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81. 发明公开

EP2150497A2 VERFAHREN ZUR RÜCKGEWINNUNG VON RUTHENIUM AUS EINEM RUTHENIUMHALTIGEN GETRÄGERTEN KATALYSATORMATERIAL 审中-公开
标题翻译： PROCESS FOR回收来自钌含钌负载催化剂材料
公开(公告)号：EP2150497A2
公开(公告)日：2010-02-10
申请号：EP08735260.5
申请日：2008-04-16
申请人： Bayer MaterialScience AG
发明人： HAAS, Michel , WEUTA, Peter , WOLF, Aurel , SCHLÜTER, Oliver, Felix-Karl
IPC分类号： C01G55/00 , C22B11/02
CPC分类号： C01G55/005 , B01J23/462 , B01J23/626 , B01J23/96 , B01J38/68 , C22B3/10 , C22B11/048 , C22B11/06 , H01L28/65 , H01M4/92 , H01M4/923 , H01M4/925 , H01M8/008 , Y02P10/214 , Y02P10/234 , Y02P20/584 , Y02P70/56 , Y02W30/86
摘要： The invention relates to a method for the recovery of ruthenium in the form of ruthenium halide, in particular ruthenium chloride from a supported catalyst material containing ruthenium, comprising at least the following steps: a) chemical decomposition of the catalyst material, b) production of a crude ruthenium salt solution, c) purification of the crude ruthenium salt solution and optional expulsion of gaseous ruthenium tetraoxide from said solution, d) subsequent treatment of the purified ruthenium compound contained in c), in particular the ruthenium tetraoxide with hydrogen halide or hydrohalic acid to obtain ruthenium halide, or in particular with hydrogen chloride or hydrochloric acid to obtain ruthenium chloride.

82. 发明授权

EP1313559B1 RECYCLABLE METATHESIS CATALYSTS 有权
标题翻译：可重复使用的复分解催化剂
公开(公告)号：EP1313559B1
公开(公告)日：2009-11-11
申请号：EP01963854.3
申请日：2001-08-09
申请人： Trustees of Boston College
发明人： HOVEYDA, Amir, H. , KINGSBURY, Jason , GARBER, Steven , GRAY, Brian, Lawrence , FOURKAS, John, T.
IPC分类号： B01J31/00 , C07F7/08 , C07F9/28 , C07F15/00
CPC分类号： C07F15/0046 , B01J23/462 , B01J31/1625 , B01J31/1641 , B01J31/1666 , B01J31/1683 , B01J31/1805 , B01J31/2208 , B01J31/2273 , B01J31/2404 , B01J31/28 , B01J31/4038 , B01J2231/482 , B01J2231/543 , B01J2531/821 , C07B2200/11 , C07C6/02 , C07C29/00 , C07C67/293 , C07C2531/22 , C07C2601/08 , C07C2601/16 , C07D233/56 , C08F290/00 , C08G83/003 , C08L51/04 , C08L51/08 , Y02P20/584 , Y02P20/588 , C07C35/18 , C07C35/06 , C07C35/21 , C07C69/013 , C07C69/145
摘要： Hyghly active, recoverable and recyclable transition metal-based metathesis catalysts and their organometallic complexes including dendrimeric complexes are disclosed, including a Ru complex bearing a 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene and styrenyl ether ligand. The heterocyclic ligand significantly enhances the catalytic activity, and the styrenyl ether allows for the easy recovery of the Ru complex. Derivatized catalysts capable of being immobilized on substrate surfaces are also disclosed. The present catalysts can be used to catalyze ring-closing metathesis (RCM), ring-opening (ROM) and cross metatheses (CM) reactions, and promote the efficient formation of various trisubstituted olefins at ambient temperature in high yield.

