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61. 发明授权

EP2456776B1 COMPLEXES ORGANOMETALLIQUES ACTIFS DERIVES DE SÉLÉNOQUINONE, LEURS PROCEDES DE SYNTHESE ET UTILISATIONS 有权
标题翻译：硒CHINON-而得的有机金属配合物，合成方法及其用途
公开(公告)号：EP2456776B1
公开(公告)日：2016-01-27
申请号：EP10752081.9
申请日：2010-07-22
申请人： Centre National de la Recherche Scientifique (CNRS)
发明人： AMOURI, Hani, Haniel
IPC分类号： C07F17/00 , A61P35/00
CPC分类号： C07F17/02

62. 发明授权

EP2816051B1 Catalyst for olefin polymerization, method for its preparation and use thereof 失效
标题翻译：烯烃聚合催化剂，其制备方法和其使用过程
公开(公告)号：EP2816051B1
公开(公告)日：2015-11-04
申请号：EP13172833.9
申请日：2013-06-19
申请人： SCG Chemicals Co., Ltd.
发明人： Khamnaen, Tossapol , Charoenchaidet, Sumate
IPC分类号： C07F17/00 , C07F7/28 , C08F10/02 , C08F4/65
CPC分类号： C08F4/6592 , C07F7/28 , C07F17/00 , C08F4/65912 , C08F4/76 , C08F10/02 , C08F2420/04 , C08F210/16 , C08F210/14

63. 发明公开

EP2935295A1 CATALYST 有权
标题翻译：催化剂
公开(公告)号：EP2935295A1
公开(公告)日：2015-10-28
申请号：EP13811217.2
申请日：2013-12-19
申请人： Borealis AG
发明人： CASTRO, Pascal , VIRKKUNEN, Ville , IZMER, Vyatcheslav , KONONOVICH, Dmitry , VOSKOBOYNIKOV, Alexander , RESCONI, Luigi
IPC分类号： C07F17/00 , C07F7/08 , C08F10/06 , C08F4/6592 , C08F4/02
CPC分类号： C07C1/326 , C07C1/20 , C07C41/30 , C07C2531/04 , C07C2531/18 , C07C2531/24 , C07C2602/24 , C07F7/0818 , C07F17/00 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F10/06 , C08F110/06 , C08F4/02 , C08F2500/03 , C08F2500/12 , C08F2500/15 , C07C13/465 , C07C43/188
摘要： A catalyst in solid particulate form free from an external carrier material comprising (I) a complex of formula (I) wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from —R′2C—, —R′2C—CR′2—, —R′2Si—, —R′2Si—SiR′2—, —R′2Ge—, wherein each R′ is independently a hydrogen atom, C1-C20-alkyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R2 is independently hydrogen or a C1-C20 hydrocarbyl radical provided that at least one R2 is not hydrogen; each R5 is independently hydrogen or a C1-20 hydrocarbyl group optionally containing one or more heteroatoms from groups 14-16; each R6 is independently hydrogen or a C1-20 hydrocarbyl group optionally containing one or more heteroatoms from groups 14-16; each n is independently 1, 2 or 3; and each R8 is a C1-20 hydrocarbyl group; and (ii) a cocatalyst comprising a compound of a group 13 metal, e.g. Al or boron.
摘要翻译：不含外部载体材料的固体颗粒形式的催化剂，其包含式（I）的络合物，其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R'是独立地为氢原子，C 1 -C 20烷基，三（C 1 -C 20烷基）甲硅烷基，C 6 -C 20芳基，C 7 -C 20芳烷基或C 7 -C 20烷芳基; 每个R 2独立地为氢或C 1 -C 20烃基，条件是至少一个R 2不是氢; 每个R 5独立地为氢或任选含有一个或多个来自第14-16族的杂原子的C 1-20烃基; 每个R 6独立地为氢或任选含有一个或多个来自第14-16族的杂原子的C 1-20烃基; 每个n独立地是1,2或3; 每个R 8为C 1-20烃基，和（ii）包含13族金属化合物如甲基丙烯酸甲酯的助催化剂。铝或硼。

