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1. 发明公开

EP2834626A1 METHODE DE TRANSFERT ISOBARIQUE D'UN FLUIDE ISSU D'UN GISEMENT ET DISPOSITIF DE MISE EN OEUVRE D'UNE TELLE METHODE 审中-公开
标题翻译：从实现这样一个程序的押金，装置的液体方法等压转让
公开(公告)号：EP2834626A1
公开(公告)日：2015-02-11
申请号：EP13714664.3
申请日：2013-04-08
申请人： Université Blaise Pascal Clermont II , INSTITUTO MEXICANO DEL PETROLEO , Institute Of Physical Chemistry - Polish Academy of Sciences
发明人： GROLIER, Jean-Pierre , RANDZIO, Stanislaw , AQUINO-OLIVOS, Marco Antonio
IPC分类号： G01N25/02 , G01N33/28
CPC分类号： G01N25/00 , E21B49/083 , G01F17/00 , G01L9/00 , G01N21/00 , G01N25/02 , G01N33/2823 , H01J49/0027
摘要： The invention concerns a method for transferring a fluid under pressure from a deposit of said fluid, by means of a sampling container (5) in which a fluid sample is kept at the reservoir pressure or sampling pressure, and a method for determining at least one thermodynamic characteristic of said fluid, in particular a method for determining the phase transition envelopes. The invention also concerns a method combining the implementation of scanning transitiometry with spectroscopic or analytical techniques, optionally in the presence of a fluid in the supercritical state. The invention also concerns a device for implementing said methods.

2. 发明公开

EP2796481A1 Process to Obtain Random Copolymers Derived from Itaconic Acid and/or its Isomers and Sodium Alkenyl Sulfonates and use of the Product Thereof 有权
标题翻译：用于生产无规共聚物，衣康酸和/或其异构体和ALKENYLNATRIUMSULFONATE暗示的保证并使用本公司产品THEREFOR
公开(公告)号：EP2796481A1
公开(公告)日：2014-10-29
申请号：EP14165784.1
申请日：2014-04-24
申请人： Instituto Mexicano Del Petroleo
发明人： Hernandez Altamirano, Raúl , Mena Cervantes, Violeta Yasmin , Zamudio Rivera, Luis Silvestre , Luna Rojero, Erick Emanuel , Martinez Magadan, José Manuel , Nieto Alvarez, David Aarón , Pons Jimenez, Mirna , Ramirez Estrada, Alejandro , Arzola Garcia, María del Pilar
IPC分类号： C08F222/02 , C02F5/02 , C02F5/08 , C08F228/02 , C08F220/58
CPC分类号： C02F5/10 , C02F2103/023 , C02F2103/08 , C02F2103/365 , C02F2303/22 , C08F222/02 , C08F228/02 , C08F2220/585
摘要： The present invention relates to the process for obtaining random copolymers based on itaconic acid and/or isomers and sodium alkenyl sulfonates, by means of polymerization in aqueous solution via free radicals at an acidic pH in the range from 1.0 to 3.5 and with a redox system as initiator, and the use thereof as calcium carbonate and calcium, strontium and barium sulfates mineral scale inhibitors and as dispersants of clays, iron oxides, calcium carbonate and strontium, barium and calcium sulfates. Random copolymers prevent and control damage to the formation by mineral salts scale that occurs in an oil reservoir, obstruction of water injection and crude oil production pipelines, as well as in production rigs due to mineral scale precipitation, all this as a consequence of high levels of salinity of the formation water and incompatible mixtures of injection water and formation water. Random copolymers are characterized for being tolerant to high concentrations of divalent ions, such as calcium, magnesium, strontium and barium, and by the fact that for its application to the reservoir and to injection or production pipelines, treated water, sea water and water that is characteristic of the reservoir (formation water) can be used as means of transportation. On the other hand, the copolymers can also be used to inhibit and disperse mineral scale occurring in cooling systems and boilers used in the oil and chemistry industry.
Furthermore, the random copolymers of the present invention are characterized for meeting internationally established environmental standards and are classified as particularly non-toxic and therefore they can be used in pipelines and equipment from oil and chemical industry that uses fresh water and sea water that are characteristic of offshore and inland facilities.
摘要翻译：本发明涉及一种用于基于衣康酸和/或同分异构体和烯基磺酸钠获得无规共聚物的制造方法，通过在经由自由基在在酸性pH范围内wässrige溶液从1.0至3.5，并用氧化还原体系聚合的手段为引发剂，和如碳酸钙和钙，锶和钡的硫酸盐矿物结垢抑制剂中的用途和粘土的分散剂，氧化铁，碳酸钙和锶，钡和硫酸钙。到地层由矿物盐规模无规共聚物防止和控制损伤并在油积存部的发生，注水和原油生产管道的阻塞，以及在生产钻机由于矿物垢沉淀，这一切都为高含量的结果的地层水的盐度和注入水和地层水的不相容混合物。无规共聚物的特征在于为是耐二价离子的高浓度，：例如钙，镁，锶和钡，以及由factthat其应用到储存器，并注入或生产管道，处理后的水，海水和水那样是特性储层（地层水）的可被用作运输和灰的装置。在另一方面，该共聚物因此可以用于抑制和分散矿物垢在冷却在石油和化学工业中使用的系统和锅炉发生的。进一步，本发明的无规共聚物的特点为会议国际公认的环境标准，被列为特别是无毒的，因此它们可以在石油，化工等行业的管道和设备被用来做使用淡水和海水也有特征性近海和内陆设施。

