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    • 49. 发明公开
    • High strength fibers of stereoregular polystyrene
    • Fasern von hoher Festigkeit ausstereoreguläremPolystyren。
    • EP0351707A2
    • 1990-01-24
    • EP89112750.8
    • 1989-07-12
    • THE DOW CHEMICAL COMPANY
    • Pedersen, David R.Pierini, Peter E.Beck, Henry NelsonSemer, Mark J.
    • D01F6/22
    • D01F6/22
    • The invention is a crystalline fiber comprising syndiotactic polystyrene, or a mixture. Preferably the fiber is a high strength fiber isotactic polystyrene and syndiotactic polystyrene wherein the fiber is monoaxially oriented, has a tensile strength of 10,000 psi or greater, and a modulus of 1,000,000 psi or greater.
      In another aspect the invention is a process for the preparation of fibers of syndiotactic polystyrene, or a mixture of isotactic polystyrene and syndiotactic polystyrene which comprises:

      A. contacting syndiotactic polystyrene, or a mixture of isotactic polystyrene and syndiotactic polystyrene with a solvent for the polystyrene at elevated temperatures under conditions such that a homogeneous solution is formed which has sufficient viscosity to be extruded;
      B. extruding the solution through an orifice to form a fiber at elevated temperatures;
      C. quenching the fiber by passing the fiber through one or more zones under conditions such that the fiber solidifies;
      D. removing the solvent for the polystyrene from the fiber; and
      E. cooling the fiber to ambient temperature.

      In the embodiment where it is desirable to prepare high strength fibers, the fibers are further exposed to the following process steps:

      F. heating the fiber to a temperature above the glass transition temperature of the polystyrene;
      G. redrawing the fiber to elongate the fiber, maximize crystallinity, and induce monoaxial orientation of the polystyrene in the fiber.
    • 本发明是包含间同立构聚苯乙烯或混合物的结晶纤维。 优选地,纤维是高强度纤维全同立构聚苯乙烯和间同立构聚苯乙烯,其中纤维是单轴取向的,拉伸强度为10,000psi或更大,模量为1,000,000psi或更大。 在另一方面,本发明是制备间同立构聚苯乙烯纤维或全同立构聚苯乙烯与间同立构聚苯乙烯的混合物的方法。