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71. 发明授权

EP1765956B1 PROCEDE DE SYNTHESE FISCHER-TROPSCH COMPRENANT UNE REGULATION AMELIOREE 失效转让
标题翻译：具有改进的控制费 - 托工艺过程
公开(公告)号：EP1765956B1
公开(公告)日：2010-08-04
申请号：EP05771067.5
申请日：2005-05-17
申请人： Institut Français du Pétrole , ENI S.p.A.
发明人： MARION, Marie-Claire , LEMAIRE, Eric , SCHWEITZER, Jean-Marc
IPC分类号： C10G2/00
CPC分类号： C10G2/332 , C10G2/30
摘要： The inventive method for producing liquid hydrocarbons by Fischer-Tropsch involves a stage (a) for generating a syngas, a stage (b) for carrying out a Fischer-Tropsch synthesis, a stage (c) for condensing a gas flow obtained at the stage (b), a stage (d) for separating the flow condensed at the stage (c), thereby obtaining a gas flow enriched in hydrocarbons and hydrogen and a stage (e) for recycling at least a part of the enriched gas flow obtained at the stage (d) towards the Fischer-Tropsch synthesis stage (b). Said method is characterised in that it consists 1) in determining two molar ratios A1 and A2 between hydrogen and carbon monoxide (H2/CO), wherein A1 is the value of said ratio in the supply of the synthesis stage (b) and A2 is the value of said ration in any of different gas flows obtained at the stages from (b) to (e), 2) in comparing the A1 and A2 ratios and 3) in adjusting the hydrogen and/or carbon monoxide concentration in the syngas in such a way that a substentially constant deviation between two A1 and A2 ratios is maintained.

72. 发明公开

EP2193841A1 Hydrocarbon synthesis catalyst and process with improved selectivity to short chain products 审中-公开
标题翻译：烃合成催化剂和方法，用于对短链产品改善的选择性
公开(公告)号：EP2193841A1
公开(公告)日：2010-06-09
申请号：EP08021305.1
申请日：2008-12-08
申请人： Sasol Technology (Proprietary) Limited
发明人： Crous, Reinier , Bromfield, Tracey, Carolyn , Booyens, Sharon
IPC分类号： B01J23/78 , B01J35/10 , C07C1/04 , C10G2/00 , B01J23/745 , B01J37/03 , B01J27/02 , B01J27/185 , B01J27/043 , B01J37/18
CPC分类号： B01J27/057 , B01J21/02 , B01J23/78 , B01J23/8435 , B01J35/023 , B01J35/1014 , B01J37/031 , B01J37/18 , B01J37/20 , B01J37/28 , C07C1/044 , C07C1/0445 , C07C2523/04 , C07C2523/745 , C07C2523/78 , C07C2523/843 , C07C2527/185 , C10G2/332 , C07C11/02
摘要： The present invention relates to a hydrocarbon synthesis catalyst comprising in its unreduced form
a) Fe as catalytically active metal,
b) an alkali metal and/or alkaline-earth metal in an alkali metal- and/or alkaline-earth metal-containing promoter, the alkali metal being present in an amount of from 0.1 to 1.0 g/100 g Fe,
c) and a further promoter comprising, or consisting of, one or more element(s) selected from the group of boron, silicon, germanium, nitrogen, phosphorus, arsenic, antimony, sulphur, selenium and tellurium, the element(s) being present in an amount of from 0.03 to 0.2 g/100 g Fe, and

wherein the catalyst in its unreduced form has a surface area of less than 50 m 2 /g, to a hydrocarbon synthesis process which is operated in the present of such a catalyst and to the use of such a catalyst in a hydrocarbon synthesis process.
摘要翻译：本发明涉及一种烃类合成催化剂在其未还原形式的包括）Fe作为催化活性金属，b）至碱金属和/或碱土金属超过碱金属 - 和/或含金属的碱土启动子，所述碱金属存在于以0.1至1.0克/ 100克Fe，c）和一个另外的启动子包括，或选自硼的选择，一个或多个元件（多个）由......组成，硅，锗，氮的量，磷，砷，锑，硫，硒和碲，元件（一个或多个）是存在于从零点03的量到0.2克/ 100克Fe和worin在其未还原形式的催化剂具有小于50的表面积这是在催化剂的本调查，并使用寻求在烃合成工艺的催化剂的操作，米2 /克，一种烃合成方法全部。