4. 发明公开

EP2644685A1 COMPOSITION COMPRISING ZWITTERIONIC GEMINAL LIQUIDS AS WETTABILITY MODIFIERS IN IMPROVED OIL RECOVERY PROCESSES 有权
标题翻译：两性离子组成宝石液体作为BENETZBARKEITSMODIFIKATOREN改善油生产过程
公开(公告)号：EP2644685A1
公开(公告)日：2013-10-02
申请号：EP11839690.2
申请日：2011-11-09
申请人： INSTITUTO MEXICANO DEL PETROLEO
发明人： HERNÁNDEZ ALTAMIRANO, Raúl , ZAMUDIO RIVERA, Luis, Silvestre , MENA CERVANTES, Violeta, Yasmín , BELTRÁN CONDE, Hiram, Isaac , DURÁN VALENCIA, Cecilia de los Ángeles , LÓPEZ RAMÍREZ, Simón , BUENROSTRO GONZÁLEZ, Eduardo , MENDOZA DE LA CRUZ, José, Luis , GARCÍA MARTÍNEZ, Jorge, Alberto , LUNA ROJERO, Erick, Emanuel , NIETO ÁLVAREZ, David, Aarón
IPC分类号： C10L1/224 , C07C229/26 , C07C227/18 , C10G75/02 , C09K8/584
CPC分类号： C09K8/584 , C07C229/12 , C10G1/04 , C10G2300/4006 , C10G2300/44 , C11D1/06
摘要： The present invention relates to the application of geminals zwitterionics liquids based on bis-N-alkyl or bis-N-alkenyl or N-cycloalkyl or N-aryl bis-beta aminoacids or its salts thereof as wettability modifiers of rocks such as limestone, dolomite, sand, quartz or heterogeneous lithologies, in the presence of brines with high content of divalent ions such as calcium, magnesium, barium and strontium, high temperature and pressure in processes of enhanced oil recovery. Wettability modifier comprises a geminal zwitterionic liquid based on bis-N-alkyl or bis-N-alkenyl or N-cycloalkyl or N-aryl bis-beta aminoacids or its salts, using as solvent distilled or brine with a high content of divalent ions such as calcium and magnesium or organic solvents compounds derived from alcohols like methanol, ethanol, isopropanol or mixtures thereof, or aromatic as isomers of xylene, toluene, or diesel, gasoline or mixtures thereof.
Geminals zwitterionics liquids based on bis-N-alkyl or bis-N-alkenyl or N-cycloalkyl or N-aryl bis-beta aminoacids or its salts are obtained by reacting an alkyl or alkenyl amine and an reactive polyether derivative of ethylene or propylene oxide or copolymer of these, which may contain in their structure mesyl or tosyl groups, and subsequently the reaction product is reacted with unsaturated acids such as acrylic acid or methacrylic acid and subsequently may or may not be neutralized with alkali metal bases such as the sodium or potassium hydroxide, carbonates or bicarbonates of potassium or sodium.
摘要翻译：本发明涉及的偕两性离子液体基于双-N-烷基或双-N-烯基或N-环烷基或N-芳基二-β氨基酸或它的盐的应用及其作为岩石的润湿性改进剂：如石灰石，白云石，砂，石英或异质的岩性，在盐水的存在下与二价离子含量高：例如钙，镁，钡和锶，高的温度和压力在强化油采收过程。润湿性改性剂包括偕两性离子液体基于上行N-烷基或双-N-烯基或N-环烷基或N-芳基二-β氨基酸或它的盐，用作为溶剂的蒸馏水或盐水与二价离子含量高的测试如钙和镁或如甲醇，乙醇，异丙醇或它们的混合物，或芳族的如二甲苯，甲苯，或柴油，汽油或它们的混合物的异构体醇衍生的有机溶剂的化合物。基于双-N-烷基或双-N-烯基或N-环烷基或N-芳基二-β氨基酸或它的盐偕两性离子液体是通过使烷基或链烯基胺和对反应性的环氧乙烷或环氧丙烷的聚醚衍生物获得或论文，其可以包含在它们的结构甲磺酰基或甲苯磺酰基团，并随后将反应产物进行反应与不饱和酸的共聚物：如丙烯酸或甲基丙烯酸，随后可以或可以不与碱金属碱中和的：如钠或氢氧化钾，碳酸盐或钾或钠的碳酸氢盐。

