(公告)号：EP1581688A1
公开(公告)日：2005-10-05
申请号：EP03789160.3
申请日：2003-12-06
申请人： Teijin Twaron B.V.
发明人： WILLEMSEN, Stephanus , STUUT, Herman
IPC分类号： D06M13/292 , D06M13/17 , D06M15/53 , D06M15/356 , D06M11/76 , D06M13/352 , B66B7/12 , B66D1/54 , B66B5/00 , D07B1/14
CPC分类号： D06M15/53 , B66B7/06 , D06M11/76 , D06M13/17 , D06M13/292 , D06M13/352 , D06M15/3562 , D06M2101/36 , D06M2200/00 , D07B1/025 , D07B1/145 , D07B1/147 , D07B2205/205 , Y10T428/29 , Y10T428/2933 , Y10T428/2938 , D07B2801/10
摘要： The invention pertains to an aramid filament yarn provided with a finish comprising >1.5wt.% of an organic substance with a conductivity of > 4 mS/cm, measured as a 50 wt.% finish composition in water at 20°C, having a specific electric resistance of the yarn

10. 发明公开

EP1521872A1 PROCESS FOR OBTAINING A SYNTHETIC ORGANIC AROMATIC HETEROCYCLIC ROD FIBER OR FILM WITH HIGH TENSILE STRENGTH AND/OR MODULUS 有权
标题翻译：用于生产有机合成纤维具有高强度和/或芳香杂环聚合物僵硬高模
公开(公告)号：EP1521872A1
公开(公告)日：2005-04-13
申请号：EP03740307.8
申请日：2003-06-23
申请人： Teijin Twaron B.V.
发明人： ZEGERS, Hendrikus, Cornelis
IPC分类号： D01D10/02 , D01F6/74 , C08J5/18
CPC分类号： D01D10/02 , D01F6/74 , Y10T428/2933
摘要： The invention pertains to a process for obtaining a synthetic organic aromatic heterocyclic rod fiber or film with high tensile strength and/or modulus comprising spinning a synthetic organic polymer to a aromatic heterocyclic rod fiber or obtaining the synthetic organic polymer as an aromatic heterocyclic rod film, followed by loading the fiber or film in the presence of a processing aid, at a temperature below the boiling point of the processing aid and above -50°- C, at a tension of 10 to 95 % of the fiber or film breaking strength, followed by removing the processing aid and/or performing a heating step at a tension of 10 to 95% of the fiber or film breaking strength.

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