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61. 发明公开

EP2403815A1 OXIDATIVE HOMO-COUPLING REACTIONS OF ARYL BORONIC ACIDS USING A POROUS COPPER METAL-ORGANIC FRAMEWORK AS A HIGHLY EFFICIENT HETEROGENEOUS CATALYST 审中-公开
标题翻译：多孔铜基金属化结构异构的高性能催化剂的芳基硼酸基础氧化HOMO离合器的反应
公开(公告)号：EP2403815A1
公开(公告)日：2012-01-11
申请号：EP10736949.8
申请日：2010-07-27
申请人： The Regents of The University of California , BASF SE
发明人： YAGHI, Omar, M. , CZAJA, Alexander, U. , WANG, Bo , LU, Zheng
IPC分类号： C07C1/32 , C07C15/14 , C07C17/269 , C07C205/06 , C07C209/68 , C07C253/30
CPC分类号： C07C201/12 , C07C1/321 , C07C17/263 , C07C209/68 , C07C253/30 , C07C2523/72 , C07C2531/28 , C07C15/14 , C07C25/18 , C07C211/50 , C07C255/51 , C07C205/06
摘要： The disclosure provides methods for the use of open metal frameworks to synthesize biaryls comprising contacting a metal organic framework (MOF) or metal organic polyhedral (MOP) with an aryl boronic acid compound under conditions wherein the MOF or MOP catalyze the synthesis of the biaryl through a homo-coupling reaction.

62. 发明公开

EP1720831A4 MANUFACTURE OF HIGHER HYDROCARBONS FROM METHANE, VIA METHANESULFONIC ACID, SULFENE, AND OTHER PATHWAYS 审中-公开
标题翻译：推动高等碳氢化合物甲烷在甲烷，亚磺酰和其它路径
公开(公告)号：EP1720831A4
公开(公告)日：2010-04-07
申请号：EP04810350
申请日：2004-11-05
申请人： RICHARDS ALAN K
发明人： RICHARDS ALAN K
IPC分类号： C07C315/00 , C07C1/00 , C07C1/32 , C07C2/86 , C07C4/02 , C07C5/31 , C07C29/09 , C07C319/00 , C07C381/00 , C10G3/00
CPC分类号： C07C2/868 , C07C1/322 , C07C29/09 , C07C381/00 , C07C2601/02 , C10G3/00 , C10G2400/20 , C10G2400/22 , Y02P30/20 , Y02P30/40 , C07C11/02 , C07C9/00 , C07C11/04 , C07C13/04 , C07C31/10

63. 发明公开

EP2168673A1 MICRO-PASSAGE CHIP 有权
标题翻译： MIKRODURCHGANGCHIP
公开(公告)号：EP2168673A1
公开(公告)日：2010-03-31
申请号：EP08777189.5
申请日：2008-06-13
申请人： HiPep Laboratories , Nippon Light Metal Company, Ltd.
发明人： NOKIHARA, Kiyoshi , OKA, Yasuo
IPC分类号： B01J19/00 , B81B1/00 , C07C1/32 , C07C15/12 , C07C17/26 , C07C22/08 , C07C25/22 , C07C41/30 , C07C43/225 , C40B60/02 , G01N37/00 , C12M1/00 , C12N15/09
CPC分类号： B01J19/0093 , B01J2219/00783 , B01J2219/00819 , B01J2219/00831 , B01J2219/0086 , B01J2219/00873 , B01L3/502707 , B01L2200/0689 , B01L2300/0883 , B01L2300/12 , B81B2201/051 , B81B2201/058 , B81B2203/0307 , B81C3/001 , B81C2203/0109 , B81C2203/032
摘要： Means for overcoming the problems which the conventional glass microchannel chips have are disclosed. That is, a microchannel chip in which microchannels can be formed at a low cost, and which has a high chemical resistance is disclosed. The microchannel chip is constituted by a substrate made of carbon, which has a channel in its surface; and a cover composed of a glass plate bonded to the substrate. The cover is bonded to the substrate by heating at least a part of the contact surface at which the substrate is in contact with the cover.
摘要翻译：揭示了传统玻璃微通道芯片所存在的问题的手段。也就是说，公开了以低成本形成微通道并且具有高耐化学性的微通道芯片。微通道芯片由碳表面构成，其表面具有通道; 以及由与基板结合的玻璃板构成的盖。通过加热基板与盖接触的接触表面的至少一部分，将盖结合到基板。