83. 发明公开

EP2103593A1 PROCESS FOR PRODUCTION OF NITROGENATED COMPOUND 审中-公开
标题翻译： VERFAHREN ZUR HERSTELLUNG EINER NITROGENIERTEN VERBINDUNG
公开(公告)号：EP2103593A1
公开(公告)日：2009-09-23
申请号：EP07831209.7
申请日：2007-11-05
申请人： Kao Corporation
发明人： SUZUKI, Yuuta , MIMURA, Yasuyuki , FUKUSHIMA, Tetsuaki
IPC分类号： C07C209/14 , B01J23/46 , B01J23/89 , B01J27/053 , B01J37/03 , B01J37/08 , B01J37/16 , C07C211/07 , C07B61/00
CPC分类号： C07C209/16 , B01J21/063 , B01J21/066 , B01J23/462 , B01J23/892 , B01J23/894 , B01J23/8946 , B01J27/053 , B01J35/1014 , B01J35/1019 , B01J37/03 , B01J37/031 , B01J37/035 , B01J37/16 , C07C209/14 , C07C211/07 , C07C211/08
摘要： The present invention relates to a process for producing an aliphatic primary amine or an aliphatic secondary amine from an aliphatic alcohol with a high catalytic activity and a high selectivity. In the process for producing an aliphatic amine according to the present invention, a linear, branched, or cyclic aliphatic alcohol having 6 to 22 carbon atoms is contacted with ammonia and hydrogen in the presence of a catalyst formed by supporting a ruthenium component on at least one material selected from the group consisting of (B) a zirconia-containing composite oxide and (C) zirconia surface-treated with a metal by hydrolysis of (A) a ruthenium compound.
摘要翻译：本发明涉及从具有高催化活性和高选择性的脂族醇生产脂族伯胺或脂族仲胺的方法。在本发明的脂肪族胺的制造方法中，将具有6〜22个碳原子的直链状，支链状或环状的脂肪族醇与氨和氢接触，在至少含有钌组分的催化剂存在下，一种选自（B）含氧化锆复合氧化物的材料和（C）通过水解（A）钌化合物用金属表面处理的氧化锆。

84. 发明公开

EP2055378A1 Method for preparing ruthenium-carrying alumina and method for oxidizing alcohol 审中-公开
标题翻译：基于氧化铝和方法，用于为Alkoholoxidierung负载的钌催化剂的制备方法
公开(公告)号：EP2055378A1
公开(公告)日：2009-05-06
申请号：EP08017943.5
申请日：2003-04-25
申请人： Sumitomo Chemical Company, Limited
发明人： Mizuno, Noritaka , Yamaguchi, Kazuya , Ishida, Hajime
IPC分类号： B01J23/46 , C07B61/00 , C07D333/22 , C07C45/38 , C07C45/39 , C07C47/54 , C07C47/542 , C07C47/575 , C07C47/55 , C07C49/78 , C07C49/792
CPC分类号： C07D333/22 , B01J21/04 , B01J23/462 , B01J37/031 , C07C45/38 , C07C45/39 , C07C51/235 , C07C53/126
摘要： A ruthenium-carrying alumina, which is prepared by suspending alumina in a solution containing trivalent ruthenium and adding a base to the suspension, is provided. This ruthenium-carrying alumina is useful as a catalyst for oxidizing alcohols by contacting the alcohols with molecular oxygen, and can be used for oxidizing the alcohols at a high conversion to produce ketones, aldehydes, carboxylic acids, etc. with good productivity.
摘要翻译：这是由在溶液中含有三价钌助悬氧化铝和将碱加入到该悬浮液制备的钌载氧化铝，所有被提供的。此钌载氧化铝是作为用于通过接触与分子氧的氧化醇醇制造用催化剂是有用的，并且可用于以高转化率氧化醇以产生酮，醛，羧酸等具有良好的生产率。

85. 发明公开

EP2049255A2 VERFAHREN ZUR REGENERIERUNG VON RUTHENIUMKATALYSATOREN FÜR DIE HYDRIERUNG VON BENZOL 审中-公开
标题翻译：的再生方法的钌催化剂为苯的氢化
公开(公告)号：EP2049255A2
公开(公告)日：2009-04-22
申请号：EP07787973.2
申请日：2007-07-27
申请人： BASF SE
发明人： HENKELMANN, Jochem , BECKER, Michael , SCHOENHERR, Michael , RUPPEL, Wilhelm , WEGERLE, Ulrike , STAECK, Bianca
IPC分类号： B01J23/46 , B01J38/04 , C07C5/10
CPC分类号： B01J38/04 , B01J23/40 , B01J23/462 , B01J23/75 , B01J23/755 , B01J23/96 , C07C5/10 , C07C2523/46 , Y02P20/584 , Y10S585/906 , C07C13/18
摘要： The present application describes a process for regenerating a ruthenium catalyst for the hydrogenation of benzene, which comprises flushing the catalyst with inert gas in a regeneration step until the original or part of the original activity is attained.

