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1. 发明公开

EP3835366A1 FLAME RETARDANT FOR THERMOSETTING RESIN INCLUDING AROMATIC PHOSPHORIC ACID ESTER, THERMOSETTING RESIN COMPOSITION INCLUDING SAME, AND CURED MATERIAL AND APPLICATION OF SAME 有权
公开(公告)号：EP3835366A1
公开(公告)日：2021-06-16
申请号：EP19847820.8
申请日：2019-06-11
申请人： Daihachi Chemical Industry Co., Ltd.
发明人： YAHATA, Shunsuke
IPC分类号： C08L101/00 , B32B5/28 , B32B27/18 , C07F9/09 , C08J5/24 , C08K5/523 , H05K1/03
摘要： A flame retardant for thermosetting resin containing an aromatic phosphoric acid ester represented by the general formula (I):

wherein R 1 to R 4 each independently represent a hydrogen atom, a C 1-4 alkyl group, or a C 1-4 alkoxy group; R 5 , R 6 , and R 9 each independently represent a C 1-10 alkyl group or a C 1-10 alkoxy group; R 7 and R 8 each independently represent a C 1-4 alkyl group or a C 1-4 alkoxy group; n represents an integer of 1 to 10; n 1 and n 2 each independently represent an integer of 0 to 3; m 1 and m 2 each independently represent an integer of 0 to 4; p represents an integer of 0 to 26; and k represents an integer of 1 to 12; and when p is 2 or more, any two substituents R 9 may be bonded to each other, and may be bonded to a carbon atom(s) of a ring to which the above substituents R 9 are bonded, forming another ring.

2. 发明公开

EP2987844A1 FLAME-RETARDANT AGENT COMPOSITION AND FLAME-RETARDANT RESIN COMPOSITION CONTAINING SAME, AND MOLDED ARTICLE 审中-公开
标题翻译： FLAMMSCHUTZMITTELZUSAMMENSETZUNG UND FLAMMHEMMENDE HARZZUSAMMENSETZUNG DAMIT SOWIEFORMKÖRPER
公开(公告)号：EP2987844A1
公开(公告)日：2016-02-24
申请号：EP14786026.6
申请日：2014-04-07
申请人： Daihachi Chemical Industry Co., Ltd.
发明人： KAKUSHOU, Fujio , FUKUHARA, Hiroyuki , NAKANO, Ryosuke
IPC分类号： C09K21/12 , C08K5/521 , C08L101/00
CPC分类号： C08K5/524 , C08K5/521 , C08K5/523 , C08L101/00 , C09K21/12
摘要： A flame-retardant agent composition containing an organophosphorous compound represented by the general formula (I):
wherein R 1 and R 2 each independently represent an alkyl group having 1 to 5 carbon atoms; R 3 and R 4 each independently represent a hydrogen atom or an alkyl group having 1 to 5 carbon atoms; Y represents a bond or a group -CH 2 -, -C(CH 3 ) 2 -, -S-, -SO 2 -, -O-, -CO- or - N=N-; k represents 0 or 1; and m represents an integer of 0 to 4 and
having a property such that a content of a compound represented by the formula (II):
wherein R 1 , R 2 and R 3 are as defined in the general formula (I)
is 1.8% by area or less when the organophosphorous compound is determined by gel permeation chromatography (GPC).
摘要翻译：一种含有通式（I）表示的有机亚磷化合物的阻燃剂组合物：其中R 1和R 2各自独立地表示具有1至5个碳原子的烷基; R 3和R 4各自独立地表示氢原子或碳原子数1〜5的烷基。 Y表示键或基团-CH 2 - ， - C（CH 3）2 - ， - S - ， - SO 2 - ， - O - ， - CO-或-N = N-; k表示0或1; m表示0〜4的整数，具有使通式（I）中所定义的式（II）表示的化合物的含量为通式（I）中定义的R 1，R 2，R 3的含量为1.8质量％当通过凝胶渗透色谱法（GPC）测定有机亚磷化合物时，面积以下。

3. 发明授权

EP1593712B1 FLAME-RETARDANT POLYCARBONATE RESIN COMPOSITION 有权
标题翻译：阻燃聚碳酸酯树脂组合物
公开(公告)号：EP1593712B1
公开(公告)日：2014-07-16
申请号：EP04706336.7
申请日：2004-01-29
申请人： DAIHACHI CHEMICAL INDUSTRY CO., LTD.
发明人： FUJISAWA, Taku , TANAKA, Sakiko
IPC分类号： C08L69/00 , C08K5/098
CPC分类号： C08L69/00 , C08K5/098 , C08L27/12 , C08L2666/04