5. 发明公开

EP1652905A1 METHOD FOR THE CATALYTIC HYDROPROCESSING OF HEAVY PETROLEUM HYDROCARBONS 审中-公开
标题翻译： VERFAHREN ZUM KATALYTISCHEN HYDROPROCESSING VON SCHWERENERDÖLKOHLENWASSERSTOFFEN
公开(公告)号：EP1652905A1
公开(公告)日：2006-05-03
申请号：EP03741616.1
申请日：2003-07-09
申请人： Instituto Mexicano Del Petroleo
发明人： Ancheyta Juarez, Jorge , BETANCOURT RIVERA, Gerardo , MARROQUIN SANCHEZ, Gustavo, J. , CENTENO NOLASCO, Guillermo , MUNOZ MOYA, José Antonio Domingo , ALONSO MARTINEZ, Fernando
IPC分类号： C10G65/12 , C10G65/02
CPC分类号： C10G65/02 , C10G45/02 , C10G65/12 , C10G2300/1033 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2300/205 , C10G2300/206 , C10G2300/308 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018
摘要： The invention relates to a method for the catalytic hydroprocessing of heavy petroleum hydrocarbons with a high concentration of contaminants (metals and asphaltenes), which is performed at low-pressure operating conditions, together with the type of reactor and the type of feedstock. The invention limits the formation of sediments and sludge in the product and can be used to produce a hydrotreated hydrocarbon with improved properties and with contaminant, API gravity and distillate levels which fall within the ranges commonly reported for standard feedstock for refining schemes.
摘要翻译：本发明涉及一种在低压运行条件下与反应器类型和原料类型一起进行高浓度污染物（金属和沥青质）的重质石油烃的催化加氢处理方法。本发明限制了产品中沉淀物和污泥的形成，并且可用于生产具有改进的性能和污染物，API重力和馏出物水平的加氢处理烃，其水平落在用于精制方案的标准原料通常报道的范围内。

