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61. 发明公开

EP3088434A1 FLUORINE-CONTAINING DIBLOCK COPOLYMER 有权
标题翻译：荧光显微镜
公开(公告)号：EP3088434A1
公开(公告)日：2016-11-02
申请号：EP14875460.9
申请日：2014-12-22
申请人： Unimatec Co., Ltd.
发明人： SAITO, Satoru , SATO, Katsuyuki , SONOI, Takehiro
IPC分类号： C08F293/00 , C08F4/00
CPC分类号： C08F293/005 , C08F220/24 , C08F2438/01 , C08F2438/03
摘要： The object of the present invention is to provide a fluorine-containing diblock copolymer having good water and oil repellency by using, as a raw material, a fluorine-containing (meth)acrylic ester having low bioaccumulation potential. The fluorine-containing diblock copolymer of the present invention is producedby: (process A) a process for producing a fluorine-containing diblock copolymer by polymerizing a fluorine-containing (meth) acrylic ester represented by the following formula (1) in the presence of a trithiocarbonic ester compound and a radical polymerization initiator and then polymerizing a non-fluorine vinyl-based monomer, or (process B) a process for producing a fluorine-containing diblock copolymer by polymerizing a non-fluorine vinyl-based monomer in the presence of a trithiocarbonic ester compound and a radical polymerization initiator and then polymerizing a fluorine-containing (meth) acrylic ester represented by the following formula (1).
摘要翻译：本发明的目的是提供一种具有低生物累积潜力的含氟（甲基）丙烯酸酯作为原料的具有良好拒油拒油性的含氟二嵌段共聚物。本发明的含氟二嵌段共聚物的制造方法是：（工序A）通过在下述式（1）表示的含氟（甲基）丙烯酸酯的存在下，使含氟二三氟碳酸酯化合物和自由基聚合引发剂，然后聚合非氟乙烯基类单体，或（方法B）通过在非氟乙烯基类单体存在下聚合制备含氟二嵌段共聚物的方法三硫代碳酸酯化合物和自由基聚合引发剂，然后聚合由下式（1）表示的含氟（甲基）丙烯酸酯。

62. 发明授权

EP2578629B1 AQUEOUS DISPERSION OF FLUORINE-CONTAINING POLYMER 有权转让
标题翻译：水分散体的含氟聚合物
公开(公告)号：EP2578629B1
公开(公告)日：2016-09-14
申请号：EP11786495.9
申请日：2011-05-13
申请人： Unimatec Co., Ltd.
发明人： KANEUMI Yoshiyama , MURAI Daisuke
IPC分类号： C08L27/12 , C08F2/24 , C08K5/5337 , C08F14/22
CPC分类号： C08K5/5317 , C08F2/26 , C08F2/30 , C08F14/22 , C08F214/22 , C08F214/26 , C08F214/28

63. 发明公开

EP2966141A1 FLUORINE-CONTAINING CALCIUM COMPOSITE PARTICLES, PREPARATION METHOD THEREFOR, AND SURFACE TREATMENT AGENT USING SAME AS ACTIVE COMPONENT 审中-公开
标题翻译： FLUOR含硫铝酸钙复合工艺用于生产和表面处理剂，作为ACTIVE
公开(公告)号：EP2966141A1
公开(公告)日：2016-01-13
申请号：EP14759655.5
申请日：2014-03-06
申请人： Unimatec Co., Ltd. , Hirosaki University
发明人： SATO Katsuyuki , SAWADA Hideo
IPC分类号： C09K3/18 , C08G77/385 , C08K3/18 , C08K5/098 , C08K5/5415 , C08L71/00
CPC分类号： C09D5/00 , C07C31/38 , C08G65/007 , C08G77/24 , C08J3/223 , C08K5/05 , C08K5/053 , C08K5/42 , C08K2003/162 , C08K2003/2206 , C08K2003/265 , C08L71/00 , C09D7/40 , C09D7/61 , C09D7/63
摘要： Fluorine-containing calcium composite particles comprising an aggregate of a fluorine-containing alcohol represented by the general formula:

