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1. 发明公开

EP0411687A3 Process for producing electrolytic lead and elemental sulfur from galena 失效
标题翻译：从GALENA生产电解铅和元素硫的工艺
公开(公告)号：EP0411687A3
公开(公告)日：1991-09-11
申请号：EP90201909.0
申请日：1990-07-13
申请人： B.U.S. ENGITEC SERVIZI AMBIENTALI S.r.l.
发明人： Olper, Marco , Fracchia, Pierluigi
IPC分类号： C25C1/18
CPC分类号： C01B17/06 , C25C1/18 , Y02P10/212
摘要： The invention proposes a process for producing electrolytic lead and elemental sulfur from galena, characterized in that it comprises the following steps:
(a) Galena is leached with an acidic aqueous solution of ferric fluoborate, with ferrous fluoborate, lead fluoborate and elemental sulfur being formed according to the reaction:
2 Fe(BF₄)₃ + PbS → 2 Fe(BF₄)₂ + Pb(BF₄)₂ + S (b) the solid residue, composed by elemental sulfur and galena gangue is filtered off; (c) the solution of ferrous fluoborate and lead fluoborate coming from the (a) step is sent to a diaphragm electolytic cell, wherein pure lead is deposited at the cathode and at the anode ferrous ion is oxidated to ferric ion; (d) the solution of ferric fluoborate regenerated at the anode in said (c) step is recycled to said (a) step of galena leaching. By operating under suitable conditions, lead can be selectively dissolved and separated from the other metals small amounts of which are contained in galena together with said lead. Sulfur produced by the reaction can be separated from the gangue by extraction with a solvent, or by flotation.

2. 发明授权

EP0411687B1 Process for producing electrolytic lead and elemental sulfur from galena 失效
标题翻译：一种用于从产生方铅矿电解铅和元素硫的过程。
公开(公告)号：EP0411687B1
公开(公告)日：1994-12-07
申请号：EP90201909.0
申请日：1990-07-13
申请人： B.U.S. ENGITEC SERVIZI AMBIENTALI S.r.l.
发明人： Olper, Marco , Fracchia, Pierluigi
IPC分类号： C25C1/18
CPC分类号： C01B17/06 , C25C1/18 , Y02P10/212

3. 发明公开

EP0379245A1 Process and plant for the processing of slag from aluminium scrap and waste melting, recovery of components thereof and treatment of gasses generated 失效
标题翻译：方法和装置用于从铝废料和废物的熔融处理炉渣，回收的累积气体的成分和治疗。
公开(公告)号：EP0379245A1
公开(公告)日：1990-07-25
申请号：EP90200079.3
申请日：1990-01-12
申请人： B.U.S. ENGITEC SERVIZI AMBIENTALI S.r.l.
发明人： Olper, Marco , Corsini, Tullio , Fracchia, Pierluigi
IPC分类号： C22B7/04 , C22B21/00
CPC分类号： C22B7/04 , C22B21/0007 , Y02P10/218
摘要： The present invention relates to a process and a plant for the processing of saline slag from the melting of aluminium scrap and waste with a saline flux in which the salts constituting the flux are recovered and other components of the slag are separated. The harmful or toxic gasses developed during this processing are subjected to combustion to produce flue gasses dispersible in the atmosphere with recovery of combustion heat, preferibly used over in processing the slag.
摘要翻译：本发明涉及一种方法和从铝废料和废物的熔化与其中构成磁通所述盐中回收和炉渣的其它组分分离的盐水通量盐水炉渣的处理的植物。该处理过程中产生的有害或有毒的气体经受燃烧，以产生与燃烧热回收大气中分散的烟道气，preferibly在处理炉渣中使用过。

4. 发明公开

EP0411687A2 Process for producing electrolytic lead and elemental sulfur from galena 失效
标题翻译：一种用于从产生方铅矿电解铅和元素硫的过程。
公开(公告)号：EP0411687A2
公开(公告)日：1991-02-06
申请号：EP90201909.0
申请日：1990-07-13
申请人： B.U.S. ENGITEC SERVIZI AMBIENTALI S.r.l.
发明人： Olper, Marco , Fracchia, Pierluigi
IPC分类号： C25C1/18
CPC分类号： C01B17/06 , C25C1/18 , Y02P10/212
摘要： The invention proposes a process for producing electrolytic lead and elemental sulfur from galena, characterized in that it comprises the following steps:

