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    • 7. 发明公开
    • PROCESS FOR MAKING ETHYLENIC POLYMER FOAM STRUCTURES
    • VERFAHREN ZUR HERSTELLUNG VON ETHYLENISCHEN POLYMERSCHAUMSTRUKTUREN
    • EP0689562A4
    • 1996-03-13
    • EP94910840
    • 1994-03-04
    • DOW CHEMICAL CO
    • PARK CHUNG PSTEVENS JAMES CKNIGHT GEORGE W
    • C08J9/14C08J9/18C08J9/00
    • C08J9/14C08J2323/16Y10S526/943
    • Disclosed is an ethylenic polymer foam structure comprising an ethylenic polymer material. The ethylenic polymer material contains a substantially linear ethylenic polymer having: a) a melt flow ratio, l10/l2 » 5.63; b) a molecular weight distribution, Mw/Mn, defined by the equation Mw/Mn « (l10/l2)-4.63; and c) a critical shear rate at onset of surface melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a linear olefin polymer having about the same l2 and Mw/Mn. The foam structures have toughness and elasticity similar to those formed from conventional LLDPE without the poor dimensional stability and foam quality associated with those structures. The foam structures have foam quality similar to those made with conventional LDPE but with enhanced toughness and elasticity. Further disclosed is a process for making the above foam structure and making it in a foam bead form. Further disclosed is a process for making an article of the foam beads.
    • 公开了包含乙烯类聚合物材料的乙烯类聚合物泡沫结构。 该乙烯型聚合物材料含有基本上线性的乙烯型聚合物,其具有:a)熔体流动比率,10/12·5.63; b)通过方程式Mw /Mn≈(110/12)-4.63定义的分子量分布,Mw / Mn; 和c)表面熔体破裂开始时的临界剪切速率比具有约相同l2和Mw / Mn的线性烯烃聚合物在表面熔体破裂开始时的临界剪切速率高至少50%。 泡沫结构具有类似于由常规LLDPE形成的韧性和弹性,而没有与这些结构相关的差的尺寸稳定性和泡沫质量。 泡沫结构具有类似于使用常规LDPE制造的泡沫质量,但具有增强的韧性和弹性。 还公开了用于制造上述泡沫结构并将其制成泡沫珠状的方法。 还公开了制造泡沫珠粒物品的方法。