C n F 2n+1 (CH 2 CF 2 ) a (CF 2 CF 2 ) b (CH 2 CH 2 ) c OH

wherein n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 0 to 3, and c is an integer of 1 to 3; and a calcium compound,
or fluorine-containing calcium composite particles comprising a condensate of a fluorine-containing alcohol represented by the general formula: R F -A-OH or the general formula: HO-A-R F '-A-OH wherein R F is a liner or branched perfluoroalkyl group that may contain an O, S, or N atom, or a polyfluoroalkyl group in which some of the fluorine atoms of the perfluoroalkyl group are replaced by hydrogen atoms; R F ' is a linear or branched perfluoroalkylene group containing an O, S, or N atom; and A is an alkylene group having 1 to 6 carbon atoms; alkoxysilane, and a calcium compound. The latter fluorine-containing calcium composite particles are used as an active ingredient of water- and oil-repellent.
摘要翻译：含氟钙复合颗粒，其包括由所述通式表示的含氟醇的聚集体：€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒC·N·2N + 1（CH 2 CF 2）（ CF 2 CF 2）b（CH 2 CH 2）C OH，其中n为1至6的整数，a为1〜4的整数，b是0〜3的整数，和c为1的整数 3; 和钙化合物或包含由所述通式表示的含氟醇的缩合物含氟钙复合粒子：RF -A-OH或通式：HO-AR F“-A-OH worin RF是一个衬里或支链全氟烷基也可以含有O，S或N原子，或其中某些全氟烷基的氟原子的由氢原子代替多氟烷基; R F“为含有O，S或N原子的直链或支链的全氟亚烷基; 和A是具有1至6个碳原子的亚烷基团; 烷氧基硅烷，和钙化合物。后期含氟钙复合粒子用作拒水拒油剂的有效成分。

64. 发明公开

EP2792693A4 FLUORINATED COPOLYMER, AND WATER-REPELLENT/OIL-REPELLENT AGENT COMPRISING SAME AS ACTIVE INGREDIENT 有权
标题翻译：含氟共聚物和拒水/油性与这种共聚物为活动
公开(公告)号：EP2792693A4
公开(公告)日：2015-11-04
申请号：EP12858348
申请日：2012-11-16
申请人： UNIMATEC CO LTD
发明人： KANEUMI YOSHIYAMA
IPC分类号： C08F220/24 , C08F220/28 , C09K3/18 , D06M15/27 , D06M15/277
CPC分类号： D06M15/277 , C08F220/24 , C08F220/28 , C08F220/68 , C08F2220/286 , D06M13/395 , D06M2101/06 , D06M2200/01 , D06M2200/10 , D06M2200/11 , D06M2200/12 , Y10T442/2172

65. 发明公开

EP2479216A4 EMULSION AND MOLD RELEASE AGENT COMPRISING THE EMULSION 有权
标题翻译：乳化剂乳化剂MIT DER EMULSION
公开(公告)号：EP2479216A4
公开(公告)日：2015-09-16
申请号：EP10817116
申请日：2010-09-10
申请人： UNIMATEC CO LTD
发明人： KANEUMI YOSHIYAMA , SATO KATSUYUKI
IPC分类号： C08L71/02 , A01N1/02 , B29C33/60 , B29C33/62 , B29K105/00 , C08G65/00 , C08G65/335 , C08K5/5317 , C08K5/5337 , C08L71/00 , C09K3/00 , C09K3/18
CPC分类号： B22C3/00 , A01N1/021 , B29C33/62 , B29K2105/0064 , C08G65/007 , C08G65/3353 , C08G2650/48 , C08K5/5337 , C08L71/00

66. 发明公开

EP2439039A4 MOLD RELEASE AGENT 有权
标题翻译： FORMLÖSUNGSMITTEL
公开(公告)号：EP2439039A4
公开(公告)日：2015-09-02
申请号：EP10783434
申请日：2010-06-03
申请人： UNIMATEC CO LTD
发明人： KANEUMI YOSHIYAMA , MURATA SEIICHIRO , SATO KATSUYUKI
IPC分类号： B29C33/62 , B29K27/12 , B29K96/02 , C08F283/06 , C08L27/12 , C08L71/02 , C09D7/12 , C09D151/00 , C09D171/02 , C09K3/00
CPC分类号： B29C33/62 , B29K2027/12 , B29K2096/02 , C08F283/06 , C08G2261/128 , C08L27/12 , C08L71/02 , C08L2205/05 , C09D151/00 , C08F214/18 , C08L2666/04