64. 发明公开

EP2902420A1 Metal complex with a cyclic amidine ligand 有权转让
标题翻译： Metallkomplex mit einem zyklischen Amidinliganden
公开(公告)号：EP2902420A1
公开(公告)日：2015-08-05
申请号：EP14153077.4
申请日：2014-01-29
申请人： Lanxess Elastomers B.V.
发明人： Dr. van Doremaele,Gerard , Dr. Berthoud, Alexandra , Dr. Quiroga Norambuena, Victor , Dr. Rupnicki, Leszek , Dr. Karbaum, Peter
IPC分类号： C08F10/00 , C08F4/6592 , C07F17/00
CPC分类号： C08F4/6592 , C07F7/28 , C08F4/65912 , C08F210/16 , C08F210/18 , C08F2420/04 , C08F10/00 , C08F210/06 , C08F2500/17 , C08F236/20 , C08F2500/25
摘要： The present invention relates to a A metal complex of formula 1

CyYML j X n (formula 1)

wherein
Cy is a cyclopentadienyl-type ligand;
M is a metal of group 4;
L is a neutral Lewis basic ligand wherein the number of said neutral ligands "j" is in the range of 0 to the amount that satisfies the 18-electron rule;

X is an anionic ligand; n is an integer denoting the number of anionic ligands X and is 1 or 2, preferably is 2;
Y is a cyclic amidine-containing ligand moiety represented by formula 2

wherein the amidine-containing ligand is covalently bonded to the metal M via the imine nitrogen atom N 2 ;
S is a -CH 2 - unit, and t is the integer number denoting the number of S and is in the range of 1-4, more preferably in the range of 1-2, most preferably is 1;
Sub 1 is an aliphatic cyclic or linear substituent comprising a group 14 atom through which Sub 1 is bonded to the amine nitrogen atom N 1 ;
Sub2 is an optionally substituted C2 unit in which the 2 carbon atoms may be SP 2 or sp 3 hybridized.
摘要翻译：本发明涉及一种式1的A金属络合物，其中Cy是环戊二烯基（式1）其中Cy是环戊二烯基型配体; M是第4组的金属; L是中性的路易斯碱性配体，其中所述中性配体“j”的数目在0至满足18电子规则的量的范围内; X是阴离子配体; n是表示阴离子配体X的数的整数，为1或2，优选为2; Y是由式2表示的含环状脒的配体部分，其中含脒配体通过亚胺氮原子N 2与金属M共价结合; S是-CH 2单元，t是表示S数的整数，在1-4的范围内，更优选在1-2的范围内，最优选为1; Sub 1是包含Sub 1键合到胺氮原子N 1上的14族原子的脂族环状或线性取代基; Sub2是任选取代的C2单元，其中2个碳原子可以是SP 2或sp 3杂交的。

65. 发明公开

EP2897726A1 PRODUCTION OF VINYL TERMINATED POLYETHYLENE 审中-公开
标题翻译：聚乙烯的生产乙烯基封端
公开(公告)号：EP2897726A1
公开(公告)日：2015-07-29
申请号：EP13839180.0
申请日：2013-09-23
申请人： ExxonMobil Chemical Patents Inc.
发明人： CROWTHER, Donna, J. , BRANT, Patrick , HAGADORN, John, R. , LOVELL, Jacqueline, A.
IPC分类号： B01J31/28 , C07F17/00 , C08F10/02
CPC分类号： C08F110/02 , C08F4/65908 , C08F4/65912 , C08F4/65927 , C08F10/02 , C10L1/1641 , C10M2205/022 , Y02P20/52 , C08F2500/03 , C08F2500/09 , C08F2500/20
摘要： This invention relates to processes to produce polyethylene involving contacting ethylene with a metallocene catalyst system; wherein the catalyst system comprises: a stoichiometric activator; and a metallocene compound. The metallocene catalyst system is also disclosed.

66. 发明授权

EP2017280B1 METALLOCENE COMPLEX AND POLYMERIZATION CATALYST COMPOSITION CONTAINING THE SAME 有权转让
标题翻译：含有该化合物的金属茂络合物和聚合催化剂组合物
公开(公告)号：EP2017280B1
公开(公告)日：2015-01-07
申请号：EP07742824.1
申请日：2007-05-02
申请人： Riken , Bridgestone Corporation , JSR Corporation
发明人： KAITA, Shojiro , TARDIF, Olivier
IPC分类号： C07F19/00 , C07F7/10 , C07F17/00 , C08F10/00 , C08F12/00 , C08F36/00 , C07F5/00
CPC分类号： C07F17/00 , C08F10/00 , C08F36/04 , C08F112/08 , C08F212/08 , C08F4/52 , C08F4/54 , C08F236/06 , C08F4/545

