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    • 74. 发明公开
    • DENTAL ADHESIVE
    • 牙科用粘合剂
    • EP3156033A1
    • 2017-04-19
    • EP15807534.1
    • 2015-06-10
    • Kuraray Noritake Dental Inc.
    • NOJIRI, YamatoTAKEI, Mitsuru
    • A61K6/00A61K6/083
    • The present invention provides a dental adhesive exhibiting excellent initial bond strength and bond durability to both enamel and dentin. The present invention relates to a dental adhesive containing: an asymmetric acrylamide-methacrylic acid ester compound (a); an acid group-containing (meth)acrylic polymerizable monomer (b); and a water-soluble polymerizable monomer (c). The asymmetric acrylamide-methacrylic acid ester compound (a) is represented by the following general formula (1):

      , where X is an optionally substituted, linear or branched C 1 to C 6 aliphatic group or an optionally substituted aromatic group, the aliphatic group is optionally interrupted by at least one linking group selected from the group consisting of -O--S-, -CO-, -CO-O-, -O-CO-, -NR 1 - , -CO-NR 1 -, -NR 1 -CO-, -CO-O-NR 1 -, -O-CO-NR 1 -, and -NR 1 -CO-NR 1 -, and R 1 is a hydrogen atom or an optionally substituted, linear or branched C 1 to C 6 aliphatic group.
    • 本发明提供了对牙釉质和牙质都表现出优异的初始粘合强度和粘合耐久性的牙科粘合剂。 本发明涉及含有不对称丙烯酰胺 - 甲基丙烯酸酯化合物(a)的牙科用粘合剂, (b)含酸性基团的(甲基)丙烯酸系可聚合单体; 和水溶性可聚合单体(c)。 不对称丙烯酰胺 - 甲基丙烯酸酯化合物(a)由以下通式(1)表示:其中X是任选取代的,直链或支链的C1-C6脂族基团或任选取代的芳族基团,所述脂族基团任选 被至少一个选自-O - , - S - , - CO - , - CO-O - , - O-CO - , - NR 1 - , - CO-NR 1 - , - NR 1 -CO - , - CO-O-NR1 - , - O-CO-NR1-和-NR1-CO-NR1-,并且R1为氢原子或任选取代的直链或支链C1至C6脂族基团。
    • 77. 发明公开
    • DENTAL COLOR TONE ADJUSTMENT MATERIAL KIT
    • MATERIALSATZFÜRZAHNÄRZTLICHEFARBTONEINSTELLUNG
    • EP3064194A1
    • 2016-09-07
    • EP14857644.0
    • 2014-10-28
    • Kuraray Noritake Dental Inc.
    • KITA, HirotakaTERAKAWA, EiichiOSHITA, Mizuko
    • A61K6/083A61K6/04
    • A61K6/0017A61C5/70A61C5/77A61C13/0004A61K6/0002A61K6/0029A61K6/0052A61K6/0055A61K6/0094A61K6/0235A61K6/083C08L33/08C08L33/10
    • The present invention provides a dental color tone adjustment material kit that has improved properties in terms of surface drying and of discoloration after curing and that enables adjustment to a desired color tone. The present invention relates to a dental color tone adjustment material kit including: a primer composition (A) including an acid group-containing polymerizable monomer (a) and a volatile organic solvent (b); and a dental color tone adjustment material B including a polymerizable monomer (d), a polymerization initiator (e), particle aggregates (f) that are chain aggregates of ultrafine filler particles having an average primary particle diameter of 1 to 50 nm, titanium dioxide (g), and a pigment (h). The monomer (a) accounts for 0.05 to 45 weight% of the primer composition (A), and the organic solvent (b) accounts for 55 to 99.95 weight% of the primer composition (A). The monomer (d) includes a polyfunctional acrylate monomer (d1) and a volatile monofunctional (meth)acrylate monomer (d2), and the monomers (d1) and (d2) account for 88 weight% or more of the monomer (d). The content of the particle aggregates (f) is 5 to 20 parts by weight, and the content of the titanium dioxide (g) is 0.05 to 2 parts by weight, per 100 parts by weight of the total of the monomer (d) and the particle aggregates (f).