67. 发明公开

EP2439038A4 GRAFT COPOLYMER AND MOLD RELEASE AGENT COMPRISING SAME AS ACTIVE INGREDIENT 有权
标题翻译：接枝共聚物和SHAPE分离介质，作为ACTIVE
公开(公告)号：EP2439038A4
公开(公告)日：2015-09-02
申请号：EP10783433
申请日：2010-06-03
申请人： UNIMATEC CO LTD
发明人： KANEUMI YOSHIYAMA , MURATA SEIICHIRO , SATO KATSUYUKI
IPC分类号： B29C33/62 , B29K27/12 , B29K96/02 , C08F283/06 , C09K3/00
CPC分类号： B29C33/62 , B29K2027/12 , B29K2096/02 , C08F283/06 , C08F214/182

68. 发明授权

EP2617700B1 NOVEL FLUORINATED VINYL ETHER COMPOUND AND MANUFACTURING METHOD THEREFOR 有权
标题翻译：用于制造新的氟化乙烯基醚AND PROCESS
公开(公告)号：EP2617700B1
公开(公告)日：2014-10-29
申请号：EP11824950.7
申请日：2011-08-24
申请人： Unimatec Co., Ltd.
发明人： MURAKAMI Soichiro , KOKIN Keisuke , MURATA Seiichiro
IPC分类号： C07C43/17 , C07C41/14 , C07C41/09 , C07B61/00
CPC分类号： C07C43/17 , C07C41/09 , C07C41/14

69. 发明公开

EP2792693A1 FLUORINATED COPOLYMER, AND WATER-REPELLENT/OIL-REPELLENT AGENT COMPRISING SAME AS ACTIVE INGREDIENT 有权
标题翻译：含氟共聚物和拒水/油性与这种共聚物为活动
公开(公告)号：EP2792693A1
公开(公告)日：2014-10-22
申请号：EP12858348.1
申请日：2012-11-16
申请人： Unimatec Co., Ltd.
发明人： KANEUMI Yoshiyama
IPC分类号： C08F220/24 , C08F220/28 , C09K3/18 , D06M15/27 , D06M15/277
CPC分类号： D06M15/277 , C08F220/24 , C08F220/28 , C08F220/68 , C08F2220/286 , D06M13/395 , D06M2101/06 , D06M2200/01 , D06M2200/10 , D06M2200/11 , D06M2200/12 , Y10T442/2172
摘要： Disclosed is a copolymer of a polyfluoroalkyl alcohol (meth)acrylic acid derivative represented by the formula: C n F 2n+1 (CH 2 CF 2 ) a (CF 2 CF 2 ) b (CH 2 CH 2 ) c OCOCR=CH 2 (R: H or CH 3 , n: 1 to 6, a: 1 to 4, b: 1 to 3, and c: 1 to 3), and a (meth)acrylic acid polyoxyalkylene ester represented by the formula: R 1 (OR 2 ) p (OR 3 ) q OCOCR=CH 2 (R: H or CH 3 ; R 1 : H, an alkyl group, or an aromatic group; R 2 and R 3 : alkylene groups having 1 to 6 carbon atoms; p: 2 to 50, q: 0 or 1 to 50), and also disclosed is a water- and oil-repellent comprising this fluorine-containing copolymer as an active ingredient. The water- and oil-repellent comprising this fluorine-containing copolymer as an active ingredient can be used as a stain-proof-type water- and oil-repellent that can apply effective stain-proof finish and stain removal finish to fiber fabrics, and that has excellent washing durability.

70. 发明公开

EP2698390A4 METHOD FOR PRODUCING FLUORINE-CONTAINING ELASTOMER 审中-公开
标题翻译：用于生产含氟弹性体
公开(公告)号：EP2698390A4
公开(公告)日：2014-10-22
申请号：EP12771208
申请日：2012-04-09
申请人： UNIMATEC CO LTD
发明人： MURAI DAISUKE , MAEDA MITSURU
IPC分类号： C08F236/20 , C08F2/26 , C08F214/18 , C08K5/14 , C08L27/12 , C08L47/00
CPC分类号： C08F236/20 , C08F214/18 , C08F214/184 , C08F214/222 , C08K5/14

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