(a) Galena is leached with an acidic aqueous solution of ferric fluoborate, with ferrous fluoborate, lead fluoborate and elemental sulfur being formed according to the reaction:
2 Fe(BF₄)₃ + PbS → 2 Fe(BF₄)₂ + Pb(BF₄)₂ + S
(b) the solid residue, composed by elemental sulfur and galena gangue is filtered off;
(c) the solution of ferrous fluoborate and lead fluoborate coming from the (a) step is sent to a diaphragm electolytic cell, wherein pure lead is deposited at the cathode and at the anode ferrous ion is oxidated to ferric ion;
(d) the solution of ferric fluoborate regenerated at the anode in said (c) step is recycled to said (a) step of galena leaching.

By operating under suitable conditions, lead can be selectively dissolved and separated from the other metals small amounts of which are contained in galena together with said lead.
Sulfur produced by the reaction can be separated from the gangue by extraction with a solvent, or by flotation.
摘要翻译：本发明提出了用于生产电解铅和从方铅矿元素硫，其特征在于在没有它包括以下步骤：（a）方铅矿在铁氟硼酸盐的酸性wässrige溶液中，用亚铁氟硼酸盐，铅氟硼酸盐和元素硫浸提而形成 gemäß到反应：2的Fe（BF 4）3 + PBS - > 2的Fe（BF 4）2 + PB（BF4）2 + S（b）该固体残余物，通过元素硫和方铅矿脉石组成的滤出; （C）氟硼酸亚铁和铅氟硼酸从步骤（a）来的溶液送到一个隔膜电解槽electolytic，worin纯铅在阴极和阳极处的亚铁离子被氧化成铁离子沉积; （D）氟硼酸铁在说步骤（c）在阳极再生的溶液再循环到所述（A）方铅矿浸出步骤。通过在合适的条件下操作，铅可以被选择性地溶解并从少量这些都与铅包含在所述方铅矿一起其它金属分开。由该反应产生的硫可从脉石通过萃取用溶剂通过浮选分离，或者。

5. 发明公开

EP0638667A1 Process for continuous electrochemical lead refining 失效
标题翻译： Verfahren zum fortlaufenden elektrochemischenLäuternvon Blei。
公开(公告)号：EP0638667A1
公开(公告)日：1995-02-15
申请号：EP93202376.5
申请日：1993-08-13
申请人： B.U.S. ENGITEC SERVIZI AMBIENTALI S.r.l.
发明人： Olper, Marco
IPC分类号： C25C1/18
CPC分类号： C25C1/18
摘要： The raw lead to be refined, whether of mineral origin or from reclaiming operations, the particle size of which has been reduced to a range not larger than 50 mm, is leached in a suitable apparatus with a solution of ferric fluoroborate in fluoroboric acid.
During the leaching step, lead gets dissolved, with ferric fluoroborate being reduced to ferrous fluoroborate according to the following reaction:

2 Fe (BF₄)₃ + Pb ---> Pb(BF₄)₂ + 2Fe(BF₄) (1)

The leaching apparatus behaves hence as an external anode installed outside of the cell.
The resulting solution is sent to the cathodic compartment of a diaphragm cell in which lead is deposited on a cathode of stainless steel, in compact, highly pure form, from which it is periodically won.
The so depleted-of-lead solution is sent to the anodic compartment of the same cell, in which a suitable anode oxidizes ferrous fluoroborate to ferric fluoroborate.
摘要翻译：无论矿物来源还是来自回收作业的原料铅在其合适的装置中用氟硼酸铁溶液在氟硼酸中浸出，将其粒度降至不大于50毫米的原料。在浸出步骤中，铅溶解，氟铁酸根据以下反应还原为氟硼酸亚铁：2 Fe（BF4）3 + Pb ---> Pb（BF4）2 + 2Fe（BF4）（1>浸出装置因此作为安装在电池外部的外部阳极，所得到的溶液被送到隔膜电池的阴极室，其中铅沉积在不锈钢的阴极上，呈紧密，高度纯净的形式，从该阴极室周期性地将这样耗尽的铅溶液送到相同电池的阳极室，其中合适的阳极将氟硼酸亚铁氧化成氟硼酸铁。

