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31. 发明授权

EP0293502B1 Method for analysis of molten metal 失效
标题翻译：金属分析方法
公开(公告)号：EP0293502B1
公开(公告)日：1992-09-30
申请号：EP87107977.8
申请日：1987-06-02
申请人： ALUMINUM COMPANY OF AMERICA
发明人： Genna, John Lawrence
IPC分类号： G01N33/20
CPC分类号： G01N1/125 , G01N33/203 , Y10T436/12

32. 发明公开

EP0450090A4 METHOD OF AND DEVICE FOR MEASURING OXYGEN ACTIVITY IN SLAG AND CONSUMABLE TYPE CRUCIBLE USED FOR SAID DEVICE 失效转让
标题翻译：用于测量SLAG中的氧活性的方法和装置以及用于上述装置的消耗型可硬化
公开(公告)号：EP0450090A4
公开(公告)日：1992-06-24
申请号：EP90914968
申请日：1990-10-15
申请人： YAMARI ELECTRONITE KABUSHIKIGAISHA
发明人： IWASE, M. 216-GO, KYOTO DAIGAKU KUMANO SHOKUIN , FUJIWARA, RYUJI , MOCHIZUKI, RYO
IPC分类号： G01N27/411 , G01N27/417 , G01N33/20
CPC分类号： G01N27/4115 , G01N33/203
摘要： This invention relates to a method and device permitting measurement of oxygen activity in the molten pig iron slag and molten steel slag with high precision. According to the conventional method of measurement depending on the oxygen-concentration cell composed of a one-end-closed tube type solid electrolyte fixed to the tip of the probe, having a contrasting platinum electrode wound around the outer surface thereof, and located directly in the molten slag layer, positioning of the cell in the flowing slag is difficult and insufficient contact of the contrasting electrode with the slag layer is caused on account of thermal contraction of the electroyte resulting from heat of the slag, whereby errors possibly occur in measurement. Unlike the direct measurement of oxygen activity in the slag, this invention provides a method in which a specific metal whose oxygen activity equilibrates with that of the slag when brought into contact with the slag is contained in the same vessel together with the slag and oxygen activity in the specific metal is measured for indirect measurement of oxygen activity in the slag, whereby the problem resulting from insufficient contact of the solid electrolyte with the contrasting electrode can be solved and measurement of oxygen activity in the slag with high precision is ensured.

33. 发明授权

EP0250411B1 AN ARRANGEMENT FOR USE IN THE THERMAL ANALYSIS AND MODIFICATION OF MOLTEN METAL 失效转让
标题翻译：用于热分析和修饰金属的安排
公开(公告)号：EP0250411B1
公开(公告)日：1992-04-01
申请号：EP86901544.6
申请日：1986-02-04
申请人： SinterCast Ltd.
发明人： BÄCKERUD, Stig, Lennart
IPC分类号： G01N25/04
CPC分类号： G01N25/04 , G01N33/203 , Y10S73/09
摘要： An arrangement for use when thermally analyzing and modifying molten metal, by recording solidification data and controlling the structural modification of the molten metal on the basis of such data. The arrangement includes a sampling container made from a material which remains substantially stable at the temperature of the molten metal and which is adapted to receive at least one thermoelement for recording the solidification data. Means are also provided for taking a sample of the molten metal with the aid of the container, and for moving the sample to an area in which substantially the same conditions prevail. In addition, the arrangement includes recording means and means for modifying the structure of the molten metal as required. The sampling container is constructed to allow molten metal to pass thereinto when the container is immersed into the molten metal, and to allow a previous content of the container to be displaced therefrom and replaced with fresh molten metal as a result of relative movement between the container and the molten metal. Means are provided to ensure that a suitable quantity of molten metal is collected during a sampling operation. This may be achieved by providing the sampling container with openings which are closed and exposed by valve means or by some other suitable arrangement.