64. 发明授权

EP1115491B1 CATALYST COMPLEX WITH PHENYLINDENYLIDENE LIGAND 有权
标题翻译：具有苯基亚乙烯基配体的催化剂络合物
公开(公告)号：EP1115491B1
公开(公告)日：2009-08-05
申请号：EP99945604.9
申请日：1999-09-09
申请人： University Of New Orleans Foundation
发明人： NOLAN, Steven P. , HUANG, Jinkun
IPC分类号： B01J31/16 , B01J31/22 , B01J31/24 , C07F15/00 , B01J31/18 , C07B37/04 , C07B43/04 , C07B49/00 , C07C1/32
CPC分类号： B01J31/2278 , B01J31/2265 , B01J31/2273 , B01J31/2295 , B01J31/2404 , B01J2231/10 , B01J2231/4205 , B01J2231/54 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07C6/04 , C07C67/30 , C07C2531/22 , C07D207/46 , C07D223/04 , C07D225/02 , C07D313/00 , C07D498/04 , C07F15/00 , C07F15/002 , C07F15/0046
摘要： Catalytic complexes including a metal atom having anionic ligands, at least one nucleophilic carbene ligand, and an alkylidene, vinylidene, or allenylidene ligand. The complexes are highly stable to air, moisture and thermal degradation. The complexes are designed to efficiently carry out a variety of olefin metathesis reactions.
摘要翻译：包括具有阴离子配体的金属原子，至少一种亲核卡宾配体和亚烷基，亚乙烯基或亚烯基配体的催化配合物。该复合物对空气，湿气和热降解高度稳定。配合物被设计为有效地进行各种烯烃复分解反应。

65. 发明授权

EP1490312B1 GRIGNARD PREPARATION OF UNSATURATED ORGANIC COMPOUNDS 有权
标题翻译：格氏生产不饱和有机化合物
公开(公告)号：EP1490312B1
公开(公告)日：2009-02-18
申请号：EP03746083.9
申请日：2003-03-31
申请人： Dow Corning Corporation
发明人： NGUYEN, Binh, T. , BEDBURY, Curtis, J.
IPC分类号： C07C1/32
CPC分类号： C07C1/326 , C07C11/12
摘要： A Grignard-type process for the preparation of unsaturated organic compounds. The process comprises contacting an unsaturated organic halide with magnesium metal in a mixture of ether and a polar halogenated hydrocarbon co-solvent, filtering the reaction product from the reaction step and thereafter, treating the reaction product filtrate from the filtration step to obtain the desired unsaturated organic compounds.

66. 发明公开

EP1947074A4 METHOD OF RAPID METHYLATION OF ALKENE COMPOUND AND KIT FOR PET TRACER PREPARATION USING THE SAME 审中-公开
标题翻译：法快速甲基化PET示踪剂生产烯烃和KIT使用其
公开(公告)号：EP1947074A4
公开(公告)日：2008-12-03
申请号：EP06811431
申请日：2006-10-06
申请人： UNIV GIFU
发明人： SUZUKI MASAAKI , HOSOYA TAKAMITSU
IPC分类号： C07C1/32 , C07B59/00 , C07B61/00 , C07C11/02 , C07C11/12 , C07C13/20 , C07C15/02 , C07C29/32 , C07C33/03 , C07C45/68 , C07C47/21 , C07C49/603 , C07C67/343 , C07C69/587 , G01T1/161
CPC分类号： C07C45/673 , C07B59/00 , C07B2200/05 , C07C1/325 , C07C29/32 , C07C67/343 , C07C2531/24 , C07C47/21 , C07C49/603 , C07C69/587 , C07C33/03
摘要： [PROBLEMS] To provide a method of rapid alkene compound methylation which is applicable to the preparation of a PET tracer and which enables an alkene compound to be rapidly methylated through cross coupling between SP2 (alkenyl) and SP3 (alkyl) carbon atoms in high yield. [MEANS FOR SOLVING PROBLEMS] Methyl iodide and an alkenyltrialkylstannane are subjected to cross coupling in an aprotic polar solvent in the presence of a complex of palladium having a valence of 0, a phosphine ligand, a cuprous halide, and a carbonate and/or alkali metal fluoride.

