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    • 8. 发明公开
    • POLYROTAXANE, AQUEOUS POLYROTAXANE DISPERSION COMPOSITION, CROSSLINKED BODY OF POLYROTAXANE AND POLYMER AND METHOD FOR PRODUCING THE SAME
    • 聚轮烷,含水POLYROTAXANDISPERSIONSZUSAMMENSETZUNG,生产交联聚轮烷体和聚合物工艺
    • EP2287206A1
    • 2011-02-23
    • EP09754581.8
    • 2009-05-15
    • Advanced Softmaterials Inc.
    • HAYASHI, YukiSHIBUYA, MarikoKUDOH, MasabumiYAMANAKA, Masahiko
    • C08B37/16C08G65/333
    • C08G65/333C08G83/007C08L71/02C08L2666/26
    • Provided are a polyrotaxane capable of using an aqueous solvent in a fabricating process although it has hydrophobicity, an aqueous composition having the polyrotaxane, a crosslinked body comprising the polyrotaxane, etc. The polyrotaxane comprises blocking groups located at both ends of a pseudo-polyrotaxane having cyclic molecules and a linear molecule which pierces the cavities of the cyclic molecules in a skewered manner to form a clathrate therewith so as not to detach the cyclic molecules, wherein the cyclic molecules have a group represented by Formula I, a group represented by Formula II and a group represented by Formula III. Incidentally, M represents, for example, a group derived from ring-opening polymerization of ε-caprolactone or the like, A represents a hydroxy group or the like, B represents a -COOH group or the like, and C represents A and/or B:

              -M-A     Formula I;

              -M-B     Formula II;

      and

              -C     Formula III.
    • 本发明提供能够使用在制造工艺wässrige溶剂虽然具有上述聚轮烷它具有疏水性在wässrige组合物的聚轮烷,交联体,其包括在聚轮烷等聚轮烷包括阻断位于两组伪聚轮烷的端部具有 环状分子和刺穿以穿串状的环状分子的空腔与以免脱离环状分子,worin环状分子有形成包合物的线性分子有一组由式I表示,一组由式II表示 和一组由式III表示。 顺便说一下,男darstellt,例如,从μ己内酯等的开环聚合衍生的基团,A darstellt羟基或类似物,B darstellt COOH基团或类似物,和C darstellt A和/或 B:€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ-MA€ƒ€ƒ€ƒ€ƒ€ƒFormulaI; €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ-M-B€ƒ€ƒ€ƒ€ƒ€ƒFormulaII; 和€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ-C€ƒ€ƒ€ƒ€ƒ€ƒFormulaIII。