86. 发明授权

EP1500432B1 METHOD FOR OXIDIZING ALCOHOL ON A RUTHENIUM-CARRYING ALUMINA CATALYST 有权
标题翻译：基于铝醇的氧化上的钌的负载型催化剂的制备方法
公开(公告)号：EP1500432B1
公开(公告)日：2009-04-22
申请号：EP03717729.2
申请日：2003-04-25
申请人： Sumitomo Chemical Company, Limited
发明人： MIZUNO, Noritaka , YAMAGUCHI, Kazuya , ISHIDA, Hajime
IPC分类号： B01J23/46 , C07B61/00 , C07D333/22 , C07C45/38 , C07C45/39 , C07C47/54 , C07C47/542 , C07C47/575 , C07C47/55 , C07C49/78 , C07C49/792 , C07C47/232 , C07C47/21 , C07C49/04 , C07C49/403 , C07C49/203 , C07C27/00 , C07C47/02 , C07C51/235 , C07C53/126 , C07C49/395
CPC分类号： C07D333/22 , B01J21/04 , B01J23/462 , B01J37/031 , C07C45/38 , C07C45/39 , C07C51/235 , C07C53/126
摘要： A method for preparing a ruthenium-carrying alumina which comprises suspending alumina in a solution containing a tri-valent ruthenium, and then adding a base to the resultant suspension. A ruthenium-carrying alumina is useful as a catalyst for use in contacting an alcohol with molecular oxygen to oxidize the alcohol, and can be used for oxidizing an alcohol at an enhanced conversion and producing a ketone, an aldehyde, a carboxylic acid and the like with improved productivity.

87. 发明公开

EP2008713A2 Nanoalloys in emissions control after-treatment system 审中-公开
标题翻译： Nanolegierungen in der Emissionssteuerung bei Nachbehandlungssystemen
公开(公告)号：EP2008713A2
公开(公告)日：2008-12-31
申请号：EP08157527.6
申请日：2008-06-04
申请人： Afton Chemical Corporation
发明人： Aradi, Allen A. , Huang, C. S. Warren
IPC分类号： B01J23/38 , B01J23/70 , B22F1/00
CPC分类号： B01J37/0215 , B01D53/945 , B01D2255/102 , B01D2255/104 , B01D2255/106 , B01D2255/202 , B01D2255/204 , B01D2255/2047 , B01D2255/20715 , B01D2255/2073 , B01D2255/20738 , B01D2255/20746 , B01D2255/20761 , B01D2255/20769 , B01D2255/2092 , B01D2255/908 , B01D2255/91 , B01J23/10 , B01J23/34 , B01J23/40 , B01J23/462 , B01J23/464 , B01J23/78 , B01J23/83 , B01J35/0013 , B01J37/036 , B01J37/038 , B01J37/346 , B22F1/0018 , B22F2998/00 , B82Y30/00 , Y02T10/22 , B22F9/24
摘要： There is disclosed a composition comprising an alloy represented by the following generic formula A a ) n (B b ) n (C c ) n (D d ) n (E e ) n (...) n ; wherein A is an oxygen storage agent; B is an anti-sintering agent; C is an oxidation catalyst; D is a reduction catalyst; and E is a NO x absorbing agent; wherein each subscript letter represents compositional stoichiometry; wherein n is greater than or equal to zero; wherein the sum of the n's is equal to or greater than 2, and wherein the alloy comprises at least two different metals. There is also disclosed a washcoat composition; a catalyst support; methods of making the alloy, the washcoat composition, and the catalyst support.
摘要翻译：公开了包含由以下通式A a）n（B b）n（C c）n（D d）n（E e）n（...）n表示的合金的组合物; 其中A是储氧剂; B是一种抗烧结剂; C是氧化催化剂; D是还原催化剂; E为NO x吸收剂; 其中每个下标字母表示组成化学计量; 其中n大于或等于零; 其中所述n的总和等于或大于2，并且其中所述合金包含至少两种不同的金属。还公开了修补基面涂料组合物; 催化剂载体; 制造合金的方法，修补基面涂层组合物和催化剂载体。

