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    • 6. 发明公开
    • PRODUCTION OF PHOSPHATE COMPOUNDS FROM MATERIALS CONTAINING PHOSPHORUS AND AT LEAST ONE OF IRON AND ALUMINIUM
    • 磷酸盐化合物的产量从含磷材料和铁中的至少一个铝
    • EP2991935A1
    • 2016-03-09
    • EP14791380.0
    • 2014-05-02
    • Easymining Sweden AB
    • COHEN, YarivENFÄLT, Patrik
    • C02F11/00C01B25/22C01B25/238C01B25/46C05B11/12C05B11/16C05F7/00
    • A method for concentration of phosphate compounds comprises dissolving (205) of sludge ash in hydrochloric acid. Insoluble residues are separated (210), thereby forming a first leach solution. A mole ratio of phosphorus to a sum of ferric iron and aluminum in the first leach solution is controlled (215) to be larger than 1. A base is added (220) to the first leach solution in an amount causing precipitation of phosphate compounds. The precipitated phosphate compounds are removed (225) from the first leach solution. Sulphuric acid is added (240) to the first leach solution, causing precipitation of sulphate compounds. The precipitated sulphate compounds are separated (245) from the first leach solution. At least a part of the leach solution is recycled (248) as the hydrochloric acid used for the dissolving of sludge ash. Further methods for processing the precipitated phosphate compounds are presented as well as arrangements for performing the methods.
    • 一种用于磷酸盐化合物的浓度的方法包括泥灰的溶解(205)中的盐酸。 不溶残渣分离(210),由此形成第一浸出溶液。 与三价铁和铝的总和在第一浸出溶液磷的摩尔比被控制(215)为大于1,一种碱加入(220)到在量曹景伟磷酸盐化合物的沉淀第一浸出溶液大。 除去沉淀的磷酸盐化合物(225)从第一浸提溶液。 加入硫酸(240)到所述第一沥滤溶液,引起硫酸盐化合物的沉淀。 将沉淀的硫酸化合物中分离(245)从第一浸提溶液。 至少所述浸提溶液的一部分被再循环(248)作为用于泥灰的溶解的盐酸。 用于处理所述沉淀的磷酸盐化合物的另外的方法被呈现以及用于执行所述方法的布置。
    • 7. 发明公开
    • PRODUCTION OF AMMONIUM PHOSPHATES
    • ER UNG ON ON。。。
    • EP2864249A1
    • 2015-04-29
    • EP13806613.9
    • 2013-06-19
    • Easymining Sweden AB
    • COHEN, YarivENFÄLT, Patrik
    • C01B25/28B01D11/04C01B25/46C05B7/00C05B11/08C05C3/00
    • An arrangement (100) for production of fully soluble, pure and well defined mono- or di-ammonium phosphates, comprises an extraction section (10), a stripping section (20) and end treatment arrangements (90). The extraction section performs a liquid-liquid extraction of phosphate between a feed liquid (1) comprising phosphoric acid and being essentially free from nitrate ions, and a solvent (5) having a solubility in water of less than 2%. The stripping section performs a liquid-liquid extraction of phosphate between solvent loaded with phosphate and a strip solution (4). The solvent depleted in phosphate is recirculated to the extraction section for further extraction of phosphate. The strip solution is an aqueous ammonium phosphate solution, wherein at least 80% of the ammonium phosphate is monoammonium phosphate and/or wherein the solvent is a water-immiscible alcohol. The end treatment arrangements comprise a source of ammonia (60), an adding arrangement (70), a cooling arrangement (50), a precipitate remover (40) and a recirculation system (80).
    • 用于生产完全可溶的,纯的和明确定义的磷酸二氢铵或磷酸二铵的装置(100)包括萃取部分(10),汽提段(20)和末端处理装置(90)。 提取部分在磷酸基本上不含硝酸根离子的进料液(1)和在水中的溶解度小于2%的溶剂(5)之间进行磷酸盐液体萃取。 汽提段在负载磷酸盐和条状溶液(4)的溶剂之间进行磷酸液体液体萃取。 将贫磷酸盐的溶剂再循环至萃取部分以进一步提取磷酸盐。 带状溶液是磷酸铵水溶液,其中至少80%的磷酸铵是磷酸氢二铵和/或其中溶剂是与水不混溶的醇。 末端处理装置包括氨源(60),添加装置(70),冷却装置(50),沉淀物去除器(40)和再循环系统(80)。