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    • 32. 发明公开
    • Preparation of highly crystallized, molded polyarylene thioether products
    • Herstellung von hoch-kristallisierten,geformten Polyarylenthioether-Produkten。
    • EP0285377A2
    • 1988-10-05
    • EP88302798.9
    • 1988-03-29
    • KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
    • Kawakami, YukichikaIwasaki, TakaoShiiki, Zenya
    • B29C71/00C08J7/02C08J5/18
    • C08J5/18B29C55/00B29C55/005B29C67/24B29C71/0009B29C71/0063B29C71/02B29K2081/00C08G75/0254C08G75/0277C08J7/02C08J2381/02D01F6/765
    • A highly crystallized, molded product of a polyarylene thioether is prepared by:

      (1) stretching a molded product, consisting of a resin having as the main component a polyarylene thioether which contains not less than 70 mol% of the repeating unit
      and which has a degree of crystallization (measured by a density method) of not more than 15%, from 2 to 5 times in size in at least one direction,
      (2) contacting the stretched molded product with at least one organic solvent having a solubility parameter SP of from 8 to 12 or with a mixed solvent containing not less than 50% by weight of the said organic solvent at a temperature of from the solidifying point of the said organic solvent or mixed solvent to 130°C, thereby preliminarily crystallizing the treated, molded product, until the degree of crystallization of the said polyarylene thioether has increased by not less than 6%, and
      (3) subjecting the preliminarily crystallized, molded product to thermal treatement at a temperature of from 140 to 300°C until the degree of crystallization of the said polyarylene thioether reaches not less than 22%.
    • 聚亚芳基硫醚的高度结晶的模制产品是通过以下步骤制备的:(1)拉伸成型产品,其由主要成分为含有不少于70重量%重复单元的聚亚芳基硫醚的树脂和 其具有在至少一个方向上具有不大于15%的结晶度(尺寸为2至5倍),(2)使拉伸的模制产品与至少一种具有溶解度的有机溶剂接触 参数SP为8〜12,或者在所述有机溶剂或混合溶剂的固化温度至130℃的温度下,含有不少于50重量%的所述有机溶剂的混合溶剂,由此预先使 直到所述聚亚芳基硫醚的结晶度增加不少于6%,和(3)将预结晶的成型产物在温度下进行热处理 e至140至300℃,直到所述聚亚芳基硫醚的结晶程度达到不低于22%。 H
    • 38. 发明公开
    • METHOD FOR PRODUCING LONG FIBER NONWOVEN FABRIC
    • VERFAHREN ZUR HERSTELLUNG EINES LANGFASERIGEN VLIESSTOFFS
    • EP2511409A1
    • 2012-10-17
    • EP10835919.1
    • 2010-12-06
    • Toray Industries, Inc.
    • NAKANO, YoheiYAKAKE, Yoshikazu
    • D04H3/00D01D5/098D01F6/76D04H3/14
    • D01F6/765B29C47/0014D01D5/0985D04H3/00
    • Abstract: Provided is a method for producing a long fiber nonwoven fabric which uses polyphenylene sulfide exhibiting excellent spinnability as the main component, and which involves a simplified step hi which heat treatment, which is performed for the purpose of having dimensional stability against heat, is not performed hi the step after a nonwoven fiber web was formed. The method for producing a long fiber nonwoven fabric involves: a step (a) for obtaining a long fiber by melting a resin which has polyphenylene sulfide as the main component, and by pulling and stretching a thread, which was frozen and solidified after being ejected through a spinneret, at a spinning speed of 3,000m/min or more by means of an ejector, while heating said thread up to the ejector outlet; a step (b) for forming the long fiber into a nonwoven fiber web by collecting the long fiber on a moving net; and a step (c) for thermally adhering the resulting nonwoven fiber web.
    • 摘要:提供一种长纤维无纺布的制造方法,该长纤维无纺布使用以可纺性为好的聚苯硫醚为主要成分,其中包括为了具有耐热尺寸稳定性而进行的热处理的简化步骤 在无纺纤维网形成之后的步骤中不进行。 长纤维无纺布的制造方法包括:通过使以聚苯硫醚为主要成分的树脂熔融而获得长纤维的步骤(a),拉伸拉伸被喷出后冷冻凝固的丝 通过喷丝头,通过喷射器以3000m / min或更高的纺丝速度通过喷丝头,同时将所述线加热到喷射器出口; 步骤(b),通过将长纤维收集在移动网上,将长纤维形成无纺纤维网; 以及用于热粘合所得非织造纤维网的步骤(c)。