6. 发明公开

EP2679542A1 Nanostrutured titania semiconductor material and its production process 审中-公开
标题翻译： Nanostrukturiertes Titandioxid-Halbleitermaterial und Verfahren zu seiner Herstellung
公开(公告)号：EP2679542A1
公开(公告)日：2014-01-01
申请号：EP13003180.0
申请日：2013-06-21
申请人： Instituto Mexicano Del Petroleo
发明人： Castillo Cervantes, Salvador , Mejía Centeno, Isidro , Camposeco Solis, Roberto , Moran Pineda, Florencia Marina , Navarrete Bolanos, Juan , Montoya DE LA Fuente, J. Ascensión , Vargas Escudero, Alfredo
IPC分类号： C01G23/053
CPC分类号： C01G23/053 , B01J21/063 , B01J35/02 , B01J37/036 , B01J37/08 , C01G23/08 , C01P2002/02 , C01P2002/60 , C01P2006/12 , C01P2006/16 , C01P2006/40
摘要： The present invention relates to a nanostructured titania semiconductor material, termed TSG-IMP and its production process via the sol-gel method.
The TSG-IMP semiconductor material basically consists of titanium oxide, with the special feature of being like nanostructures, which gives special physicochemical properties, with ability to disperse and stabilize metal particles with high activity and selectivity in catalytic processes mainly.
The process of obtaining the semiconductor material TSG-IMP comprises adding to a system with constant stirring reflux, a titanium alkoxide to an alcoholic solution, adding an acid to the alcoholic solution, controlling the pH from 1 to 5; subjecting the acidic solution to agitation and reflux conditions at a temperature of 70 to 80°C; stabilizing the medium and proceeding with the addition of bidistilled water in a water / alkoxide molar ratio of 1-2/0.100-0.150, continuing with reflux until gelation; subjecting the gel to a treatment of aging, for a time from 1 to 24 hours for complete formation of the titania; drying the titania nanostructured at a temperature of 50 to 80°C for about 1 to 24 hours, and subjecting the dried titania to a calcination step at a temperature of 200 to 600°C, during a time from 1 to 12 hours.
The dimension of the crystal size of the titania nanostructures of semiconducting material depends on TSG-IMP particular handling or assembly of the sol gel method variables such as the types of metal alkoxides of titanium used, the characteristics of the solvents, relationship alkoxide / water, and the medium in which the hydrolysis takes place, which can be acidic or basic.
摘要翻译：本发明涉及一种称为TSG-IMP的纳米结构二氧化钛半导体材料及其通过溶胶 - 凝胶法的制备方法。 TSG-IMP半导体材料主要由二氧化钛组成，其特征如纳米结构，具有特殊的物理化学性质，主要在催化过程中以高活性和选择性分散和稳定金属颗粒。获得半导体材料TSG-IMP的方法包括向不断搅拌回流的系统中加入醇钛醇盐，向醇溶液中加入酸，将pH控制在1至5; 在70〜80℃的温度下对酸性溶液进行搅拌和回流条件; 稳定培养基并加入水/醇盐摩尔比为1-2 / 0.100-0.150的双蒸水，继续回流直到凝胶化; 使凝胶经历老化处理1至24小时以完成二氧化钛的形成; 在50〜80℃的温度下将纳米结构的二氧化钛干燥约1〜24小时，并在200〜600℃的温度下，在1〜12小时内对经干燥的二氧化钛进行煅烧工序。半导体材料的二氧化钛纳米结构的晶体尺寸的尺寸取决于TSG-IMP特定的处理或组装溶胶凝胶法变量，例如所用钛的金属醇盐类型，溶剂的特性，醇盐/水的关系，和发生水解的介质，其可以是酸性或碱性的。