34. 发明公开

EP0358168A2 Method, apparatus and probe for measuring the activity of a solute element in molten metal 失效
标题翻译：一种方法，装置及测试方法在熔融金属元素的溶质的活性的测量。
公开(公告)号：EP0358168A2
公开(公告)日：1990-03-14
申请号：EP89116377.6
申请日：1989-09-05
申请人： Sasabe, Minoru , NKK CORPORATION , Osaka Sanso Kogyo Limited
发明人： Sasabe, Minoru , Hasegawa, Teruyuki c/o Patent & License Dept., , Ishikawa, Hiroaki c/o Patent & License Dept., , Kawai, Yoshihiko c/o Patent & License Dept., , Furuta, Chikayoshi c/o Osaka Sanso Kogyo Ltd., , Nagatsuka, Toshio c/o Osaka Sanso Kogyo Ltd., , Matsushige, Haruhiko c/o Osaka Sanso Kogyo Ltd.,
IPC分类号： G01N27/406
CPC分类号： G01N27/4114 , G01N33/203
摘要： A method for measuring an activity of a solute element M in molten metal comprises steps of measuring an electromotive force E1 corresponding oxygen content of the molten metal by means of a solid electrolyte (26) having oxygen ion conductivity and measuring temperature T of the molten metal, also measuring the electromotive force E2 corresponding to manganese content of the molten metal by means of a solid electrolyte (26) having oxygen ion conductivity and coated with MnO, and obtaining the manganese activity a Mn on the basis of the measured electromotive forces E1, E2 and the measured temperature T. Another activity measuring method comprises steps of measuring the temperature T and solidifying temperature Ts of molten metal, obtaining the carbon concentration [C] of the molten metal on the basis of the solidifying temperature Ts, also measuring the manganese electromotive force E2 in the molten metal by means of a solid electrolyte (26) having oxygen ion conductivity and coated with MnO, and obtaining the manganese activity a Mn on the basis of the measured electromotive force E2, the carbon concentration [C], and the measured temperature T. An Mn sensor electrode (11) comprises a solid electrolyte (26) surrounding a reference (25) and having oxygen ion conductivity, and a coating layer (27) composed of MnO or a composite oxide thereof and covering the outer periphery of the solid electrolyte (26). The MnO or the composite oxide for the coating layer (27) has a composition such that two or more balance portions A, B, C, D are provided for an electromotive force E1, E2 measured by an electromotive force measuring circuit, the electromotive force E1, E2 being defined by the manganese activity a Mn in the first one A, C of the balance portions, and by the oxygen activity a O in the molten metal in the last balance portion B, D.
摘要翻译：一种用于测量熔化金属的溶质元素M的活性的方法，由具有氧离子传导性和测量的熔融金属的温度T的固体电解质（26）的装置包括熔融金属的电动势E1相应的氧含量测量的步骤通过固体电解质（26），具有氧离子传导性的装置，以便测量所述电动势E2对应于锰的熔融金属的含量和涂有MnO和测量的电动势E1，E2的基础上获得的锰活性AMN 和所测量的温度T的另一种活性测定方法包括测量温度T和凝固的熔融金属的温度Ts，从而获得熔融金属的碳浓度[C]固化温度Ts的基础上，因此测量锰电动势的步骤力E2在熔融金属通过的固体电解质的装置（26），其具有的氧离子传导性和涂布机智 ħMnO和获得锰活性AMN测量的电动势E2的基础上，碳浓度[C]，和所测量的温度T的锰传感器电极（11）包括围绕基准的固体电解质（26）（ 25）和具有氧离子传导性，和MnO的组成的涂层（27）或复合氧化物和其覆盖固体电解质（26）的外周。 MnO的或用于涂层（27）的复合氧化物具有测试做A，B，C，D是在电动势提供了一种用于在电动势E1，E2通过测量两个或更多的平衡部分测量电路，该电动势的组合物 E1，E2被通过在第一一项所述的锰活性AMN定义的，平衡部C，并通过在部分B，D的负载平衡的氧活性AO在熔融金属