6. 发明授权

EP0379245B1 Process and plant for the processing of slag from aluminium scrap and waste melting, recovery of components thereof and treatment of gasses generated 失效
标题翻译：方法和装置用于从铝废料和废物的熔融处理炉渣，回收的累积气体的成分和治疗。
公开(公告)号：EP0379245B1
公开(公告)日：1994-04-06
申请号：EP90200079.3
申请日：1990-01-12
申请人： B.U.S. ENGITEC SERVIZI AMBIENTALI S.r.l.
发明人： Olper, Marco , Corsini, Tullio , Fracchia, Pierluigi
IPC分类号： C22B7/04 , C22B21/00
CPC分类号： C22B7/04 , C22B21/0007 , Y02P10/218

7. 发明公开

EP0313153A1 Hydrometallurgical process for recovering in pure metal form all the lead contained in the active mass of exhausted batteries 失效
标题翻译：从废旧电池的活性材料中回收的全部纯金属Bleies的湿法冶金方法。
公开(公告)号：EP0313153A1
公开(公告)日：1989-04-26
申请号：EP88202285.8
申请日：1988-10-13
申请人： B.U.S. ENGITEC SERVIZI AMBIENTALI S.r.l.
发明人： Olper, Marco , Fracchia, Pierluigi
IPC分类号： H01M10/54 , C22B3/00
CPC分类号： H01M10/54 , C22B13/045 , Y02P10/212 , Y02W30/84
摘要： A totally hydrometallurgical process for recovering in pure metal form all the lead contained in the active mass of used batteries, separated from the other processes, and desulphurized according to known processes, is disclosed.
The raw material is leached with an acid suitable for electrowinning. The residue from the acidic leaching is substantially formed by PbO₂ and organic substances.
This residue is transformed into lead sulphate by reacting it with concentrated sulphuric acid, and the so obtained lead sulphate is recycled to the desulphurization step.
By this system, a nearly complete solubilization of the lead contained in the active mass of the batteries is achieved, with the absence of any polluting residues. The electrolyte is the submitted to electrolysis in order to recover lead as cathodes.
摘要翻译：在METALFORM包含在用于电池的活性物质的所有引线，从其它过程分离，并且脱硫gemäß回收纯已知方法中的全湿法冶金工艺，是游离缺失盘。原料浸出用酸为适合于电解。从酸性浸出残余物基本上由二氧化铅和有机物质形成。该残余物用浓硫酸反应它转化成硫酸铅，和太阳获得硫酸铅循环至脱硫步骤。通过这个系统，包含在电池的活性物质的铅几乎完全溶解得以实现，与没有任何污染的残留物。为了回收铅作为阴极电解液被提交到电解。

8. 发明公开

EP0551155A1 Process for recovering zinc and lead from flue dusts from electrical steel works and for recycling said purified metals to the furnace, and installation for implementing said process 失效
标题翻译：一种用于锌和铅从烟道粉尘从电钢厂，以及用于返回纯化金属熔炉和植物恢复为执行该方法的过程。
公开(公告)号：EP0551155A1
公开(公告)日：1993-07-14
申请号：EP93200018.5
申请日：1993-01-06
申请人： B.U.S. ENGITEC SERVIZI AMBIENTALI S.r.l.
发明人： Olper, Marco , Fracchia, Pier Luigi , Maccagni, Massimo
IPC分类号： C22B7/02 , C22B3/14 , C22B15/00 , C22B19/28
CPC分类号： C22B13/045 , C22B7/02 , C22B15/008 , C22B17/04 , C22B19/28 , Y02P10/234 , Y02P10/236
摘要： Process for extracting metals, such as zinc, lead, copper and cadmium, from flue dusts coming from electrical furnaces for steel making, which process comprises:

