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    • 81. 发明公开
    • Image recording material
    • Bildaufzeichnungsmaterial
    • EP1325810A2
    • 2003-07-09
    • EP03000042.6
    • 2003-01-07
    • FUJI PHOTO FILM CO., LTD.
    • Aoshima, Keitaro
    • B41C1/10G03F7/004
    • G03F7/035B41C1/1008B41C1/1016B41C2201/02B41C2201/14B41C2210/04B41C2210/06B41C2210/22B41C2210/24G03F7/033G03F7/037G03F7/038G03F7/0384G03F7/0387G03F7/0388
    • The invention provides a negative image recording material comprising: a support and an image recording layer disposed on the support, the image recording layer comprising an amide-acid compound containing a carboxyl group and an amide group expressed by the following General Formula (1):
         wherein L 11 represents a hydrogen atom or a hydrocarbon group having 30 or fewer carbon atoms which may have a substituent; and wherein the amide-acid compound is insolubilized by a thermal ring-closure reaction between the carboxyl group and the amide group.
      The invention further provides a negative image recording material comprising a support, an image recording layer disposed on the support, the image recording layer containing a polymerization initiator and a polymerizable compound, and an overcoat layer disposed on the image recording layer, the overcoat layer containing the amide-acid compound expressed by the General Formula (1).
    • 本发明提供一种负型图像记录材料,包括:载体和设置在载体上的图像记录层,该图像记录层包含由以下通式(1)表示的含羧基和酰胺基的酰胺酸化合物: 其中L 11表示氢原子或具有30个以下可具有取代基的碳原子的烃基; 并且其中酰胺酸化合物通过羧基和酰胺基之间的热封闭反应而不溶解。 本发明还提供了一种负型图像记录材料,包括载体,设置在载体上的图像记录层,含有聚合引发剂的图像记录层和可聚合化合物,以及设置在图像记录层上的外涂层, 所述外涂层含有由通式(1)表示的酰胺酸化合物。
    • 82. 发明公开
    • PHOTOSENSITIVE RESIN COMPOSITION AND FLEXOGRAPHIC RESIN PLATE
    • FOTOEMPFINDLICHE ZUSAMMENSETZUNGEN UND FLEXODRUCKPLATTE
    • EP0950923A1
    • 1999-10-20
    • EP98951683.6
    • 1998-11-04
    • TOKYO OHKA KOGYO CO., LTD.Nippon Shokubai Co., Ltd.
    • TAKAGI, ToshiyaAOYAMA, ToshimiKAHARA, KojiKOBAYASHI, NobuhiroYOSHIDA, Masatoshi
    • G03F7/027G03F7/00C08G18/67
    • C08G18/4018C08G18/67C08G18/672C08G18/8175G03F7/035G03F7/0388
    • The present invention provides a photosensitive resin composition which comprises an urethane resin obtained by reacting (A) a carboxyl group-containing polymer having an acid value of 30 mg KOH/g or more and a glass transition temperature of 30°C or more, (B) a compound having two isocyanate groups in one molecule, (C) a compound having two hydroxyl groups in one molecule and (D) a photopolymerizable unsaturated monomer having one hydroxyl group in one molecule, and a photopolymerization initiator, and a resin plate for flexography using the photosensitive resin composition, whereby the photosensitive resin composition having water developing properties, high in sensitivity and impact resilience, and excellent in water resistance, ink resistance and press life of a hardened portion forming a line pattern area of a printing plate material and the resin plate for flexography prepared by the use of the photosensitive resin composition can be provided.
    • 本发明提供一种感光性树脂组合物,其包含通过使(A)含有酸值为30mg KOH / g以上且含有30℃以上的玻璃化转变温度的含羧基聚合物与(A) B)在一个分子中具有两个异氰酸酯基的化合物,(C)在一个分子中具有两个羟基的化合物和(D)在一个分子中具有一个羟基的光聚合性不饱和单体和光聚合引发剂,以及用于 使用感光性树脂组合物的柔性印刷版,由此具有水显影性,高灵敏度和回弹性的感光性树脂组合物,形成印版材料的线图案区域的硬化部分的耐水性,耐油墨性和印刷寿命优异, 可以提供通过使用感光性树脂组合物制备的用于柔性版印刷用树脂板。
    • 83. 发明公开
    • Photocurable polyurethane-acrylate ionomer compositions for aqueous developable printing plates
    • 光固化性聚氨酯丙烯酸酯的离聚物组合物的水性可显影的印刷板。
    • EP0602292A1
    • 1994-06-22
    • EP92311588.5
    • 1992-12-18
    • PT Sub, Inc.
    • Huynh-Tran, Truc-Chi Thi
    • G03F7/027G03F7/035C08F299/06C08G18/10C08G18/08C08G18/67
    • G03F7/0384C08G18/638C08G18/672C08G18/675G03F7/035Y10S430/114Y10S430/128C08G18/0823C08G18/63C08G18/6674
    • A photopolymer useful in preparing water-developable, solid printing plates is prepared by (A) preparing a urethane prepolymer by reacting a polyoxyalkylene diol (optionally carboxylic acid grafted) with an excess of diisocyanate, followed by chain extending the resulting prepolymer mixture with a dialkylolpropionic acid and preferably with additional diols(s) such as alkane diol(s) and (meth)acrylate-containing diol(s). Use of a new (meth)acrylate-containing diol in such chain extension completes the formation of photopolymer. However, in a third operation (B) hydroxyalkylmethacrylate may be reacted with the result of (A) whether or not (meth)acrylate-containing diol is used in (A). The carboxylic acid groups of the photopolymer may also be partially neutralized with a base. The photopolymer is suitably formulated with additional photoactive (meth)acrylate monomers or oligomers and photoinitiator for casting on a substrate or extruding to form a flexographic printing plate. Following UV exposure of the plate through a negative, unexposed areas can be removed by washing with an aqueous alkaline solution to give a plate with a desirable relief image. The use of the aqueous alkaline washout solution as opposed to organic solvents minimizes pollution problems.
    • 在制备水可显影,固体印刷板中有用的光聚合物是由(A)制备通过在过量二异氰酸酯反应的聚氧化烯二醇(任选地羧酸接枝的)用制备的聚氨酯预聚物,随后链将所得的预聚物混合物与dialkylolpropionic扩展 酸,优选与另外的二醇(或多个):如烷烃二醇(S)和(甲基)二醇(S)含有丙烯酸酯 - 。 一个新的(甲基)丙烯酸酯含有的搜索扩链二醇的使用完成光聚合物的形成。 然而,在第三操作(B)羟基 - 甲基丙烯酸烷基酯可以与(A)的结果进行反应是否含丙烯酸酯的(甲基)二醇(A)中使用。 光聚合物的羧酸基团可以因此用碱部分中和。 光聚合物适当地与额外的光活性(甲基)丙烯酸酯单体或低聚物和光引发剂用于铸造上的基片或挤出,以形成柔性版印版配制。 通过负,未曝光的区域之后的板的UV曝光可以通过在wässrige碱性溶液与洗涤,得到具有浮雕图像,较好的一个板被移除。 相对于有机溶剂的使用wässrige碱性冲洗溶液的最小化污染问题。