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    • 7. 发明公开
    • THERMOCHROMIC WRITING INSTRUMENT
    • 仪器ZUM THERMOCHROMEN SCHREIBEN
    • EP3121027A1
    • 2017-01-25
    • EP16183545.9
    • 2008-02-08
    • THE PILOT INK CO., LTD.Kabushiki Kaisha Pilot Corporation (also trading as Pilot Corporation)
    • INAMURA, YoshinoriSEKINE, NobuoANDO, Masashi
    • B43K7/12B43K24/06B43K24/08B43K24/12C09D11/16B43K1/08B43K23/12B43K27/12B43K29/02B43K7/02B43K7/08B43K7/10C09D11/00
    • B43K5/16B43K1/086B43K7/02B43K7/08B43K7/10B43K7/12B43K23/12B43K24/06B43K24/08B43K24/082B43K24/12B43K27/12B43K29/02C09D11/16C09D11/50
    • A thermochromic writing instrument containing a thermochromic ink (83) comprises a barrel (2) and a writing body (8) accommodated in the barrel (2). A pen tip (81) capable of ejecting the thermochromic ink (83) is provided at a front end of the writing body (8), and a friction portion (4), having a low abrasion property, capable of thermally changing color of the handwriting of the thermochromic ink (83) by the frictional heat generated when the handwriting is rubbed with the friction portion (4) is provided on the outer surface of the barrel (2). The writing body (8) is accommodated in the barrel (2) so as to be capable of moving in a longitudinal direction, and the thermochromic writing instrument further comprises an operation portion (5) provided on the outer surface of the barrel (2) so as to project radially outward from a side wall of the barrel (2). The pen tip (81) of the writing body (8) is adapted to project from / retract into a front-end hole (31) of the barrel (2) by operating the operation portion (5). The thermochromic writing instrument further comprises a side slide type projection/retraction mechanism which shifts the pen tip (81) from the pen-tip-retracted state to the pen-tip-projected state by a forward press operation of the operation portion (5). The friction portion (4) is provided at the front end of the barrel (2), whereby the friction portion (4) and the operation portion (5) are disposed independently of each other on the outer surface of the barrel (2).
    • 包含热变色油墨(83)的热变色书写工具包括容纳在筒体(2)中的筒体(2)和书写本体(8)。 一种能够喷射热变色油墨(83)的笔尖(81)设置在书写本体(8)的前端,并且具有低磨损性能的摩擦部分(4)能够热变色 在手指与摩擦部分(4)摩擦时产生的摩擦热被设置在筒体(2)的外表面上,使热变色油墨(83)的手写。 书写体(8)容纳在筒体(2)中以能够沿纵向移动,并且热变色书写工具还包括设置在镜筒(2)的外表面上的操作部分(5) 从而从筒体(2)的侧壁向径向外侧突出。 书写体(8)的笔尖(81)适于通过操作操作部分(5)从所述筒体(2)的前端孔(31)突出/缩回。 热变色书写工具还包括侧滑动型投影/缩回机构,其通过操作部分(5)的向前按压操作将笔尖(81)从笔尖缩回状态移动到笔尖投影状态, 。 摩擦部分(4)设置在枪管(2)的前端,摩擦部分(4)和操作部分(5)彼此独立地设置在枪管(2)的外表面上。
    • 8. 发明公开
    • THERMOCHROMIC COLOR-MEMORY COMPOSITION AND THERMOCHROMIC COLOR-MEMORY MICROCAPSULE PIGMENT ENCAPSULATING THE SAME
    • 热血红蛋白US AM UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG UNG
    • EP3103853A1
    • 2016-12-14
    • EP15746368.8
    • 2015-02-04
    • THE PILOT INK CO., LTD.
    • ONO Yoshiaki
    • C09K9/02B41M5/337C09B67/08C09D11/037C09D11/17
    • B43K8/00B41M5/305B41M5/323B41M5/3333B41M5/3375C09B67/0097C09D11/037C09D11/17C09D11/18C09D11/50C09K9/02C09K2211/1007
    • [Problems] An object of the present invention is to provide: thermochromic color-memory composition which effectively expresses a property of being capable of interchangeably memorizing and retaining colors and is thus applicable to various fields; and thermochromic color-memory microcapsule pigment encapsulating the same.
      [Means for Solution] Provided are thermochromic color-memory composition and thermochromic color-memory microcapsule pigment encapsulating the same, the thermochromic color-memory composition including: (a) a component composed of an electron-donating color-developing organic compound; (b) a component composed of an electron-accepting compound; and (c) a component composed of an ester compound represented by the following Formula (1) as a reaction medium which controls color reaction between the components (a) and (b):

      (wherein, R represents an alkyl group having 3 to 18 carbon atoms or an aliphatic acyl group having 3 to 18 carbon atoms; X represents a hydrogen atom, an alkyl group having 1 to 3 carbon atoms, an alkoxy group having 1 or 2 carbon atoms or a halogen atom; Y represents a hydrogen atom or a methyl group; and Z represents a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 or 2 carbon atoms or a halogen atom).
    • 本发明的目的在于提供一种能够有效地表现出能够互换地记忆和保持颜色的性质的热致变色色记忆体组合物,因此适用于各种领域; 和包含其的热变色色记忆微胶囊颜料。 [解决方案]提供了一种热变色色记忆组合物和包含其的热变色色记忆微胶囊颜料,该热变色色记忆组合物包括:(a)由给电子显色有机化合物组成的组分; (b)由电子接受性化合物构成的成分; 和(c)由下式(1)表示的酯化合物组成的组分作为控制组分(a)和(b)之间的显色反应的反应介质:(其中R表示具有3至18个的烷基 碳原子或碳原子数3〜18的脂肪族酰基; X表示氢原子,碳原子数1〜3的烷基,碳原子数1〜2的烷氧基或卤素原子; Y表示氢原子或 甲基; Z表示氢原子,碳原子数1〜4的烷基,碳原子数为1或2的烷氧基或卤原子)。