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    • 36. 发明授权
    • SUBSTITUIERTE 2-AMINOTHIOPHENE ENTHALTENDE HERBIZIDE MITTEL
    • 取代的2-氨基噻吩除草剂含有中
    • EP0561853B1
    • 1998-02-25
    • EP92900007.3
    • 1991-12-03
    • BASF Aktiengesellschaft
    • HAGEN, HelmutNILZ, GerhardWALTER, HelmutLANDES, Andreas
    • A01N25/32C07D333/26C07D333/62
    • C07D409/04A01N25/32C07D333/38C07D333/68C07D409/12C07D417/12
    • Herbicidal agents contain as antagonistic compound at least one substituted 2-aminothiophene having formula (I), in which R1, R2 stand for H, CN, alkyl, halogen alkyl, if necessary substituted phenyl, CO-R?6 or R1 + R2¿ stand for a C¿3?-C6 alkylene chain, upon which a benzene ring, if necessary substituted, may be annulated, a C2-C3 alkylene chain broken by -O- or -N(R?7¿)-, which may also carry 1-4 alkenyl residues or a group CO-N(R?7)-CO; R3¿ stands for CN, if necessary substituted -C(NH¿2?)=N-C6H5, -C(NH3?+Hal-)=N-C¿6H5, CX-R6; Hal stands for halogen; R4 stands for H, alkyl, alkenyl, if necessary substituted phenyl, if necessary substituted triazin, -PX(OR8)2, -CX-R9, -SO2R10, -SO2-NHR10, -CX-N(R?7)-CY-R8¿, -CX-N(R7)-SO2-R?11 or R3=R4¿ stand for CO-O-CO; R5 stands for H, alkyl, -CX-R9, -SO2-R10; X, Y stand for O, S; R7 stands for H, phenyl, alkyl; R8 stands for H, alkyl, if necessary substituted phenyl; R9 stands for alkyl, halogen alkyl, alkenyl, halogen alkenyl, if necessary substituted cycloalkyl or cycloalkenyl, NH¿2?, alkylamino, dialkylamino, cycloalkylamino, if necessary substituted phenyl or phenylamino; R?10¿ stands for alkyl, if necessary substituted phenyl; R11 stands for NH¿2?, alkylamino, dialkylamino, if necessary substituted pyrrolidinyl, piperidinyl, morpholinyl, piperazinyl; R?4 + R5¿ stand for =CR12R13 or -CO-W-CO-; R12 stands for H, NH¿2?, alkylamino, cycloalkylamino; R?13¿ stands for NH¿2?, alkylamino, dialkylamino, cycloalkylamino, if necessary substituted thienylamino, pyrrolidinyl, piperidinyl, morpholinyl, if necessary substituted phenyl or pyridyl; W stands for an ethylene or ethenylene bridge, if necessary substituted, or for an aromatic or heteroaromatic 5/6 membered cycloalkylene or cycloalkenylene bridge, if necessary substituted. Also disclosed are a basic salt of compound (I), in which R?3¿ stands for hydroxycarbonyl, hydroxythiocarbonyl, or an acid salt of compound (I) which contains a basic hydrogen atom, and at least one herbicidal active substance from (A) the group of 4-aryloxy- and 4-heteroaryloxy-phenoxyacetic acid derivates or from (B) the group of cyclohexan-1,3-dione derivates.