35. 发明公开

EP0239116A3 Method for determining deoxidant concentration in molten metal 失效转让
标题翻译：确定金属中脱氧剂浓度的方法
公开(公告)号：EP0239116A3
公开(公告)日：1990-01-24
申请号：EP87104527.4
申请日：1987-03-26
申请人： PRAXAIR TECHNOLOGY, INC.
发明人： Riley, Michael Francis
IPC分类号： G01N33/20
CPC分类号： G01N33/203
摘要： A method for rapidly and accurately determining the deoxidant concentration of a molten metal bath having a complex slag and/or complex deoxidation products, without the need for a chemical analysis of the metal.

36. 发明公开

EP0295112A3 Probe for measuring concentration of impurity element in molten metal 失效
标题翻译：用于测量金属元素中浓度元素的浓度的探测
公开(公告)号：EP0295112A3
公开(公告)日：1989-10-11
申请号：EP88305301.9
申请日：1988-06-10
申请人： Osaka Sanso Kogyo Limited , NIPPON KOKAN KABUSHIKI KAISHA , Sasabe, Minoru
发明人： Hamada, Nobuo , Nagatsuka, Toshio
IPC分类号： G01N27/416
CPC分类号： G01N27/4112 , G01N27/4114 , G01N33/203
摘要： A probe for measuring the concentration of an element contained as an impurity in a molten metal which comprises a solid electrode having coating layer provided on its surface, and standard electrode for providing a predetermined oxygen potential is disclosed, characterized in that the coating layer contains an oxide of the element which is the object of measurement or a compound oxide containing the element, a metallic fluoride and a binder so as to maintain at an approximately constant level the activity of the oxide of the element. Employment of the probe enables fast measurement of the concentration of an element contained as an impurity in a molten metal.

37. 发明授权

EP0138499B1 Molten metal sampler with tellurium additive 有权
标题翻译：用金属添加剂的金属取样器
公开(公告)号：EP0138499B1
公开(公告)日：1989-03-29
申请号：EP84306698.6
申请日：1984-10-01
申请人： Falk, Richard Arden
发明人： Falk, Richard Arden
IPC分类号： G01N25/04 , G01N33/20
CPC分类号： G01N33/203 , G01N25/04

38. 发明公开

EP0300136A2 Treatment of liquid melts 失效
标题翻译： Behandlung vonflüssigenSchmelzen。
公开(公告)号：EP0300136A2
公开(公告)日：1989-01-25
申请号：EP88105717.8
申请日：1985-05-17
申请人： MOUNTFORD, Norman Duncan Gerard
发明人： MOUNTFORD, Norman Duncan Gerard
IPC分类号： G01N33/20
CPC分类号： G01N29/228 , G01N29/032 , G01N29/2462 , G01N29/28 , G01N33/203 , G01N2291/02416 , G01N2291/0252
摘要： In order to reduce the number of inhomogeneous particles distributed through a liquid metal melt, the melt is treated by:
creating a standing wave of ultrasound energy within the melt, whereby the inhomogeneous particles concentrate, and are encouraged to coalesce, at the nodes of the standing wave; and
separating the coalesced particles from the bulk of the liquid melt.
摘要翻译：为了减少通过液态金属熔体分布的不均匀颗粒的数量，通过在熔体内产生超声能量的驻波来处理熔体，由此不均匀的颗粒集中并被鼓励聚结在驻波; 并从大部分液体熔体中分离聚结的颗粒。