67. 发明公开

EP1970351A1 Method of preparing metalloaluminophosphate (Meapo) molecular sieve 审中-公开
标题翻译： Verfahren zur Herstellung von Metallaluminophosphat（MEAPO）-Molekularsieben
公开(公告)号：EP1970351A1
公开(公告)日：2008-09-17
申请号：EP07300861.7
申请日：2007-03-13
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) Etablissement Public
发明人： Vermeiren, Walter , Nesterenko, Nikolai , Petitto, Carolina, Résidence de Mail des Abbés C1 , Di Renzo, Francesco, Les Cèdres BC , Fajula, Francois
IPC分类号： C01B37/08 , B01J29/85 , C07C1/20 , C07C1/26 , C07C1/32
CPC分类号： B01J29/84 , B01J29/85 , C01B37/06 , C01B37/08 , C07C1/20 , C07C1/26 , C07C1/322 , C07C2529/84 , C07C2529/85 , Y02P30/42 , C07C11/02
摘要： The present invention also relates to a method for preparing metalloaluminophosphate (MeAPO) molecular sieve said method comprising :
a) forming a reaction mixture containing a texture influencing agent (TIA), an organic templating agent (TEMP), at least a reactive inorganic source of MeO 2 insoluble in the TIA, reactive sources of Al 2 O 3 and P 2 O 5 ,
b) crystallizing the above reaction mixture thus formed until crystals of the metalloaluminophosphate are formed,
c) recovering a solid reaction product,
d) washing it with water to remove the TIA and
e) calcinating it to remove the organic template.
In a usual embodiment said reaction mixture has a composition expressed in terms of molar oxide ratios of :
TEMP/Al 2 O 3 = 0.3-5 , more desirable 0.5-2
MeO 2 /Al 2 O 3 = 0.005-2.0, more desirable 0.022-0.8
P 2 O 5 /Al 2 O 3 =0.5-2, more desirable 0.8-1.2
TIA/Al 2 O 3 = 3-30, more desirable 6-20
In a usual embodiment the metalloaluminophosphate (MeAPO) molecular sieves made with the above method have a lamellar crystal morphology having an empirical chemical composition on an anhydrous basis, after synthesis and calcination, expressed by the formula H x Me y Al z P k O 2 wherein, y+z+k=1, x
y has a value ranging from 0.0008 to 0.4 and more desirable from 0.005 to 0.18
z has a value ranging from 0.25 to 0.67 and more desirable from 0.38 to 0.55
k has a value ranging from 0.2 to 0.67 and more desirable from 0.36 to 0.54
said molecular sieve having predominantly a plate crystal morphology.
In an advantageous embodiment the MeAPO made by the method of the invention have essentially a structure CHA or AEI or a mixture thereof. Preferably they have essentially the structure SAPO 18 or SAPO 34 or a mixture thereof.
The present invention also relates to catalysts consisting of the above MeAPO molecular sieves made by the method of the invention or comprising the above MeAPO molecular sieves made by the method of the invention.
The present invention also relates to a process for making an olefin product from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock wherein said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock is contacted with the above catalyst under conditions effective to convert the oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to olefin products.
摘要翻译：本发明还涉及一种制备金属铝磷酸盐（MeAPO）分子筛的方法，所述方法包括：a）形成含有纹理影响剂（TIA），有机模板剂（TEMP），至少反应性无机源 MeO 2不溶于TIA，Al 2 O 3和P 2 O 5的反应性源，b）使如此形成的上述反应混合物结晶直到形成金属铝磷酸盐晶体，c）回收固体反应产物，d）用水去除TIA，e）煅烧以除去有机模板。在通常的实施方案中，所述反应混合物具有以摩尔氧化物比例表示的组成：TEMP / Al 2 O 3 = 0.3-5，更优选0.5-2 MeO 2 / Al 2 O 3 = 0.005-2.0，更优选0.022 -0.8 P 2 O 5 / Al 2 O 3 = 0.5-2，更优选0.8-1.2 TIA / Al 2 O 3 = 3-30，更优选6-20在通常的实施方案中，金属铝磷酸盐（MeAPO）分子筛由上述方法具有在无水基础上经合成和煅烧的经验化学组成的层状晶体形态，由式H x Me y Al z P k O 2表示，其中，y + z + k = 1，x <= yy具有0.0008至0.4的值，更优选0.005至0.18z具有范围为0.25至0.67的值，更优选从0.38至0.55k具有范围为0.2至0.67且更优选为0.36至0.54的所述分子主要是板晶形态的筛。在有利的实施方案中，通过本发明的方法制备的MeAPO基本上具有结构CHA或AEI或其混合物。优选地，它们基本上具有SAPO 18或SAPO 34或其混合物的结构。本发明还涉及由通过本发明的方法制备的上述MeAPO分子筛或包含通过本发明的方法制备的上述MeAPO分子筛组成的催化剂。本发明还涉及一种由含氧卤化物或含硫有机原料制备烯烃产物的方法，其中所述含氧卤化物或含硫有机原料与上述催化剂接触有效地将含氧卤化物或含硫有机原料转化为烯烃产物的条件。