67. 发明授权

EP2609102B1 MOLYBDENUM (IV) AMIDE PRECURSORS AND USE THEREOF IN ATOMIC LAYER DEPOSITION 失效转让
标题翻译：钼（IV）-AMIDVORLÄUFER及其USE IN核位置分离
公开(公告)号：EP2609102B1
公开(公告)日：2014-12-31
申请号：EP11752057.7
申请日：2011-08-25
申请人： Sigma-Aldrich Co. LLC
发明人： HEYS, Peter, Nicholas , ODEDRA, Rajesh , HINDLEY, Sarah, Louise
IPC分类号： C07F11/00 , C07F17/00 , C23C16/40 , C23C16/455 , B05D1/00
CPC分类号： B05D1/60 , C07F11/00 , C07F17/00 , C23C16/405 , C23C16/45525
摘要： Molybdenum (IV) amide complexes are disclosed herein corresponding in structure to Formula (I): wherein: L is -NR1R2; R1 and R2 are C1-C6-alkyl or hydrogen; R is C1-C6-alkyl; and n is zero, 1, 2 or 3. Further, methods of forming MoO2 films by atomic layer deposition (ALD) using Formula (I) complexes and Mo[N(Me)(Et)]4 are disclosed herein.

68. 发明公开

EP2718303A4 NEW CYCLOPENTA[B]FLUORENYL TRANSITION METAL COMPOUND, CATALYST COMPOSITION CONTAINING THE SAME, AND METHOD OF PREPARING ETHYLENE HOMOPOLYMER OR COPOLYMER OF ETHYLENE AND alpha-OLEFIN USING THE SAME 有权转让
标题翻译： NEW环戊二烯并[b]芴基过渡金属化合物，催化剂组合物和合适的工艺生产乙烯均聚物或乙烯共聚物和α-烯烃SO
公开(公告)号：EP2718303A4
公开(公告)日：2014-12-24
申请号：EP12796849
申请日：2012-06-08
申请人： SK INNOVATION CO LTD , SK GLOBAL CHEMICAL CO LTD
发明人： SHIN DONG CHEOL , LEE HO SEONG , KIM SEONG KYUN , LEE SANG ICK , KIM SUN YOUNG , HAHN JONG SOK , JEON CHAN WOONG , KIM JEONG HWAN
IPC分类号： C07F17/00 , C08F4/6592 , C08F10/02 , C08F210/16
CPC分类号： C08F210/16 , C07F7/0816 , C07F7/28 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/76 , C08F210/02 , C08F210/06 , C08F210/18 , C08F2420/02 , Y10S526/943 , C08F210/14 , C08F2500/12 , C08F210/08 , C08F236/20 , C08F2500/17 , C08F2500/25
摘要： The present invention relates to a method of preparing an ethylene-α-olefin-diene copolymer and an ethylene-α-olefin-diene copolymer prepared thereby, by using a transition metal compound based on a cyclopenta[b]fluorenyl group as a catalyst.