    • 本发明提供了一种牙科色调调节材料试剂盒,其在表面干燥和固化后的变色方面具有改进的性能,并且能够调节所需的色调。 本发明涉及一种牙科色调调节材料试剂盒,其包括:含有酸基的可聚合单体(a)和挥发性有机溶剂(b)的底漆组合物(A) 和包含作为平均一次粒径为1〜50nm的超细填料粒子的链状聚集体的聚合性单体(d),聚合引发剂(e),粒子聚集体(f))的牙科色调调整材料B,二氧化钛 (g)和颜料(h)。 单体(a)占底漆组合物(A)的0.05〜45重量%,有机溶剂(b)占底漆组合物(A)的55〜99.95重量%。 单体(d)包括多官能丙烯酸酯单体(d1)和挥发性单官能(甲基)丙烯酸酯单体(d2),单体(d1)和(d2)占单体(d)的88重量%以上。 粒子聚集体(f)的含量为5〜20重量份,二氧化钛(g)的含量相对于单体(d)和(d)的总量为100重量份为0.05〜2重量份, 颗粒聚集体(f)。
    • 79. 发明公开
    • DENTAL CURABLE COMPOSITION AND DENTAL FLOWABLE COMPOSITE RESIN
    • 佛罗里达州牙买加血统
    • EP2926796A4
    • 2016-08-03
    • EP13857989
    • 2013-11-26
    • KURARAY NORITAKE DENTAL INC
    • KAMEYA TAKEHIROISHINO HIROSHIGETSUJI AKIKO
    • A61K6/083A61K6/00A61K6/027
    • A61K6/083A61C5/50A61C19/02A61K6/0005A61K6/0008A61K6/0017A61K6/0073A61K6/027A61K6/0276C08L33/10
    • The present invention provides a dental curable composition suitable as a flowable composite resin. The dental curable composition, when in the form of a cured product, has excellent mechanical strength, polishability, and gloss retention, and, when in the form of a paste, has consistency appropriate for discharge through a needle attached to the tip of a syringe and exhibits good formability and handling properties after discharge through the needle. The present invention is a dental curable composition including: a polymerizable monomer (A); irregularly-shaped inorganic particles (B) having an average particle diameter of 0.1 to 0.3 µm and surface-treated with a silane coupling agent having a particular structure; and inorganic ultrafine particles (C) having an average particle diameter of 5 to 50 nm and surface-treated with a silane coupling agent having a particular structure, the dental curable composition containing 92.5 to 98 weight% of the irregularly-shaped inorganic particles (B) and 2 to 7.5 weight% of the inorganic ultrafine particles (C) relative to the amount of total inorganic particles and having a consistency of 25 to 55.
    • 本发明提供适合作为可流动复合树脂的牙科用固化性组合物。 当固化产物形式为固化产物时,该牙科用可固化组合物具有优异的机械强度,抛光性和光泽保持性,并且当以糊状形式时,具有适合于通过连接到注射器尖端的针排出的稠度 并且在通过针排出后表现出良好的成形性和操作性能。 本发明是一种牙科用固化性组合物,其含有:聚合性单体(A) 不规则形状的平均粒径为0.1〜0.3μm的无机粒子(B),并用具有特定结构的硅烷偶联剂进行表面处理; 和平均粒径为5〜50nm的无机超细粒子(C),并用具有特定结构的硅烷偶联剂进行表面处理,所述牙科用固化性组合物含有92.5〜98重量%的不规则形状的无机粒子(B )和2〜7.5重量%的无机超细颗粒(C)相对于总无机颗粒的量并且具有25至55的稠度。