73. 发明授权

EP1708983B1 PROCESS FOR THE PREPARATION OF AN ALKOXYLATED ALCOHOL COMPOSITION 有权
标题翻译：一种用于生产烷氧基化醇成分
公开(公告)号：EP1708983B1
公开(公告)日：2010-05-26
申请号：EP04804761.7
申请日：2004-12-10
申请人： Shell Internationale Research Maatschappij B.V.
发明人： DIRKZWAGER, Hendrik , FENOUIL, Laurent Alain , WIERSMA, Rendert Jan
IPC分类号： C07C41/00 , C07C43/00 , C10G2/00 , C10G29/22
CPC分类号： C10G29/22 , C07C41/03 , C10G2/32 , C10G2/332 , C07C43/11
摘要： Process for the preparation of an alkoxylated alcohol composition comprising one or more alkoxylated alcohols wherein the process comprises the steps of: (a) reacting carbon monoxide with hydrogen under Fischer-Tropsch reaction conditions in the. presence of a Fischer-Tropsch catalyst; (b) separating from the product of step (a) at least one hydrocarbon fraction comprising paraffins having from 9 to 17 carbon atoms, the hydrocarbon fraction additionally comprising at least one portion of alcohols; (c) contacting one or more of the hydrocarbon fractions obtained in step (b) with an alkylene oxide; and (d) recovering an alkoxylated alcohol composition from the reaction product of step (c).

74. 发明公开

EP2004581A4 CATALYSTS AND METHODS FOR SYNTHESIZING ALIPHATIC HYDROCARBONS FROM CO AND H2 审中-公开
标题翻译：催化剂和方法合成脂肪烃CO和H2
公开(公告)号：EP2004581A4
公开(公告)日：2010-03-10
申请号：EP07760458
申请日：2007-04-11
申请人： WESCO
发明人： LVOVICH LAPIDUS ALBERT , SERGEEVICH BUDTSOV VLADIMIR
IPC分类号： C07C27/00 , B01J21/00 , B01J23/75 , B01J29/06 , B01J37/02 , C10G2/00
CPC分类号： B01J29/072 , B01J29/146 , B01J29/46 , B01J37/0205 , B01J37/18 , B01J2229/18 , B01J2229/40 , C10G2/332 , C10G2/334

75. 发明公开

EP2033943A1 Catalyst for methanation of carbon oxides, preparation method of the catalyst and process for the methanation 有权转让
标题翻译：一种催化剂对碳氧化物的甲烷化，处理用于催化剂和Methanierungsverfahren的制备
公开(公告)号：EP2033943A1
公开(公告)日：2009-03-11
申请号：EP08161695.5
申请日：2008-08-04
申请人： Daiki Ataka Engineering Co., Ltd. , Hashimoto, Koji
发明人： Hashimoto, Koji Daiki Ataka Engineering Co., Ltd. , Takano, Hiroyuki Daiki Ataka Engineering Co., Ltd. , Izumiya, Kouichi Daiki Ataka Engineering Co., Ltd. , Kumagai, Naokazu Daiki Ataka Engineering Co., Ltd. , Kato, Zenta , Shinomiya, Hiroyuki
IPC分类号： C07C1/04 , C07C1/02 , B01J37/00 , B01J23/74 , B01J21/00
CPC分类号： C07C1/12 , B01J23/002 , B01J23/78 , B01J23/83 , B01J37/0236 , B01J37/04 , B01J37/08 , B01J2523/00 , C07C1/0435 , C07C1/044 , C07C2521/06 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2523/78 , C07C2523/83 , C10G2/332 , C10L3/08 , Y02P20/52 , C07C9/04 , B01J2523/23 , B01J2523/3706 , B01J2523/3737 , B01J2523/48 , B01J2523/847 , B01J2523/842 , B01J2523/3718 , B01J2523/845 , B01J2523/3762 , B01J2523/3725 , B01J2523/36 , B01J2523/22 , B01J2523/3712 , B01J2523/375
摘要： Disclosed is a catalyst for methanation reaction producing methane with high conversion by reaction of hydrogen with carbon dioxide, or a gas mixture of carbon dioxide and carbon monoxide, or a gas mixture containing these compounds as the main components. The catalyst is prepared by the steps of mixing (A) aqueous zirconia sol with salts of (B) stabilizing element(s), which is selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Gd, Dy, Ca and Mg, and (C) iron group element(s), drying and calcining the mixture to obtain a catalyst precursor, and subsequent reduction of the precursor. The catalyst comprises, by atomic %, A: 18-17%, B: 1-20% and C: 25-80% based on the elemental states of the metals. The catalyst is characterized by multiple oxide of tetragonal zirconia structure, in which not only the stabilizing element (s) but also a part of the iron group element(s) is incorporated, and on which the iron group element(s) in the metallic state is supported.
摘要翻译：公开了一种用于甲烷化反应产生甲烷通过与二氧化碳或二氧化碳和一氧化碳，或气体混合物含有合成化合物作为主要成分的气体混合物的氢反应高转化率的催化剂。该催化剂是通过混合（A）wässrige氧化锆溶胶与（B）稳定化元素（一个或多个）中，盐的步骤制备所有这一切都被选自Y，镧，铈，镨，钕，钐，钆，镝的选择，Ca和Mg，以及（C）铁族元素（一个或多个），干燥并煅烧该混合物以获得催化剂前体，和随后的还原前体。所述催化剂包括，由原子％，A：18-17％，B：1-20％和C：25-80％，基于金属的元素状态。该催化剂是由四方晶氧化锆结构的复合氧化物为特征的，其中不仅稳定元件（一个或多个），所以，但铁族元素（一个或多个）的一部分中，并且其中在金属铁族元素（一个或多个）上支持状态。