4. 发明授权

EP1219677B1 FLAME RETARDANTS FOR RESINS AND FLAME-RETARDED RESIN COMPOSITIONS CONTAINING THE SAME 有权
标题翻译：阻燃剂树脂和隔爆树脂组成物含
公开(公告)号：EP1219677B1
公开(公告)日：2010-12-08
申请号：EP00937309.3
申请日：2000-06-19
申请人： DAIHACHI CHEMICAL INDUSTRY CO., LTD.
发明人： TOKUYASU, Noriaki , KAMEDA, Katumi
IPC分类号： C09K21/12 , C08K5/527
CPC分类号： C09K21/12 , C08G2101/0008 , C08G2101/0025 , C08G2101/005 , C08K5/527 , C08L75/04
摘要： Flame retardants for resins, which contain as the principal component phosphorinane-type phosphates represented by general formula (I) (wherein R1 and R2 are each independently C1-C6 alkyl; and R3 is C1-C20 alkyl), and which can impart excellent flame retardance to resins without lowering in the physical properties inherent in the resins and are excellent in resistance to hydrolysis and free from halogen; and flame-retarded resin compositions excellent in mechanical characteristics.

5. 发明授权

EP1191029B1 PROCESS FOR THE PREPARATION OF CONDENSED PHOSPHORIC ESTERS 有权
标题翻译：用于生产缩合磷酸酯
公开(公告)号：EP1191029B1
公开(公告)日：2008-05-21
申请号：EP99954438.0
申请日：1999-11-08
申请人： DAIHACHI CHEMICAL INDUSTRY CO., LTD.
发明人： NAKAMURA, Shin , NOGUCHI, Kazuo , FUJISAWA, Taku , OHKAWA, Takafumi
IPC分类号： C07F9/12 , C07F9/14
CPC分类号： C09K21/12 , C07F9/12 , C07F9/1406
摘要： A process for the preparation of condensed phosphoric esters extremely lowered in volatiles content, which comprises the first step of reacting a phosphorus oxytrihalide with a bisphenol to prepare a phosphorohalidate, the second step of removing unreacted phosphorus oxytrihalide, and the third step of reacting the phosphorohalidate with a monophenol at a specific ratio.

6. 发明公开

EP1857586A1 FLAME-RETARDANT POLYESTER FIBER AND METHOD FOR PRODUCING SAME 审中-公开
标题翻译： IHH HERSTELLUNGSVERFAHREN公司的FLAMMFESTE POLYESTERFASER
公开(公告)号：EP1857586A1
公开(公告)日：2007-11-21
申请号：EP06728614.6
申请日：2006-03-03
申请人： DAIHACHI CHEMICAL INDUSTRY CO., LTD.
发明人： TANAKA, Yoshinori , MASUI, Yuki
IPC分类号： D06M13/292 , D06M13/52 , D06M101/32
CPC分类号： D06M13/292 , C09K21/12 , D06M13/52 , D06M2101/32 , D06M2200/30
摘要： A preparation process of flame-retardant polyester fibers, comprising the steps of: impregnating polyester fibers with a flame retardancy giving liquid containing a phosphorus compound as a flame-retarder represented by the formula (I):

wherein Ar represents a phenyl or naphthyl group which may be substituted by C 1-4 alkyl groups, and n represents an integer 1 to 3; thermally treating the polyester fibers under normal or increased pressure after or at the same time as the impregnation treatment; and thereby giving flame retardancy to the polyester fibers.
摘要翻译：一种阻燃聚酯纤维的制备方法，包括以下步骤：将具有阻燃性的聚酯纤维浸渍，得到含有磷化合物的液体作为由式（I）表示的阻燃剂：其中Ar表示苯基或萘基，可以被C 1-4烷基取代，n表示1〜3的整数，在浸渍处理之后或同时在正常或增加的压力下热处理聚酯纤维; 从而对聚酯纤维产生阻燃性。

7. 发明授权

EP1227101B1 PROCESS FOR THE PREPARATION OF CONDENSED PHOSPHORIC ACID ESTERS 有权
标题翻译：用于生产缩合磷酸酯
公开(公告)号：EP1227101B1
公开(公告)日：2006-04-19
申请号：EP00931613.4
申请日：2000-05-30
申请人： DAIHACHI CHEMICAL INDUSTRY CO., LTD.
发明人： NAKAMURA, Shin , FUJISAWA, Taku , OKAWA, Takafumi
IPC分类号： C07F9/12 , C09K21/12 , C08K5/523
CPC分类号： C09K21/12 , C07F9/12
摘要： A process for the preparation of condensed phosphoric acid esters by using bisphenol A derivatives as the raw material, which can give high-purity condensed phosphoric acid esters little containing monomeric phosphoric acid esters which cause lowering in heat resistance and staining of molds when used as additives for resins. This process comprises reacting a bisphenol A derivative with a phosphorus oxytrihalide and a hydroxyl compound in the presence of a decomposition inhibitor.

