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    • 63. 发明公开
    • POLYOXALATE AND METHOD FOR PRODUCING SAME
    • 多伦多维多利亚州ZUR HERSTELLUNG DAVON
    • EP3088437A1
    • 2016-11-02
    • EP14874361.0
    • 2014-12-24
    • Toyo Seikan Group Holdings, Ltd.
    • YOSHIKAWA, SeishiYAMADA, Toshiki
    • C08G63/16C08G63/78
    • C08G63/16C08G63/78C09K8/035C09K8/12C09K8/68C09K8/885
    • A polyoxalate containing, as a chief constituent unit, a recurring unit represented by the following formula (1):

              -(-CO-CO-O-A-O-) n -     (1)

      wherein n is a positive number, and
      A is a divalent organic group,
      and having a quantity of heat of fusion ΔHm of not less than 60 J/g as measured by the DSC in the first time of elevating the temperature and as calculated by the following formula: ΔHm = ΔHm ′ − ΔHc wherein,
      ΔHm' is a quantity of heat of fusion (J/g) inclusive of heat of crystallization while the temperature is being elevated, and
      ΔHc is a quantity of heat (J/g) generated by the crystallization,
      permitting the components to be volatilized in an amount of not more than 2.0% by weight when the temperature is elevated up to 200°C as measured by the TGA, and having a 5% weight loss temperature (Td5%) of not higher than 230°C, and a process for the production thereof. The polyoxalate exhibits a highly hydrolysable capability even at low temperatures, can be excellently crushed, i.e., is capable of effectively preventing itself from undergoing the blocking when it is being crushed.
    • 含有以下式(1)表示的重复单元作为主要组成单元的聚草酸酯:ƒ€ƒ€ƒ€ƒ€ƒ€ƒ - ( - CO-CO-OAO-)n - (1)其中n是正数,A是二价有机基团,并且具有不小于60J / g的熔融热量“Hm”,其通过 DSC在第一次升高温度时按以下公式计算:“Hm =”Hm²“”Hc其中,“Hm”是熔化热量(J / g),包括结晶热 而温度升高时,“Hc是通过结晶产生的热量(J / g),当温度升至200℃时,允许组分挥发量不超过2.0重量% ℃,并且具有不高于230℃的5%重量损失温度(Td5%)及其制备方法。 即使在低温下,聚草酸酯也显示出高度可水解的能力,可以非常好地破碎,即当其被粉碎时能够有效地防止其自身遭受阻塞。