76. 发明公开

EP2004581A2 CATALYSTS AND METHODS FOR SYNTHESIZING ALIPHATIC HYDROCARBONS FROM CO AND H2 审中-公开
标题翻译：催化剂和方法合成脂肪烃CO和H2
公开(公告)号：EP2004581A2
公开(公告)日：2008-12-24
申请号：EP07760458.5
申请日：2007-04-11
申请人： Wesco
发明人： LVOVICH, Lapidus, Albert , SERGEEVICH, Budtsov, Vladimir
IPC分类号： C07C27/00 , B01J29/06 , B01J21/00
CPC分类号： B01J29/072 , B01J29/146 , B01J29/46 , B01J37/0205 , B01J37/18 , B01J2229/18 , B01J2229/40 , C10G2/332 , C10G2/334
摘要： There is disclosed in embodiments catalysts produced by a two-stage loading of a zeolite carrier with an aqueous solution of a cobalt compound, with drying in an air current after each loading. Methods using the catalysts to produce synfuel are disclosed.

77. 发明公开

EP1963460A1 METHOD TO START A PROCESS FOR PRODUCING HYDROCARBONS FROM SYNTHESIS GAS 审中-公开
标题翻译：启动方法一种生产合成气的烃
公开(公告)号：EP1963460A1
公开(公告)日：2008-09-03
申请号：EP06830397.3
申请日：2006-12-06
申请人： Shell Internationale Research Maatschappij B.V.
发明人： HOEK, Arend , KUEH, Lip Piang
IPC分类号： C10G2/00 , C07C1/04
CPC分类号： C10G2/32 , C10G2/332 , C10G2300/1022 , C10G2300/301
摘要： The present invention provides a method to start a steady state process for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons from synthesis gas, which method comprises the steps of: (i) providing an activated catalyst in tubes of a fixed bed reactor, preferably a multitubular fixed bed reactor, the catalyst being suitable to convert synthesis gas to normally gaseous, normally liquid and optionally normally solid hydrocarbons; (ii) contacting the activated catalyst with a liquid to obtain a wetted activated catalyst; (iii) contacting the wetted activated catalyst with synthesis gas and catalytically converting the synthesis gas at an elevated temperature and pressure to obtain the normally gaseous, normally liquid and optionally normally solid hydrocarbons.

78. 发明公开

EP1963010A1 METAL NITRATE CONVERSION METHOD 有权
标题翻译：用于金属硝酸盐的转化
公开(公告)号：EP1963010A1
公开(公告)日：2008-09-03
申请号：EP06808566.1
申请日：2006-11-17
申请人： Johnson Matthey Public Limited Company
发明人： SIETSMA, Jelle, Rudolf, Anne , VAN DILLEN, Adrianus, Jacobus , DE JONGH, Petra, Elisabeth , DE JONG, Krijn, Pieter
IPC分类号： B01J23/70 , B01J37/08 , B01J37/12 , C01G1/02 , C01G3/02 , C01G3/08 , C01G49/02 , C01G51/04 , C01G53/04 , C07C1/04
CPC分类号： C01G1/02 , B01J21/04 , B01J21/08 , B01J23/70 , B01J23/75 , B01J23/755 , B01J29/0333 , B01J35/006 , B01J35/0066 , B01J37/088 , B01J37/12 , B01J37/16 , B82Y30/00 , C01B13/18 , C01G3/02 , C01G3/08 , C01G49/02 , C01G51/04 , C01G53/04 , C01P2002/72 , C01P2004/04 , C01P2004/64 , C01P2006/12 , C01P2006/14 , C10G2/332 , C10G2/333 , C10G2/334 , C10G3/45 , C10G3/46 , C10G45/48 , C11C3/123 , Y02P30/20
摘要： A method is described for converting a supported metal nitrate into the corresponding supported metal oxide comprising heating the metal nitrate to effect its decomposition under a gas mixture that contains nitric oxide and has an oxygen content of