8. 发明公开

EP1559734A1 COMPOSITION FOR FLAME-RETARDANT FLEXIBLE POLYURETHANE FOAM 审中-公开
标题翻译： FF FF FF FF FF FF FF FF FF FF FF FF FF FF FF FF
公开(公告)号：EP1559734A1
公开(公告)日：2005-08-03
申请号：EP03770117.4
申请日：2003-11-04
申请人： DAIHACHI CHEMICAL INDUSTRY CO., LTD.
发明人： TOKUYASU, Noriaki , HAMADA, Toshiya
IPC分类号： C08G18/48 , C08L75/08 , C08K5/3492 , C08K5/521
CPC分类号： C08G18/4829 , C08G2101/0008 , C08G2101/005 , C08G2101/0083 , C08K5/521 , C08L75/08
摘要： The present invention provides a composition for a flame-retardant flexible polyurethane foam comprising:(A) 100 parts by weight of a polyol component containing a polyether polyol having at least 2 hydroxyl groups and a number average molecular weight of 2,000 to 5,000; (B) 3 to 50 parts by weight of a melamine-based flame retardant having an average particle diameter of 30 to 60 µm; (C) 5 to 35 parts by weight of an additive-type phosphorus-containing flame retardant; (D) 0.01 to 2 parts by weight of a catalyst; (E) 0.1 to 10 parts by weight of a blowing agent; (F) 0.1 to 3 parts by weight of a silicone foam stabilizer; and (G) a polyisocyanate component in an amount corresponding to an isocyanate index of 90 to 120.
The composition of the present invention enables a highly flame-retardant polyurethane foam to be obtained even with the use of a general-purpose polyol.
摘要翻译：本发明提供了一种阻燃软质聚氨酯泡沫塑料组合物，其包含：（A）100重量份含有至少2个羟基和数均分子量为2,000至5,000的聚醚多元醇的多元醇组分; （B）3〜50重量份平均粒径为30〜60μm的三聚氰胺类阻燃剂; （C）5〜35重量份的添加型含磷阻燃剂; （D）0.01〜2重量份的催化剂; （E）0.1〜10重量份的发泡剂; （F）0.1〜3重量份硅氧烷泡沫稳定剂; 和（G）对应于异氰酸酯指数为90至120的量的多异氰酸酯组分。本发明的组合物使得即使使用通用方法也可获得高度阻燃的聚氨酯泡沫多元醇。

9. 发明公开

EP1403272A8 PROCESS FOR PREPARATION OF PHOSPHORIC ESTERS 有权
标题翻译：用于生产磷酸酯
公开(公告)号：EP1403272A8
公开(公告)日：2004-06-16
申请号：EP02724648.7
申请日：2002-04-25
申请人： DAIHACHI CHEMICAL INDUSTRY CO., LTD.
发明人： TAMURA, Kazunari
IPC分类号： C07F9/12
CPC分类号： C07F9/1406 , C07F9/12
摘要： A process for preparing a phosphoric ester, comprising: Step (1) of reacting naphthol with phosphorus oxychloride in a molar ratio of 1:1.3 or more in the presence of a metallic halide and removing unreacted phosphorus oxychloride and Step (2) of reacting the reaction product of Step (1) with phenol in a molar ratio (molar ratio of chlorine contained in the reaction product to phenol) of 1:1-1.5 and removing hydrogen chloride produced as a by-product to thereby obtain a phosphoric ester represented by the general formula (I): wherein n is 1 or 2.

10. 发明授权

EP1153929B1 Process for producing phosphorohalidates 有权
标题翻译：一种制备Phosphorohalidaten过程
公开(公告)号：EP1153929B1
公开(公告)日：2003-04-09
申请号：EP00902011.6
申请日：2000-01-28
申请人： DAIHACHI CHEMICAL INDUSTRY CO., LTD.
发明人： FUJITA, Yasunori
IPC分类号： C07F9/12 , C07F9/14
CPC分类号： C07F9/1406 , C07F9/12

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