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    • 5. 发明公开
    • Process for the oxidation of fine coal
    • Verfahren zur Oxidierung pulvriger Kohle。
    • EP0298710A2
    • 1989-01-11
    • EP88306134.3
    • 1988-07-06
    • ENERKOM (PTY) LIMITED
    • Cronje, Izak Johannes
    • C08H5/02C07G1/00C10L9/06
    • C08H99/00C05F11/02
    • This invention relates to the production of a solid oxidised coal containing humic acids. Coal with a mean particle size of less than 3mm is slurried with water and then oxidised with oxygen or mixtures of oxygen and air at temperatures ranging from 100 to 300°C, at partial oxygen pressures ranging from 0,1 to 10 MPa and reaction periods ranging from 5 to 600 minutes. In the absence of catalysts, e.g. alkaline bases, the main product of oxidation is humic acids. These humic acids are not dissolved because the pH of this slurry is in the range 4 to 9. Small amounts of fulvic acids are formed and these are soluble in the water of the slurry.
      The coal-derived humic acids may for example find application as soil conditioners, organic fertilisers, briquettte and pellet binders, drilling fluid dispersants and viscosity control agents, whilst the coal-derived fulvic acids may be utilised for the production of fuel extenders, plasticisers and petrochemicals.
    • 本发明涉及含有腐殖酸的固体氧化煤的生产。 平均粒度小于3mm的煤用水制浆,然后用氧气或氧气和空气的混合物氧化,温度范围为100至300℃,部分氧气压力为0.1至10MPa,反应时间为 从5到600分钟。 在不存在催化剂的情况下 碱性碱,氧化的主要产物是腐殖酸。 这些腐殖酸不溶解,因为这种浆料的pH值在4至9的范围内。形成少量的富里酸,并且它们可溶于浆料的水中。 煤源腐殖酸可以例如用作土壤调节剂,有机肥料,团块和颗粒粘合剂,钻井液分散剂和粘度控制剂,而煤衍生的腐殖酸可用于生产燃料增量剂,增塑剂和 石化产品。