79. 发明公开

EP1941004A1 FISCHER TROPSCH PROCESS 有权
标题翻译： FISCHER TROPSCH过程
公开(公告)号：EP1941004A1
公开(公告)日：2008-07-09
申请号：EP06794839.8
申请日：2006-10-20
申请人： BP EXPLORATION OPERATING COMPANY LIMITED , Davy Process Technology Limited
发明人： CLARKSON, Jay, Simon , GAMLIN, Timothy, Douglas , HARDY, Lawerence, Trevor
IPC分类号： C10G2/00 , B01J23/80 , B01J37/03
CPC分类号： B01J23/80 , C10G2/332 , C10G2300/703
摘要： The present invention relates to a process for converting synthesis gas to hydrocarbons, in particular to hydrocarbons in the C5-C60 range particularly suitable for use as liquid motor fuels, in a slurry reactor in the presence of a Fischer-Tropsch catalyst comprising cobalt and zinc oxide wherein the Fischer-Tropsch catalyst is activated with a reducing gas consisting of hyrogen and an inert gas at 330 to 400 °C prior to contact with synthesis gas in the slurry reactor.
摘要翻译：本发明涉及一种在含有钴和锌的费 - 托催化剂存在下在淤浆反应器中将合成气转化为烃的方法，特别是将C5-C60范围的烃特别适合用作液体发动机燃料的方法其中费 - 托催化剂在与淤浆反应器中的合成气接触之前在330-400℃下用由氢气和惰性气体组成的还原气体活化。

80. 发明公开

EP1935845A1 Process for producing hydrocarbons from a hydrocarbonaceous feedstock 审中-公开
标题翻译：一种用于从烃原料制备烃类的方法
公开(公告)号：EP1935845A1
公开(公告)日：2008-06-25
申请号：EP06127010.4
申请日：2006-12-22
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
发明人： Rigby, Anthony Malcolm
IPC分类号： C01B3/12 , C10G2/00
CPC分类号： C10G2/332 , C01B3/12 , C01B3/36 , C01B2203/0255 , C01B2203/0283 , C01B2203/062 , C10G2/32 , Y02P20/145
摘要： A process for producing hydrocarbons from a hydrocarbonaceous feedstock comprising the following steps:
(a) partially oxidising the hydrocarbonaceous feedstock to obtain synthesis gas;
(b) supplying the synthesis gas to a hydrocarbon synthesis reactor wherein the synthesis gas is catalytically converted at elevated temperature and pressure into hydrocarbons;
(c) discharging a liquid hydrocarbon product stream and a gaseous stream comprising gaseous hydrocarbon products, water vapour and unconverted synthesis gas from the hydrocarbon synthesis reactor;
(d) subjecting at least part of the gaseous stream to a catalytic water-gas shift conversion to obtain a shifted gaseous stream; and
(e) supplying at least part of the shifted gaseous stream to a hydrocarbon synthesis reactor wherein the synthesis gas is catalytically converted at elevated temperature and pressure into hydrocarbons.
摘要翻译：一种用于从烃原料生产烃，包括以下步骤的过程：（a）中部分氧化的烃类原料，得到的合成气; （b）提供合成气到烃类合成反应器worin将合成气在升高的温度和压力下为烃催化转化; （C）排出液体烃产物流和气态物流包含气态烃类产品从碳氢化合物合成反应器的水蒸汽和未转化的合成气; （D）对所述气流进行催化的水煤气变换转换以获得一个偏移气态流的至少一部分; 和（e）供给的气体流的至少一部分偏移到碳氢化合物合成反应器worin合成气被催化在升高的温度和压力下为烃转化。

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