68. 发明公开

EP1572606A4 CROSS-COUPLING SYNTHESIS OF ALKYL (DIALKYLPHENYL) INDENES 审中-公开
标题翻译：烷基（二烷基苯基）茚交叉耦合合成
公开(公告)号：EP1572606A4
公开(公告)日：2008-07-09
申请号：EP03756347
申请日：2003-05-28
申请人： BOULDER SCIENT CO
发明人： BARNES HAMLIN H
IPC分类号： C07C1/32 , C07C13/00
CPC分类号： C07C1/321 , C07C2531/22 , C07C13/465
摘要： A cross-coupling synthesis of 2-alkyl-4-(2,6dialkylphenyl)indenes is described. A 2-alkylidene is treated with a dialkylboronic acid in the presence of a catalyst. A feature of the invention is the use of a cross-coupling catalyst comprising palladium dichloride (1,5-cyclooctadiene) as a cross-coupling catalyst.

69. 发明公开

EP1386663A4 MICROENCAPSULATED METAL CATALYST 有权
标题翻译：微囊化金属催化剂
公开(公告)号：EP1386663A4
公开(公告)日：2007-03-21
申请号：EP02701554
申请日：2002-02-15
申请人： JAPAN SCIENCE & TECH AGENCY
发明人： KOBAYASHI SHU
IPC分类号： B01J13/06 , C07D333/08 , B01J13/14 , B01J23/44 , B01J31/06 , B01J31/16 , B01J31/24 , B01J33/00 , B01J35/08 , C07B61/00 , C07C1/32 , C07C15/14 , C07C67/343 , C07C69/618 , C07C69/738 , C07C69/757 , C07C319/20 , C07C321/22
CPC分类号： C07C67/343 , B01J13/06 , B01J13/14 , B01J23/44 , B01J31/165 , B01J31/2404 , B01J2231/4205 , B01J2231/44 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , C07C69/73 , C07C69/738 , C07C69/618 , C07C69/757
摘要： A microencapsulated Group VIII metal catalyst which is stable even in air, easy to recover, and reutilizable. It comprises a polymer having side chains each comprising an aromatic substituent and, encapsulated in the polymer, a metal catalyst comprising a Group VIII metal.

70. 发明公开

EP1129057A4 SYNTHESIS OF N-SILYLATED CYCLOPENTAPHENANTHRENE COMPOUNDS 审中-公开
标题翻译：合成ON ON EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN
公开(公告)号：EP1129057A4
公开(公告)日：2004-10-06
申请号：EP00963345
申请日：2000-08-31
申请人： BOULDER SCIENT CO
发明人： ASKHAM FREDRIC R
IPC分类号： C07C29/143 , B01J31/22 , C07C1/24 , C07C1/32 , C07C13/66 , C07C13/68 , C07C15/02 , C07C29/14 , C07C35/06 , C07C35/42 , C07C35/44 , C07C303/28 , C07C309/66 , C07C309/71 , C07F7/10 , C07F7/28 , C07F17/00 , C08F4/44 , C08F4/64 , C08F10/00
CPC分类号： C07F17/00 , B01J31/2295 , B01J2531/40 , C07C13/66 , C07C29/143 , C07C303/28 , C07C2603/40 , C07F7/10 , C08F10/00 , Y10S526/943 , C08F4/6592 , C07C309/66
摘要： A method of converting Compound A (1,3-dehydro-cyclopenta[1]phenanthren-2-one) to Compound C (1H-cyclopenta[1]phenanthren) in situ in a single reactor is disclosed.
摘要翻译：公开了合成某些N-甲硅烷基环戊菲（IV族金属）络合物的方法。

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