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    • 87. 发明公开
    • Method for the preparation of an improved photographic tabular emulsion rich in chloride
    • Verfahren zur Herstellung einer动物desserten photoischen乳液mit氯酸盐Tafelkörnern
    • EP0843207A1
    • 1998-05-20
    • EP97202948.2
    • 1997-09-23
    • AGFA-GEVAERT N.V.
    • Verrept, PeterAndriessen, Hieronymus
    • G03C1/005G03C1/035G03C1/047
    • G03C1/0053G03C1/047G03C5/16G03C2001/03558G03C2001/0818G03C2200/01Y10S430/167
    • A method is disclosed of preparing of a photographic silver halide emulsion comprising precipitating in one or more precipitation steps in a reaction vessel, followed by desalting by means of flocculation and washing or by means of ultrafiltration, said emulsion comprising gelatin as a binder and {100} tabular silver halide grains containing at least 50 mole % of chloride, wherein at least 40 % by number of all grains is provided by said tabular grains, and wherein said tabular grains exhibit an average aspect ratio of at least 2, an average thickness of at most 0.5 µm, and an average equivalent circular crystal diameter of 0.3 µm or more, characterized in that during said precipitation step(s) said gelatin binder present in said reaction vessel is substantially free of calcium ions and is oxidised to a degree in order to have a methionine content of at most 4000 ppm.
    • 公开了一种制备照相卤化银乳剂的方法,包括在反应容器中的一个或多个沉淀步骤中沉淀,然后通过絮凝和洗涤或通过超滤脱盐,所述乳液包含明胶作为粘合剂和ä100ü表格 含有至少50摩尔%氯化物的卤化银颗粒,其中由所述片状颗粒提供至少40%的全部颗粒,并且其中所述片状颗粒的平均纵横比为至少2,平均厚度至多为 0.5μm,平均当量圆形晶体直径为0.3μm或更大,其特征在于,在所述沉淀步骤期间,存在于所述反应容器中的所述明胶粘合剂基本上不含钙离子并按顺序氧化至一定程度 具有至多4000ppm的甲硫氨酸含量。