7. 发明公开

EP1941944A1 METHOD OF PREPARING A CATALYTIC COMPOSITION FOR THE HYDROPROCESSING OF PETROLEUM FRACTIONS 审中-公开
标题翻译： VERFAHREN ZUR HERSTELLUNG EINER KATALYSATORZUSAMMENSETZUNGFÜRDAS HYDROPROCESSING VONERDÖLFRAKTIONEN
公开(公告)号：EP1941944A1
公开(公告)日：2008-07-09
申请号：EP06799438.4
申请日：2006-08-22
申请人： INSTITUTO MEXICANO DEL PETROLEO
发明人： TOLEDO ANTONIO, José Antonio , PÉREZ LUNA, Miguel , CORTÉS JACOME, María Antonia , ESCOBAR AGUILAR, José , MOSQUEIRA MONDRAGÓN, María, de Lourdes Araceli , ANGELES CHAVEZ, Carlos , LÓPEZ SALINAS, Esteban , PÉREZ MORENO, Víctor , FERRAT TORRES, Gerardo , MORA VALLEJO, Rodolfo Juventino , LOZADA Y CASSOU, Marcelo
IPC分类号： B01J23/85 , B01J27/049 , B01J27/22 , B01J31/02 , B01J37/03 , B01J37/08 , B01J37/20 , C10G45/08 , C10G49/04 , B01J35/08
CPC分类号： B01J27/0515 , B01J23/85 , B01J23/882 , B01J23/883 , B01J35/002 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0018 , B01J37/03 , B01J37/084 , B01J37/20 , C10G45/08 , C10G45/50
摘要： The invention relates to a method of preparing a catalytic composition comprising at least one non-noble metal from group VIII and at least one metal from group VIB of the periodic table. The invention also relates to the catalytic composition thus produced, which has a high specific activity in reactions involving the hydroprocessing of light and intermediate fractions, preferably in reactions involving the hydrotreatment of hydrocarbon streams, including hydrodesulphurisation (HDS), hydrodenitrogenation (HDN) and hydro-dearomatisation (HDA).
摘要翻译：本发明涉及一种制备催化组合物的方法，所述催化组合物包含至少一种来自VIII族的非贵金属和至少一种来自元素周期表VIB族的金属。本发明还涉及如此制备的催化组合物，其在涉及光加氢处理的反应和中间馏分的反应中具有高比活性，优选在涉及烃流加氢处理的反应（包括加氢脱硫（HDS）），加氢脱氮（HDN）和氢脱甲酰化（HDA）。

8. 发明公开

EP1748033A1 NANOSTRUCTURED TITANIUM OXIDE MATERIAL AND METHOD OF OBTAINING SAME 审中-公开
标题翻译：纳米结构氧化钛及其制造方法
公开(公告)号：EP1748033A1
公开(公告)日：2007-01-31
申请号：EP04734956.8
申请日：2004-05-26
申请人： Instituto Mexicano Del Petroleo
发明人： TOLEDO ANTONIO, J.A., Av. Eje Central Norte Lazaro , ANGELES CHAVEZ, C., Av. Eje Central Norte Lázaro , CORTES JACOME, M.A., Av. Eje Central Norte Lazaro , ALVAREZ RAMIREZ, F., Av. Eje Central Norte Lázaro , RUIZ MORALES, Y., Av. Eje Central Norte Lázaro , FERRAT TORRES, G., Av. Eje Central Norte Lázaro , FLORES ORTIZ, L.F., Av. Eje Central Norte Lazaro , LOPEZ SALINAS, E., Av. Eje Central Norte Lázaro , LOZADA Y CASSOU, M., Av. Eje Central Norte Lázaro
IPC分类号： C01G23/00
CPC分类号： B82Y30/00 , C01G23/047 , C01P2002/72 , C01P2002/77 , C01P2006/17
摘要： The invention relates to nanostructured materials comprising titanium oxide (TiO 2-x , where 0= x=1), having a hitherto-unknown orthorhombic crystalline structure which is the basic unit in the construction of nanofibres, nanowires, nanorods, nanocoils and/or nanotubes. The materials are produced from an isostructural precursor comprising hydrogen titanate and/or mixed sodium and hydrogen titanate, corresponding to the hydrogenated, protonated, hydrated and/or alkaline phases of the aforementioned structure, and are obtained from titanium compounds, such as: titanium oxide having a crystalline anatase structure, amorphous titanium oxide, titanium oxide having a crystalline rutile structure, and/or directly from rutile mineral and/or ilmenite. The invention also relates to the method of obtaining the inventive materials.

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