88. 发明授权

EP1451107B1 CATALYSTS FOR AMMONIA SYNTHESIS 有权
标题翻译：氨合成催化剂
公开(公告)号：EP1451107B1
公开(公告)日：2008-12-31
申请号：EP02782956.3
申请日：2002-10-18
申请人： Ammonia Casale S.A.
发明人： FORNI, Lucio , PERNICONE, Nicola
IPC分类号： C01C1/04 , B01J23/46 , B01J21/18
CPC分类号： B01J23/58 , B01J21/18 , B01J23/462 , B01J35/002 , B01J35/1019 , B01J37/0205 , C01C1/0411 , Y02P20/52
摘要： We claim catalysts for ammonia synthesis based on ruthenium, directly supported over graphite having BET specific surface area in excess of 10 m /g, preferably in excess of 100 m /g and more preferably in excess of 280 m /g, said graphite being characterised by X-ray diffraction pattern containing the diffraction lines characteristic of the crystalline graphite only, with exclusion of relevant bands due to amorphous carbon, to which catalysts barium, caesium and potassium are added as promoters. The graphitic supports allow to avoid the known pre-treatments and post-treatments needed in the case of supports obtained by partial graphitisation of active carbons and during use they are affected negligibly by the methanation shown by the supports obtained from active carbons. Furthermore, the catalysts of the present invention are characterised by a very high activity, even with ruthenium loadings well below the known loading.
摘要翻译：我们要求保护基于钌的氨合成催化剂，其直接负载在BET比表面积超过10m 2 / g，优选超过100m 2 / g，更优选超过280m 2 / g的石墨上， g，所述石墨的特征在于X射线衍射图仅包含结晶石墨的衍射线特征，排除由无定形碳引起的相关谱带，催化剂中加入钡，铯和钾作为助催化剂。石墨载体允许避免在通过活性炭部分石墨化获得的载体的情况下所需的已知预处理和后处理，并且在使用期间它们受从活性炭获得的载体显示的甲烷化可忽略的影响。此外，本发明的催化剂的特征在于非常高的活性，即使钌加载量远低于已知的加载量。

89. 发明公开

EP1958693A1 METHOD FOR PRODUCTION OF SUPPORTED RUTHENIUM AND METHOD FOR PRODUCTION OF CHLORINE 审中-公开
标题翻译：用于生产钌的负载和工艺来生产氯
公开(公告)号：EP1958693A1
公开(公告)日：2008-08-20
申请号：EP06834144.5
申请日：2006-11-30
申请人： Sumitomo Chemical Company, Limited
发明人： SEKI, Kohei
IPC分类号： B01J38/12 , B01J23/46 , B01J23/96 , C01B7/04
CPC分类号： B01J23/462 , B01J21/06 , B01J21/063 , B01J23/96 , B01J37/0009 , B01J38/10 , B01J38/68 , C01B7/04 , C22B11/026 , Y02P10/214 , Y02P20/584
摘要： The present invention provides a process for producing supported ruthenium, which comprises recovering a ruthenium compound from supported ruthenium used as a catalyst in production of chlorine by oxidation of hydrogen chloride with oxygen, and supporting the ruthenium compound on a carrier; and a process for producing chlorine, which comprises producing a supported ruthenium catalyst by the process mentioned above and oxidizing hydrogen chloride with oxygen in the presence of the supported ruthenium.
摘要翻译：本发明提供一种制备负载的钌，其包括回收来自通过氯化氢与氧的氧化作催化剂在生产氯气的负载的钌钌化合物，和支撑在载体上钌化合物的方法; 和用于生产氯，该方法包括制备由上述处理的负载的钌催化剂和在载持的钌的存在下用氧来氧化氯化氢的方法。

90. 发明授权

EP1565952B1 METAL ALLOY FOR ELECTROCHEMICAL OXIDATION REACTIONS AND METHOD OF PRODUCTION THEREOF 无效
标题翻译：合金用于电化学氧化反应和方法及其
公开(公告)号：EP1565952B1
公开(公告)日：2008-04-16
申请号：EP03775391.0
申请日：2003-11-25
申请人： BASF Fuel Cell GmbH
发明人： CAO, Lixin , TSOU, Yu-Min , DE CASTRO, Emory
IPC分类号： H01M4/88 , H01M4/92
CPC分类号： H01M4/921 , B01J23/462 , B01J37/086 , B01J37/18 , H01M4/8885
摘要： The invention is relative to an alloyed catalyst for electro-oxidation reactions, and in particular to a binary platinum-ruthenium alloy suitable as the active component of a direct methanol fuel cell anode, as well as to the method of producing the same.

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