69. 发明公开

EP2800754A1 PROCESS FOR THE PREPARATION OF METALLOCENE COMPLEXES 失效
标题翻译： VERFAHREN ZUR HERSTELLUNG VON METALLOCENKOMPLEXEN
公开(公告)号：EP2800754A1
公开(公告)日：2014-11-12
申请号：EP12805598.5
申请日：2012-12-13
申请人： SAUDI BASIC INDUSTRIES CORPORATION (SABIC)
发明人： AL-HUMYDY, Abdulaziz Hamad , ABURAQABAH, Atieh , GÖRL, Christian , ALT, Helmut
IPC分类号： C07F17/00 , C07C1/32 , C08F10/00
CPC分类号： C07F7/00 , C07C1/321 , C07C2102/08 , C07C2602/08 , C07F17/00 , C08F4/65912 , C08F110/02 , C07C13/465 , C08F4/65927
摘要： The invention relates to a process comprising the step of reacting a 2-indenylpinacolyl borane compound with a bromosubstituted compound in the presence of a Pd catalyst and a base to form the corresponding bridged bis(indenyl) ligand. This process step is very efficient and leads to less (homocoupled) byproducts than other known processes. The process of the invention may further comprise the step of reacting a 2-bromo indene compound with pinacolborane in the presence of a Pd catalyst and a base, to form the corresponding 2-indenylpinacolylborane compound. With this, the invention provides an improved and easy two-step process to prepared bridged bis(indenyl)ligands. These bridged bis(indenyl)ligands may suitably be used in the preparation of metallocene complexes, such as 2,2'-bis(2-indenyl)biphenyl ZrCI
2 and 1,2-bis(2-indenyl)benzene ZrCI
2 . These metallocene complexes may be used for the polymerization, optionally in the presence of a cocatalyst, of one or more a-olefins, preferably for the polymerization of ethylene. In a preferred embodiment, the Pd catalyst is preferably is(triphenylphosphin)palladium dichloride (PPh
3 )
2 PdCI
2 ).
摘要翻译：制备桥联双（茚基）配体的方法，包括在Pd催化剂和碱的存在下使2-茚基茚基甲硅烷基化合物与溴取代的化合物反应以形成相应的桥连双（茚基）配体的步骤。该方法还可以包括在Pd催化剂和碱的存在下使2-溴茚化合物与频哪醇硼烷反应以形成相应的2-茚基茚基苯基硼烷化合物的步骤。这些桥连的双（茚基）配体可适当地用于制备茂金属络合物，例如2,2'-双（2-茚基）联苯基ZrCl 2和1,2-双（2-茚基）苯ZrCl 2。这些茂金属络合物可以用于聚合，任选地在助催化剂存在下，一种或多种α-烯烃，优选用于聚合乙烯。

70. 发明公开

EP2800753A1 PROCESS FOR THE PREPARATION OF METALLOCENE COMPLEXES 有权
标题翻译：制备金属茂配合物的方法
公开(公告)号：EP2800753A1
公开(公告)日：2014-11-12
申请号：EP12805597.7
申请日：2012-12-13
申请人： SAUDI BASIC INDUSTRIES CORPORATION (SABIC)
发明人： AL-HUMYDI, Abdulaziz Hamad , ABURAQABAH, Atieh , GÖRL, Christian , ALT, Helmut
IPC分类号： C07F17/00 , C08F10/00
CPC分类号： C08F4/76 , C07C1/321 , C07C2/66 , C07C13/32 , C07C13/36 , C07C13/38 , C07F17/00 , C08F4/65927 , C08F110/02 , C08F4/65912
摘要： A process comprising reacting a 2-indenylboranic acid (ester) with a bromosubstituted compound in the presence of the Pd catalyst bis(triphenylphosphin)palladium dichloride and a base to form the corresponding bridged bis(indenyl) ligand. Where the 2-indenylboranic acid (ester) is the pinacolester of 2-indenylboranic acid, the process may further comprise reacting a 2-bromo indene compound with pinacolborane in the presence of a Pd catalyst and a base to form the corresponding 2-indenylpinacolylborane compound. Bridged bis(indenyl)ligands may suitably be used in the preparation of metallocene complexes, such as 2,2′-bis(2-indenyl)biphenyl ZrCl2 and 1,2-bis (2-indenyl)benzene ZrCl2. These metallocene complexes may be used for the polymerization, optionally in the presence of a cocatalyst, of one or more α-olefins, preferably for the polymerization of ethylene.
摘要翻译：本发明涉及包括以下步骤的方法：（a）在Pd催化剂双（三苯基膦）二氯化钯（PPh 3）2 PdCl 2）和碱的存在下，使2-茚基硼酸（酯）与溴取代的化合物反应，形成相应的桥联双（茚基）配体。在2-茚基硼酸（酯）是2-茚基硼酸的频哪醇酯的情况下，本发明的方法可以进一步包括使2-溴茚化合物与频哪醇硼烷在Pd催化剂和碱存在下反应的步骤，以形成相应的2-茚基频哪基硼烷化合物。由此，本发明提供了制备桥联双（茚基）配体的改进且简单的两步法，当使用Pd催化剂双（三苯基膦）二氯化钯（PPh 3）2 PdCl 2时，其在商业上非常有吸引力。桥连双（茚基）配体可适用于制备茂金属络合物，例如2,2'-双（2-茚基）联苯ZrCl 2和1,2-双（2-茚基）苯ZrCl 2。这些茂金属络合物可用于任选在助催化剂存在下聚合一种或多种α-烯烃，优选用于乙烯聚合。

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