(a) treating said flue dusts with an aqueous solution of ammonium chloride and sodium chloride, with zinc, cadmium and copper being dissolved as ammine-complexes, and lead being dissolved as a chlorocomplex;
(b) separating the resulting solution from the solid residue;
(c) treating the solution from (b) with zinc powder in order to precipitate, by substitution, nobler-than-zinc metals in the electrochemical series;
(d) separating the solution from the precipitate obtained in (c);
(e) electrowinning zinc from the solution obtained in (d), in an electrolysis cell, with zinc being deposited at the cathode and oxygen developing at the anode;
(f) treating further flue dusts from electrical furnaces with the zinc-depleted solution from (e);
(g) recycling the residue from (b) to the electrical furnace, in order to reduce iron oxide and fumigate the zinc contained therein, as zinc ferrite.
摘要翻译：过程，用于提取金属，颜色：如锌，铅，铜和镉，从烟道粉尘从电炉来炼钢，该方法包括：（a）处理所述烟道粉尘与氯化铵和氯化钠wässrige溶液中，用锌，镉和铜溶解作为氨络合物，和铅被溶解作为chlorocomplex; （B）分离固体残余物得到的溶液; （C）处理从（b）与锌粉的溶液，以便沉淀，通过取代，在电化学系列比锌更贵重-金属; （D）分离在（c）中获得的沉淀物的溶液; （E）从在（d）中获得的溶液电解锌，在电解电池中，与锌在阴极和氧气在阳极显影被沉积; （F）进一步处理从电炉粉尘烟气与来自（e）中的锌贫化的溶液; （G）再循环从（b）向所述电炉，铁素体，以减少氧化铁和熏蒸锌其中所含的残余物，如锌。 Ť

9. 发明授权

EP0313153B1 Hydrometallurgical process for recovering in pure metal form all the lead contained in the active mass of exhausted batteries 失效
标题翻译：用于在纯金属形式中回收所有含铅的活性质量的超滤电池
公开(公告)号：EP0313153B1
公开(公告)日：1993-01-13
申请号：EP88202285.8
申请日：1988-10-13
申请人： B.U.S. ENGITEC SERVIZI AMBIENTALI S.r.l.
发明人： Olper, Marco , Fracchia, Pierluigi
IPC分类号： H01M10/54 , C22B3/00
CPC分类号： H01M10/54 , C22B13/045 , Y02P10/212 , Y02W30/84

10. 发明公开

EP0454257A1 Process for the integral recovery of the sulphur contained in spent lead batteries, obtained in the form of pure sulphuric acid for reuse in the production of new batteries 失效
标题翻译：一种用于从用过的铅酸电池在纯硫酸中在生产新的电池再利用的形式的硫的积分恢复过程。
公开(公告)号：EP0454257A1
公开(公告)日：1991-10-30
申请号：EP91200965.1
申请日：1991-04-22
申请人： B.U.S. ENGITEC SERVIZI AMBIENTALI S.r.l.
发明人： Olper, Marco , Fracchia, Pierluigi
IPC分类号： H01M10/54
CPC分类号： H01M10/54 , Y02W30/84
摘要： The invention relates to a process for recovering the components of spent lead acid batteries of the type comprising an active mass desulphurization stage in which sodium sulphate is formed, characterised in that the sodium sulphate solution thus formed is fed to an electrolysis stage in which a soda solution is produced at the cathode and a sulphuric acid solution is produced at the anode, said soda solution produced at the cathode being recycled to said active mass desulphurization stage and said sulphuric acid solution produced at the anode being recovered for reuse as battery electrolyte in the production of new lead acid batteries.
摘要翻译：本发明涉及一种用于回收的类型包括其中硫酸钠活性物质脱硫阶段的废铅酸电池的部件形成，DASS由此形成在电解阶段被馈送到硫酸钠溶液，其中的钠溶液在阴极产生和硫酸溶液在阳极产生，所述阴极处产生的苏打溶液被再循环到所述的活性物质的脱硫阶段和所述回收再利用作为电池电解质在阳极处产生的硫酸溶液新的生产铅酸电池。

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