39. 发明公开

EP0295798A1 Probe for determination of gas concentration in molten metal 有权转让
标题翻译： Sonde zur Bestimmung der Konzentration eines Geschmolzenem Metall的气体。
公开(公告)号：EP0295798A1
公开(公告)日：1988-12-21
申请号：EP88304758.1
申请日：1988-05-26
申请人： ALCAN INTERNATIONAL LIMITED
发明人： Dube, Ghyslain , Martin, Jean-Pierre , Doutre, Don A.
IPC分类号： G01N33/20
CPC分类号： G01N33/203
摘要： The invention provides a new immersion head probe for use in apparatus for the determination of the concentration of gas dissolved in a molten metal. Such determinations are needed to facilitate removal of the gas, which can cause bubbles in the solidified metal and subsequent processing difficulties. The apparatus circulates an inert carrier gas through the probe in gas exchange contact with the molten metal to entrain dissolved gas until an equilibrium mixture is obtained; the concentration of the dissolved gas in the mixture then is representative of its concentration in the molten metal. The head consists of a monolithic or integral body of a porous gas-permeable material of sufficient mechanical strength at the temperature of the molten metal and of sufficient porosity, pore size and permeability to permit the necessary gas diffusion in a reasonable period of time. The body of the probe preferably is thin in one direction to minimize the path length for the gas to diffuse therein, and is provided with a carrier gas inlet and outlet suitably spaced apart to ensure that the gas diffuses throughout the body. If the test is to be carried out in a stationary body of molten metal, the probe may be vibrated or the metal may be stirred to increase the probe/metal contact, both decreasing the time required for the gas mixture to reach sufficient equilibrium.
摘要翻译：本发明提供了一种用于测定溶解在熔融金属中的气体浓度的装置中的新型浸没头探针。需要这种测定以便于去除气体，这可能导致固化金属中的气泡和随后的加工困难。该装置使惰性载气通过探针与熔融金属气体交换接触，以夹带溶解的气体直至得到平衡混合物; 混合物中溶解气体的浓度则代表其在熔融金属中的浓度。头部由在熔融金属的温度下具有足够的机械强度并且具有足够的孔隙率，孔径和渗透性的多孔气体可渗透材料的整体或整体组成，以允许在合理的时间段内必需的气体扩散。探针的主体优选地在一个方向上是薄的，以最小化气体在其中扩散的路径长度，并且设置有适当间隔开的载气入口和出口，以确保气体在整个身体中扩散。如果要在熔融金属的固定体中进行试验，探头可能会振动，或者可以搅拌金属以增加探针/金属接触，同时减少气体混合物达到足够平衡所需的时间。

40. 发明公开

EP0250411A1 AN ARRANGEMENT FOR USE IN THE THERMAL ANALYSIS AND MODIFICATION OF MOLTEN METAL 失效转让
标题翻译：安排FOR USE IN热分析和改性熔融金属。
公开(公告)号：EP0250411A1
公开(公告)日：1988-01-07
申请号：EP86901544.0
申请日：1986-02-04
申请人： SINTER-CAST AB
发明人： BÄCKERUD, Stig, Lennart
IPC分类号： G01N , G01N25 , C22C1 , C22C21 , C22C23 , G01N1 , G01N33
CPC分类号： G01N25/04 , G01N33/203 , Y10S73/09
摘要： Un agencement est utilisé pour l'analyse et la modification thermiques de métaux fondus par l'enregistrement de données de solidification et par l'ajustement des modifications structurelles du métal fondu sur la base de ces données. L'agencement comprend un récipient d'échantillonnage fait d'un matériau sensiblement stable à la température du métal fondu et contenant au moins un thermoélément pour enregistrer les données de solidification. Un dispositif permet de prendre un échantillon du métal fondu à l'aide du récipient, et transporte l'échantillon jusqu'à une zone où règnent essentiellement les mêmes conditions. En outre, l'agencement comprend un dispositif d'enregistrement et un dispositif de modification de la structure des métaux fondus, selon les besoins. Le récipient d'échantillonnage est construit de façon à se remplir de métal fondu lorsque le récipient est immergé dans le métal fondu, le contenu antérieur du récipient étant remplacé par du métal fondu frais suite au déplacement relatif du récipient dans le métal fondu. Un dispositif assure la collecte d'une quantité adéquate de métal fondu pendant l'opération d'échantillonnage. Cet objectif peut être atteint en formant des ouvertures dans le récipient fermées et ouvertes par un dispositif de soupape ou par un autre agencement approprié.

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