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    • 79. 发明公开
    • Process for the recovery of alkylation catalyst
    • Verfahren zur Wiedergewinnung von Alkylierungskatalysator。
    • EP0671213A1
    • 1995-09-13
    • EP95102313.4
    • 1995-02-20
    • Haldor Topsoe A/S
    • Hommeltoft, Sven Ivar
    • B01J31/40C07C2/62
    • B01J31/0225B01J31/0224B01J31/0239B01J31/40B01J2231/4205C07C2/54C07C2531/025Y02P20/584
    • Process for the recovery of spent fluorinated sulphonic catalyst from acid soluble oil (ASO) being formed during alkylation of hydrocarbons in presence of the acid catalyst, comprising steps of
         washing the ASO with water and recovering an aqueous solution of the acid catalyst,
         neutralizing the acid in the aqueous solution by adding to the solution a basic compound being selected from the group of amino compounds, ammonia and ammonium salts, thereby, forming ammonium salts of the acid catalyst with a melting point at which the obtained acid catalyst salt in a subsequent concentration and drying step is in the form of a melt,
         drying the melt, and finally
         recovering the acid catalyst by protonisation of the dried melt with sulphuric acid and distilling off the recovered acid catalyst from the sulphuric acid.
    • 在酸催化剂存在下,在烃的烷基化期间由酸性溶解油(ASO)回收乏氟氟磺酸催化剂的方法,包括以下步骤:用水洗涤ASO并回收酸催化剂的水溶液,中和酸 在该溶液中通过向该溶液中加入选自氨基化合物,氨和铵盐的碱性化合物,由此形成酸催化剂的铵盐,其熔点在所得到的酸催化剂盐的浓度 并且干燥步骤为熔体形式,干燥熔体,最后通过用硫酸使干燥的熔体质子化回收酸催化剂,并从硫酸中蒸出回收的酸催化剂。